Measuring the activation energy of thiol desorption using lateral force microscopy

Scanning

Volumn 34, Issue 3, 2012, Pages 200-205

  Liao, Yen Chih ^a   Sun, Huizhong ^a   Weeks, Brandon L ^a  

^a Department of Electrical and Computer Engineering   (United States)

Author keywords

AFM other scanned probe microscopes; surface analysis

Indexed keywords

16-MERCAPTOHEXADECANOIC ACID; ACTIVATION ENERGY OF DESORPTIONS; AFM/OTHER SCANNED PROBE MICROSCOPES; EFFECT OF TEMPERATURE; FRICTION FORCE; FRICTION SIGNALS; GOLD SURFACES; KINETIC MODELS; LATERAL FORCE; LATERAL FORCE MICROSCOPY; MODEL MATERIALS; SURFACE SCIENCE; THIOL MOLECULES;

ACTIVATION ENERGY; ATOMIC FORCE MICROSCOPY; FRICTION; LUNAR SURFACE ANALYSIS; SELF ASSEMBLED MONOLAYERS; SURFACE ANALYSIS;

DESORPTION;

16 MERCAPTOHEXADECANOIC ACID; GOLD; PALMITIC ACID; SELF ASSEMBLED MONOLAYER; THIOL; UNCLASSIFIED DRUG;

ARTICLE; ATOMIC FORCE MICROSCOPY; DESORPTION; ENERGY; HEATING; PRIORITY JOURNAL; THERMOSTABILITY;

FRICTION; GOLD; KINETICS; MICROSCOPY, ATOMIC FORCE; MOLECULAR STRUCTURE; PALMITIC ACIDS; SULFHYDRYL COMPOUNDS; SURFACE PROPERTIES; TEMPERATURE; TIME FACTORS;

EID: 84864290676     PISSN: 01610457     EISSN: 19328745     Source Type: Journal    
DOI: 10.1002/sca.20293     Document Type: Article

References (33)

1. Aizenberg J, Black AJ, Whitesides GM,. 1999. Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver. J Am Chem Soc 121: 4500-4509.
2. Bhushan B, Dandavate C,. 2000. Thin-film friction and adhesion studies using atomic force microscopy. J Appl Phys 87: 1201-1210.
3. Brito R, Tremont R, Feliciano O, Cabrera CR,. 2003. Chemical derivatization of self-assembled 3-mercaptopropionic and 16-mercaptohexadecanoic acids at platinum surfaces with 3-aminopropyltrimethoxysilane: a spectroscopic and electrochemical study. J Electroanal Chem 540: 53-59.
4. Chandekar A, Sengupta SK, Whitten JE,. 2010. Thermal stability of thiol and silane monolayers: a comparative study. Appl Surf Sci 256: 2742-2749.
5. Delamarche E, Michel B, Kang H, Gerber C,. 1994. Thermal stability of self-assembled monolayers. Langmuir 10: 4103-4108.
6. Fenter P, Eisenberger P, Li J, Camillone N, Bernasek S, Scoles G, Ramanarayanan TA, Liang KS,. 1991. Structure of octadecyl thiol self-assembled on the silver(111) surface: an incommensurate monolayer. Langmuir 7: 2013-2016. (Pubitemid 21735660)
7. Ferretti S, Paynter S, Russell DA, Sapsford KE, Richardson DJ,. 2000. Self-assembled monolayers: a versatile tool for the formulation of bio-surfaces. Trends Anal Chem 19: 530-540.
8. Fontes GN, Moreira RL, Neves BRA,. 2004. Thermally induced stacking of octadecylphosphonic acid self-assembled bilayers. Nanotechnology 15: 682.
9. Garg N, Carrasquillo-Molina E, Lee TR,. 2002. Self-assembled monolayers composed of aromatic thiols on gold: structural characterization and thermal stability in solution. Langmuir 18: 2717-2726. (Pubitemid 35383844)
10. Gole A, Orendorff CJ, Murphy CJ,. 2004. Immobilization of gold nanorods onto acid-terminated self-assembled monolayers via electrostatic interactions. Langmuir 20: 7117-7122.
11. Hayashi K, Sugimura H, Takai O,. 2001. Frictional properties of organosilane self-assembled monolayer in vacuum. Jpn J Appl Phys 40: 4344.
12. Ishida T, Fukushima H, Mizutani W, Miyashita S, Ogiso H, Ozaki K, Tokumoto H,. 2001. Annealing effect of self-assembled monolayers generated from terphenyl derivatized thiols on Au(111). Langmuir 18: 83-92.
13. Laibinis PE, Fox MA, Folkers JP, Whitesides GM,. 1991. Comparisons of self-assembled monolayers on silver and gold: mixed monolayers derived from HS(CH2)21X and HS(CH2)10Y (X, Y = CH3, CH2OH) have similar properties. Langmuir 7: 3167-3173.
14. Libioulle L, Bietsch A, Schmid H, Michel B, Delamarche E,. 1998. Contact-inking stamps for microcontact printing of alkanethiols on gold. Langmuir 15: 300-304.
15. Liu Y, Wu T, Evans DF,. 1994. Lateral force microscopy study on the shear properties of self-assembled monolayers of dialkylammonium surfactant on mica. Langmuir 10: 2241-2245.
16. Love JC, Estroff LA, Kriebel JK, Nuzzo RG, Whitesides GM,. 2005. Self-assembled monolayers of thiolates on metals as a form of nanotechnology. Chem Rev 105: 1103-1170.
17. Lowry TH, Richardson KS,. 1987. Mechanism and theory in organic chemistry, xii. New York: Harper 8 Row. 1090p.
18. Mrksich M, Whitesides GM,. 1995. Patterning self-assembled monolayers using microcontact printing: a new technology for biosensors? Trends Biotechnol 13: 228-235.
19. Neves BRA, Salmon ME, Russell PE, Troughton EB,. 2000. Thermal stability study of self-assembled monolayers on mica. Langmuir 16: 2409-2412. (Pubitemid 30576756)
20. Noy A, Sanders CH, Vezenov DV, Wong SS, Lieber CM,. 1998. Chemically-sensitive imaging in tapping mode by chemical force microscopy: relationship between phase lag and adhesion. Langmuir 14: 1508-1511. (Pubitemid 128587127)
21. Ruckenstein E, Li ZF,. 2005. Surface modification and functionalization through the self-assembled monolayer and graft polymerization. Adv Colloid Interf Sci 113: 43-63. (Pubitemid 40324887)
22. Schlenoff JB, Li M, Ly H,. 1995. Stability and self-exchange in alkanethiol monolayers. J Am Chem Soc 117: 12528-12536. (Pubitemid 26200346)
23. Schreiber F,. 2000. Structure and growth of self-assembling monolayers. Prog Surf Sci 65: 151-257.
24. Schwartz DK,. 2001. Mechanisms and kinetics of self-assembled monolayer formation. Annu Rev Phys Chem 52: 107-137. (Pubitemid 33655119)
25. Sellers H, Ulman A, Shnidman Y, Eilers JE,. 1993. Structure and binding of alkanethiolates on gold and silver surfaces: implications for self-assembled monolayers. J Am Chem Soc 115: 9389-9401.
26. Shadnam MR, Amirfazli A,. 2005. Kinetics of alkanethiol monolayer desorption from gold in air. Chem Commun 4869-4871. (Pubitemid 41503216)
27. Tian F, Xiao X, Loy MMT, Wang C, Bai C,. 1998. Humidity and temperature effect on frictional properties of mica and alkylsilane monolayer self-assembled on mica. Langmuir 15: 244-249.
28. Wagner P, Hegner M, Guentherodt H-J, Semenza G,. 1995. Formation and in situ modification of monolayerschemisorbed on ultraflat template-stripped gold surfaces. Langmuir 11: 3867-3875.
29. Whitesides GM, Laibinis PE,. 1990. Wet chemical approaches to the characterization of organic surfaces: self-assembled monolayers, wetting, and the physical-organic chemistry of the solid-liquid interface. Langmuir 6: 87-96.
30. Wilbur JL, Kumar A, Kim E, Whitesides GM,. 1994. Microfabrication by microcontact printing of self-assembled monolayers. Adv Mater 6: 600-604. (Pubitemid 24972295)
31. Xiao X, Hu J, Charych DH, Salmeron M,. 1996. Chain length dependence of the frictional properties of alkylsilane molecules self-assembled on mica studied by atomic force microscopy. Langmuir 12: 235-237. (Pubitemid 126567932)
32. Yang X, Perry SS,. 2003. Friction and molecular order of alkanethiol self-assembled monolayers on Au(111) at elevated temperatures measured by atomic force microscopy. Langmuir 19: 6135-6139.
33. Zhang G, Sun H, Abbott JM, Weeks BL,. 2009. Engineering the microstructure of organic energetic materials. ACS Appl Mater Interf 1: 1086-1089.