Diastereoselective synthesis of seven-membered-ring trans-alkenes from dienes and aldehydes by silylene transfer

Journal of the American Chemical Society

Volumn 134, Issue 30, 2012, Pages 12482-12484

  Greene, Margaret A ^a,b   Prévost, Michel ^a,c   Tolopilo, Joshua ^a   Woerpel, K A ^a  

^a NEW YORK UNIVERSITY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c CLIN RESEARCH INSTITUTE OF MONTREAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON-CARBON DOUBLE BONDS; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE SYNTHESIS; HIGH REACTIVITY; SIGMATROPIC REARRANGEMENT REACTION; SILYLENES;

ALDEHYDES; HYDROGEN BONDS; ORGANIC COMPOUNDS; STEREOSELECTIVITY;

OLEFINS;

ALDEHYDE; ALKADIENE; ALKENE; CYCLOPROPANE; OXYGEN; SILANE DERIVATIVE; SILICON; SILVER; SILYLENE; UNCLASSIFIED DRUG; VINYLSILACYCLOPROPANE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; HYDROGEN BOND; STEREOCHEMISTRY; SYNTHESIS;

ALDEHYDES; ALKENES; CATALYSIS; POLYENES; SILANES; SILVER; STEREOISOMERISM;

EID: 84864464498     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja305713v     Document Type: Article

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