Equations of state for the NaCl-H2O-CH4 system and the NaCl-H2O-CO2-CH4 system: Phase equilibria and volumetric properties above 573 K

Geochimica et Cosmochimica Acta

Volumn 67, Issue 4, 2003, Pages 671-680

  Duan, Zhenhao ^a   Møller, Nancy ^a   Weare, John H ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; CARBON DIOXIDE; EQUATION OF STATE; METHANE; PARAMETERIZATION; PHASE EQUILIBRIUM; QUATERNARY; SODIUM CHLORIDE; THERMODYNAMICS;

EID: 0037441988     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(02)01226-7     Document Type: Article

References (50)

1. 2 streams and live oil system. Soc. Pet. J. 25, 268-274.
2. Anderko A. and Pitzer K. S. (1991) Equation of state for pure fluids and mixtures based on a truncated virial expansion. AIChE J. Am. Inst. Chem. Eng. 37, 1379-1391.
3. 2O above 573 K. Geochim. Cosmochim. Acta 57, 1657-1680.
4. Bazayev A. R., Skripka V. G., Namiot A. Yu. (1974) Volumetric properties of mixtures of water vapor with methane and nitrogen at elevated temperatures and pressures. Zh. Fiz. Khrim. VINTI deposit No. 1631.
5. Bischoff J. L. (1980) Geothermal system at 21°N, East Pacific Rise: Physical limits on geothermal fluid and role of adiabatic expansion. Science 207, 1465-1469.
6. 2O-NaCl as an example. Pure Appl. Chem. 67, 873-880.
7. Boublik T. (1970) Hard sphere equation of state. J. Chem. Phys. 53, 471-472.
8. Cotterman R. L., Schwarz B. J., and Prausnitz J. M. (1986) Molecular thermodynamics for fluids at low and high densities, part I: pure fluids containing small and large molecules. AIChE J. Am. Inst. Chem. Eng. 32, 1787-1812.
9. Crawford M. L. (1981) Phase equilibria in aqueous fluid inclusions. Min. Assoc. Can. Short Course Handb. 6, 75-100.
10. Diamond L. W. (1990) Fluid inclusion evidence for P-V-T-X evolution of hydrothermal solutions in late alpine gold-quartz veins at Brusson, Val d'Ayas, Northwest Italian Alps. Am. J. Sci. 290, 912-958.
11. Dimitrelis D. and Prausnitz J. M. (1986) Comparison of two hardsphere reference systems for perturbation theories for mixtures. Fluid Phase Equil. 31, 1-21.
12. 2O system: I. Pure systems from 0 to 1000 °C and 0 to 8000 bar. Geochim. Cosmochim. Acta 56, 2605-2617.
13. 2O system: II. mixtures from 50 to 1000 °C and from 0 to 1000 bar. Geochim. Cosmochim. Acta 56, 2619-2631.
14. Duan Z., Møller N., and Weare J. H. (1992c) The prediction of methane solubilities in natural waters to high ionic strength from 0 to 250 °C and from 0 to 1600 bar. Geochim. Cosmochim. Acta 56, 1451-1460.
15. 2 system: prediction of phase equilibria and volumetric properties. Geochim. Cosmochim. Acta 59, 2869-2882.
16. 2 up to 2000 K and 100 kbar from a corresponding states/one fluid equation of state. Geochim. Cosmochim. Acta 64, 1069-1075.
17. Dubessy J., Buschaert S., Lamb W., and Pironon J. (2001) Methanebearing fluid inclusions: Raman analysis, thermodynamic modeling and application to petroleum basins. Chem Geol. 173, 193-205.
18. Fournier R. O. (1987) Conceptual models of brine evolution in magmatic hydrothermal systems. In Volcanism in Hawaii (eds. R. W. Derker, T. L. Wright, and P. H. Stauffer), pp. 1487-1506.
19. 2 on molten halides. Indes. Acta Chem. Scand. 16, 689-694.
20. Gubbins K. E. and Twu C. H. (1978) Thermodynamics of polyatomic fluid mixtures - I. Theory. Chem. Eng. Sci. 33, 863-878.
21. Hanor J. S. (1979) The sedimentary genesis of hydrothermal fluids. In Geochemistry of hydrothermal ore deposits (ed. H. L. Barnes), pp. 137-168. , Wiley-Interscience, New York.
22. Kelly D. S. (1996) Methane rich fluids in the oceanic crust. J. Geophys. Res. (Solid Earth) 101, 2943-2962.
23. Kharaka Y. K., Carothers W. W., Law L. M. (1985) Origin of gaseous hydrocarbons in geopressured geothermal waters. Proc. Sixth U.S. Gulf Coast Geopress.-Geotherm. Energy Conf. 6, 125.
24. 4-NaCl bis 250 Mpa und 800 K. Thesis, Institute for Physical Chemistry, Univ. Karlsrule.
25. 2 to 800 K and 250 Mpa. Ber. Bunsenges. Phys. Chem. 91, 627-634.
26. 4-NaCl system at 1 kbar, 400-600 degrees-C using synthetic fluid inclusions. Geochim. Cosmochim. Acta 60, 1885-1897.
27. Lichtner P. C. (1985) Continuum model for simultaneous chemical reactions and mass transport in hydrothermal systems. Geochim. Cosmochim. Acta 49, 779-800.
28. Michelsen M. L. (1993) Phase equilibrium calculations. What is easy and what is difficult? Comp. Chem. Eng. 17, 431-439.
29. Mullis J., Dubessy J., Poty B., and O'Neil J. (1994) Fluid regimes during late stages of a continental collision: physical, chemical, and stable isotope measurements of fluid inclusions in fissure quartz from a getraverse through the Central Alps, Switzerland. Geochim. Cosmochim. Acta 58, 2239-2267.
30. 2-NaCl system during emerald mineralization at Gravelotte, Murchison Greenstone belt, Northest Transvaal, South Africa. Geochim. Cosmochim. Acta 57, 89-103.
31. nd Ed), New York, New York.
32. Pruess K. (1987) TOUGH User's Guide. Lawrence Berkeley Laboratory Report. LBL-20700.
33. Ramboz C. (1979) Fluid inclusion study of the copper mineralization in the Southwest Tintic District (Utah). Bull. Soc. Fr. Min. 102, 622- 632.
34. 2 -bearing fluid in a wolframite vein: Reconstruction from fluid inclusion studies. Geochim. Cosmochim. Acta 49, 205-219.
35. Reamer H. H., Olds R. H., Sage B. H., and Lacey W. N. (1944) Phase equilibria in hydrocarbon systems: methane-carbon dioxide system in the gaseous region. Ind. Eng. Chem. 36, 88-90.
36. Riney T. D. (1992) Pleasant Bayou geopressured-geothermal reservoir analysis. J. Energy Res. Tech. - Trans. AMSE. 119, 237-238.
37. Stell G., Rasaiah J. C., and Narang H. (1972) Thermodynamic perturbation theory for simple fluids, I. Mol. Phys. 23, 393-406.
38. Stell G., Rasaiah J. C., and Narang H. (1974) Thermodynamic perturbation theory for simple fluids, II. Mol. Phys. 27, 1393-1414.
39. Sultanov R. C. and Skripka V. G. (1971) Moisture content of methane at high temperatures methane at high pressures and temperatures (in Russian). Dokl. Akad. Nauk SSSR. 176, 423-425.
40. Sultanov R. C., Skripka V. G., and Namiot A. Yu (1972) Solubility of methane in water at high temperatures and pressures. Caz. Promyshlen. 17, 6-7 (in Russian).
41. 2-NaCl inclusions from the footwall contact of the Tano granitic pegmatite: Estimates of internal pressure and compositions from microthermometry, laser Raman spectroscopy, and gas chromatography. Geochim. Cosmochim. Acta 54, 559-573.
42. Triklis D. S. and Linshits L. R. (1967) Molar volumes and thermodynamic properties of carbon dioxide and methane. Energy Res. Tech. 114, 315-322.
43. Truesdell A. H. and White D. E. (1973) Production of overheated steam from vapor dominated geothermal reservoirs. Geotherm. 2, 154- 166.
44. Twu C. I. and Gubbins K. E. (1975) Excess thermodynamic properties for liquid mixture properties for liquid mixtures of non-spherical molecules. Mol. Phys. 29, 713-729.
45. Vrolijk P., Myers G., and Moore J. C. (1988) Warm fluid migration along tectonic melanges in the Kodiak accretionary complex, Alaska. J. Geophys. Res. 93, 10313-10324.
46. Walas M. (1985) Phase equilibria in chemical engineering. Butterworth publishers, Boston.
47. Welhan J. A. and Craig H. (1979) Methane and hydrogen in East Pacific Rise hydrothermal fluids. Geophy. Res. Lett. 6, 829-831.
48. Welsch H. (1973) Die system xenon-wasser und methan-wasser bei holen drucken und temperaturen. Ph.D. dissertation, Univ. Karlsruhe.
49. White D. E., Anderson E. T., and Grubbs D. K. (1963) Geothermal brine well: mile-deep drill hole may tap ore-bearing magmatic water and rocks undergoing metamorphism. Science 139, 919-922.
50. 2O system using synthetic fluid