Synthesis and characterization of all acrylic block copolymer/clay nanocomposites prepared via surface initiated atom transfer radical polymerization (SI-ATRP)

Industrial and Engineering Chemistry Research

Volumn 51, Issue 29, 2012, Pages 9760-9768

  Haloi, Dhruba J ^a   Ata, Souvik ^a   Singha, Nikhil K ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

2-ETHYL HEXYL ACRYLATE; ALL-ACRYLIC BLOCK COPOLYMERS; ATRP INITIATOR; CLOISITE; DIETHYLENETRIAMINE; FOURIER TRANSFORM INFRARED; GRAFTING REACTIONS; MACROINITIATORS; METHYL METHACRYLATES; NANO CLAYS; NANOCLAY LOADINGS; REACTION CONDITIONS; STRATEGIC ADVANTAGES; SURFACE INITIATED POLYMERIZATION; SURFACE INITIATED-ATOM TRANSFER RADICAL POLYMERIZATION; TEM ANALYSIS;

BLOCK COPOLYMERS; BROMINE COMPOUNDS; ESTERS; GEL PERMEATION CHROMATOGRAPHY; GRAFTING (CHEMICAL); INTERNET PROTOCOLS; LOADING; NANOCOMPOSITES; POLYMERIZATION; SODIUM; SURFACE PROPERTIES; SURFACE REACTIONS; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 84864245396     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie300953c     Document Type: Article

References (40)

1. Polymer-Clay Nanocomposites; Pinnavaia, T. J. and Beall, G. W., Eds.; Wiley: New York, 2000.
2. Nanocomposite Science and Technology; Ajayan, P. M., Schadler, L. S., and Braun, P. V., Eds.; Wiley-VCH Verlag GmbH & Co., KGaA: Weinheim, Germany, 2003.
3. Block Copolymers: Synthetic Strategies, Physical Properties, and Applications; Hadjichristidis, N., Pispasm, S., and Floudas, G., Eds.; J. Wiley & Sons: Chichester, UK, 2002.
4. Fan, X.; Xia, C.; Advincula, R. Grafting of polymers from clay nanoparticles via in situ free radical surface-initiated polymerization: Monocationic versus bicationic initiators Langmuir 2003, 19, 4381
5. Jordan, R.; West, N.; Ulman, A.; Chou, Y. M.; Nuyken, O. Nanocomposites by surface-initiated living cationic polymerization of 2-oxazolines on functionalized gold nanoparticles Macromolecules 2001, 34, 1606
6. Lenarda, M.; Chessa, G.; Moretti, E.; Polizzi, S.; Storaro, L.; Talo, A. Toward the preparation of a nanocomposite material through surface initiated controlled/"living" radical polymerization of styrene inside the channels of MCM-41 silica J. Mater. Sci. 2006, 41, 6305
7. Liu, Y.; Klep, V.; Zdyrko, B.; Luzinov, I. Polymer grafting via ATRP initiated from macroinitiator synthesized on surface Langmuir 2004, 20, 6710
8. Karagoz, B.; Bayramoglu, G.; Altintas, B.; Bicak, N.; Arica, M. Y. Poly(glycidyl methacrylate)-polystyrene diblocks copolymer grafted nanocomposite microspheres from surface-initiated atom transfer radical polymerization for lipase immobilization: Application in flavor ester synthesis Ind. Eng. Chem. Res. 2010, 49, 9655
9. Prucker, O.; Rühe, J. Synthesis of poly(styrene) monolayers attached to high surface area silica gels through self-assembled monolayers of azo initiators Macromolecules 1998, 31, 592
10. Prucker, O.; Rühe, J. Mechanism of radical chain polymerizations initiated by azo compounds covalently bound to the surface of spherical particles Macromolecules 1998, 31, 602
11. Blomberg, S.; Ostberg, S.; Harth, E.; Bosman, A. W.; Horn, B. V.; Hawker, C. J. Production of crosslinked, hollow nanoparticles by surface-initiated living free-radical polymerization J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 1309
12. Husemann, M.; Mecerreyes, D.; Hawker, C. J.; Hedrick, J. L.; Shah, R.; Abbott, N. L. Surface-initiated polymerization for amplification of self-assembled monolayers patterned by microcontact printing Angew. Chem., Int. Ed. 1999, 38, 647
13. Matyjaszewski, K.; Davis, T. P. Handbook of Radical Polymerization, 1 st ed.; Wiley-Interscience: 2002.
14. Controlled/Living Radical Polymerization Progress in ATRP, NMP and RAFT, ACS Symposium Series; Matyjaszewski, K., Ed.; American Chemical Society: Washington, DC, 1997; p 685.
15. Li, Q.; Zhang, L.; Zhang, Z.; Zhou, N.; Cheng, Z.; Zhu, X. Air-tolerantly surface-initiated AGET ATRP mediated by iron catalyst from silica nanoparticles J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 2006
16. Liu, Y. L.; Han, C. C.; Wei, T. C.; Chang, Y. Surface-initiated atom transfer radical polymerization from porous poly(tetrafluoroethylene) membranes using the C-F groups as initiators J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 2076
17. Cheng, Z.; Zhu, X.; Shi, Z. L.; Neoh, K. G.; Kang, E. T. Polymer microspheres with permanent antibacterial surface from surface-initiated atom transfer radical polymerization Ind. Eng. Chem. Res. 2005, 44, 7098
18. Lei, Z.; Bi, S. Preparation of polymer nanocomposites of core-shell structure via surface-initiated atom transfer radical polymerizations Mater. Lett. 2007, 61, 3531
19. Datta, H.; Bhowmick, A. K.; Singha, N. K. Tailor-made hybrid nanostructure of poly(ethyl acrylate)/clay by surface-initiated atom transfer radical polymerization J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 5014
20. Kim, J. B.; Huang, W.; Miller, M. D.; Baker, G. L.; Bruening, M. L. Kinetics of surface-initiated atom transfer radical polymerization J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 386
21. Xu, F. J.; Kang, E. T.; Neoh, K. G. Resist-free micropatterning of binary polymer brushes on Si(100) via surface-initiated living radical polymerizations J. Mater. Chem. 2006, 16, 2948
22. Kim, J. B.; Bruening, M. L.; Baker, G. L. Surface-initiated atom transfer radical polymerization on gold at ambient temperature J. Am. Chem. Soc. 2000, 122, 7616
23. Kim, D. J.; Kang, S. M.; Kong, B.; Kim, W. J.; Paik, H. J.; Choi, H.; Choi, I. S. Formation of thermoresponsive gold nanoparticle/PNIPAAm hybrids by surface-initiated, atom transfer radical polymerization in aqueous media. Macromol. Chem. Phys. 2005, 206, 1941.
24. Xu, F. J.; Xu, D.; Kang, E. T.; Neoh, K. G. Self-doped conductive polymer-silicon hybrids from atom transfer radical graft copolymerization of sodium styrenesulfonate with polyaniline covalently tethered on the Si (100) surface J. Mater. Chem. 2004, 14, 2674
25. Xiao, D.; Wirth, M. J. Kinetics of surface-initiated atom transfer radical polymerization of acrylamide on silica Macromolecules 2002, 35, 2919
26. Mu, B.; Wang, T.; Liu, P. Well-defined dendritic-graft copolymer grafted silica nanoparticle by consecutive surface-initiated atom transfer radical polymerizations Ind. Eng. Chem. Res. 2007, 46, 3069
27. Paripovic, D.; Klok, H. A. Improving the stability in aqueous media of polymer brushes grafted from silicon oxide substrates by surface-initiated atom transfer radical polymerization Macromol. Chem. Phys. 2011, 212, 950
28. Lee, S. H.; Dreyer, D. R.; An, J.; Velamakanni, A.; Piner, R. D.; Park, S.; Zhu, Y.; Kim, S. O.; Bielawski, C. W.; Ruoff, R. S. Polymer brushes via controlled, surface-initiated atom transfer radical polymerization (ATRP) from graphene oxide Macromol. Rapid Commun. 2010, 31, 281
29. Baskaran, D.; Mays, J. W.; Bratcher, M. S. Polymer-grafted multiwalled carbon nanotubes through surface-initiated polymerization Angew. Chem., Int. Ed. 2004, 43, 2138
30. Liu, P.; Su, Z. Surface-initiated atom transfer radical polymerization (SI-ATRP) of MMA from PANI powders Polym. Bull. 2005, 55, 411
31. Liu, H.; Yi, J. Polystyrene/magnesium hydroxide nanocomposite particles prepared by surface-initiated in-situ polymerization Appl. Surf. Sci. 2009, 255, 5714
32. Liu, P.; Su, Z. Surface-initiated atom transfer radical polymerization (SI-ATRP) of n -butyl acrylate from starch granules Carb. Polym. 2005, 62, 159
33. Xu, F. J.; Zhao, J. P.; Kang, E. T.; Neoh, K. G. Surface functionalization of polyimide films via chloromethylation and surface-initiated atom transfer radical polymerization Ind. Eng. Chem. Res. 2007, 46, 4866
34. Liu, P.; Wang, T. Preparation of well-defined star polymer from hyperbranched macroinitiator based attapulgite by surface-initiated atom transfer radical polymerization technique Ind. Eng. Chem. Res. 2007, 46, 97
35. Zhang, F.; Xu, F. J.; Kang, E. T.; Neoh, K. G. Modification of titanium via surface-initiated atom transfer radical polymerization (ATRP) Ind. Eng. Chem. Res. 2006, 45, 3067
36. Haloi, D. J.; Singha, N. K. Synthesis of poly(2-ethylhexyl acrylate)/clay nanocomposite by in situ living radical polymerization J. Polym. Sci. Part A: Polym Chem. 2011, 49, 1564
37. Matyjaszewski, K.; Nakagawa, Y.; Jasieczek, C. B. Polymerization of n -butyl acrylate by atom transfer radical polymerization. Remarkable effect of ethylene carbonate and other solvents Macromolecules 1998, 31, 1535
38. Datta, H.; Singha, N. K. Atom transfer radical polymerization of hexyl acrylate: Preparation of all-acrylate block copolymer J Polym Sci Part A: Polym Chem. 2008, 46, 3499
39. Hamley, I. W. Nanostructure fabrication using block copolymers Nanotechnology 2003, 14, R39
40. Hamley, I. W. Block Copolymers; Oxford University Press: England, 1998.