Esterification of fatty acids using Candida antarctica lipase A in water-abundant systems

Biotechnology Letters

Volumn 34, Issue 8, 2012, Pages 1459-1463

  Brenneis, Rudolf ^a   Baeck, Burkhard ^a  

^a BAM FEDERAL INSTITUTE FOR MATERIALS RESEARCH AND TESTING   (Germany)

Author keywords

2 Ethyl 1 hexyl palmitic acid ester; Candida antarctica lipase A; Enzymatic esterification; Fatty acids; Water abundant system

Indexed keywords

1-DECANOL; 2-ETHYL-1-HEXANOL; CANDIDA ANTARCTICA; CANDIDA ANTARCTICA LIPASE A; ENZYMATIC ESTERIFICATION; LINEAR ALCOHOLS; LIPASE A; MOLAR RATIO; STIRRED TANK REACTORS; SUBSTRATE SELECTIVITY; WATER-ABUNDANT SYSTEM;

ALCOHOLS; ESTERIFICATION; FATTY ACIDS; ISOMERS; OLEIC ACID; PALMITIC ACID; REACTION RATES; SATURATED FATTY ACIDS; TANKS (CONTAINERS);

ESTERS;

2 ETHYLHEXANOL; 2-ETHYLHEXANOL; CHOLESTEROL ESTERASE; ETHYLHEXYL PALMITATE; FUNGAL PROTEIN; HEXANOL; PALMITIC ACID; PALMITIC ACID DERIVATIVE; WATER;

ARTICLE; BIOREACTOR; CANDIDA; CHEMISTRY; ENZYMOLOGY; ESTERIFICATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; METABOLISM;

BIOREACTORS; CANDIDA; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; ESTERIFICATION; FUNGAL PROTEINS; HEXANOLS; PALMITATES; PALMITIC ACID; STEROL ESTERASE; WATER;

CANDIDA ANTARCTICA;

EID: 84864391215     PISSN: 01415492     EISSN: 15736776     Source Type: Journal    
DOI: 10.1007/s10529-012-0928-1     Document Type: Article

References (14)

1. Brenneis R, Baeck B, Kley G (2004) Alcoholysis of waste fats with 2-ethyl-1-hexanol using Candida antarctica lipase A in large-scale tests. Eur J Lipid Sci Technol 106: 809-814.
2. Christensen MW, Andersen L, Husum TL, Kirk O (2003) Industrial lipase immobilization. Eur J Lipid Sci Technol 105: 318-321.
3. de Maria PD, Carboni-Oerlemans C, Tuin B, Bargeman G, van der Meer A, van Gemert R (2005) Biotechnological applications of Candida antarctica lipase A: state-of-the-art. J Mol Catal B Enzyme 37: 36-46.
4. Ericsson DJ, Kasrayan K, Johansson P, Bergfors T, Sandström AG, Bäckvall JE, Mowbray SL (2008) X-ray structure of Candida antarctica Lipase A shows a novel lid structure and a likely mode of interfacial activation. J Mol Biol 376: 109-119.
5. Hesselbach J, Herrmann C, Bock R, Dettmer T, Kley G, Köcher P, Brenneis R, Meyer-Pittroff R, Falk O, Hansen A (2003) Kühlschmierstoffe aus technischen tierischen Fetten und Altspeisefetten-Herstellung, Technologie und Ökobilanzierung. Transkript (Sonderheft, Nachhaltige Biokatalyse, Okt. 2003), pp 24-27.
6. Hills G (2003) Industrial use of lipases to produce fatty acid esters. Eur J Lipid Sci Technol 105: 601-607.
7. Jiang Y, Morley KL, Schrag JD, Kazlauskas RJ (2011) Different active-site loop orientation in serine hydrolases versus acyltransferases. Chem Bio Chem 12: 768-776.
8. Kirk O, Christensen MW (2002) Lipases from Candida antarctica: unique biocatalysts from a unique origin. Org Process Res Dev 6: 446-451.
9. Larsen MW, Zielinska DF, Martinelle M, Hidalgo A, Jensen LJ, Bornscheuer UT, Hult K (2010) Suppression of water as a nucleophile in Candida antarctica lipase B catalysis. Chem Bio Chem 11: 796-801.
10. Liljeblad A, Kallio P, Vainio M, Niemi J, Kanerva LT (2010) Formation and hydrolysis of amide bonds by lipase A from Candida antarctica: exceptional features. Org Biomol Chem 8: 886-895.
11. Martinelle M, Holmquist M, Hult K (1995) On the interfacial activation of Candida antarctica lipase A and B as compared with Humicola lanuginosa lipase. Biochim Biophys Acta 1258: 272-276.
12. Wichmann H, Bahadir M (2007) Bio-based ester oils for use as lubricants in metal working. Clean 35: 49-51.
13. Xu X (2003) Engineering of enzymatic reactions and reactors for lipid modification and synthesis. Eur J Lipid Sci Technol 105: 289-304.
14. Yahya ARM, Anderson WA, Moo-Young M (1998) Ester synthesis in lipase-catalyzed reactions. Enzyme Microb Technol 23: 438-450.