A thermodynamic model for predicting mineral reactivity in supercritical carbon dioxide: I. Phase behavior of carbon dioxide-water-chloride salt systems across the H 2O-rich to the CO 2-rich regions

Chemical Geology

Volumn 322-323, Issue , 2012, Pages 151-171

  Springer, Ronald D ^a   Wang, Zheming ^b   Anderko, Andrzej ^a   Wang, Peiming ^a   Felmy, Andrew R ^b  

^a OLI SYSTEMS INC   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

Chloride salts; Mineral reactivity; Mixed solvent electrolyte model; Supercritical carbon dioxide; Thermodynamic modeling

Indexed keywords

AQUEOUS SYSTEM; CHLORIDE SALTS; COMPOSITION RANGES; ELECTROLYTE CONCENTRATION; ELECTROLYTE MODELS; EQUATION OF STATE; EXCESS GIBBS ENERGY; EXPERIMENTAL DATABASE; FORSTERITES; LITERATURE DATA; MINERAL TRANSFORMATIONS; MIXED-PHASE SYSTEM; NESQUEHONITE; NEUTRAL MOLECULES; RICH PHASE; SALT SYSTEMS; SOLUBILITY MEASUREMENT; SUPERCRITICAL CARBON DIOXIDES; SUPERCRITICAL CO; TERNARY MIXTURES; THERMODYNAMIC MODEL; THERMODYNAMIC MODELING; WATER ACTIVITY;

CALCIUM CHLORIDE; CHLORIDE MINERALS; ELECTROLYTES; FORECASTING; INTERNET PROTOCOLS; MINERALS; NEAR INFRARED SPECTROSCOPY; OLIVINE; PHASE EQUILIBRIA; SODIUM CHLORIDE; SOLUBILITY; SUPERCRITICAL FLUID EXTRACTION; TEMPERATURE;

CARBON DIOXIDE;

AQUEOUS SOLUTION; CARBON DIOXIDE; CHLORIDE; CONCENTRATION (COMPOSITION); ELECTROLYTE; GIBBS FREE ENERGY; PARAMETERIZATION; SOLUBILITY; TEMPERATURE; THERMODYNAMICS; TRANSFORMATION; WATER CONTENT;

EID: 84864403970     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2012.07.008     Document Type: Article

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