Separation and recovery of copper, nickel, cobalt and zinc in chloride solutions by synergistic solvent extraction

Hydrometallurgy

Volumn 127-128, Issue , 2012, Pages 1-7

  Zhu, Z ^a   Zhang, W ^a   Pranolo, Y ^a   Cheng, C Y ^a  

^a CSIRO   (Australia)

Author keywords

Copper; LIX63; Nickel; Synergistic solvent extraction; Versatic 10

Indexed keywords

ALAMINE 336; CHLORIDE LEACH; CHLORIDE SOLUTIONS; INDUSTRIAL OPERATIONS; ION-EXCHANGE TECHNIQUES; LIX63; NICKEL ELECTROLYTES; NICKEL EXTRACTION; ORGANIC SOLUTIONS; PROCESS FLOW-SHEET; RAFFINATES; STRIPPING KINETICS; SULPHATES; SYNERGISTIC SOLVENT EXTRACTION; VERSATIC 10;

CALCIUM; CHLORINE COMPOUNDS; COBALT; COPPER; ELECTROWINNING; LEACHING; MANGANESE; SEPARATION; SOLVENT EXTRACTION; ZINC;

NICKEL;

EID: 84864029866     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2012.07.001     Document Type: Article

References (30)

1. J.G. Ahn, J.W. Ahn, K.H. Park, J.S. Sohn, and M.S. Lee Solvent extraction separation of nickel and cobalt by Alamine 336 from hydrochloric acid solutions Proceedings of International Symposium of Solvent Extraction (ISSE), Bhubaneswar, India, September 26-27, 2002 2002 65 70
2. A.H. Aprahamian, and G.P. Demopoulos The solution chemistry and solvent extraction behaviour or Cu, Fe, Ni, Zn, Pb, Sn, Ag, As, Sb, Bi, Se and Te in acid chloride solutions reviewed from the standpoint of PGM refining Miner. Process. Extr. Metall. Rev. 14 1995 143 167
3. W.G. Bacon, and I.O. Mihaylov Solvent extraction as an enabling technology in the nickel industry K.C. Sole, P.M. Cole, J.S. Preston, D.J. Robinson, Proceedings of International Solvent Extraction Conference (ISEC 2002) vol. 1 2002 Chris van Rensburg Publications (Pty) Ltd Cape Town, South Africa March 17-21, 2002 1 8
4. W.G. Bacon, D.F. Colton, I.O. Mihaylov, A. Singhal, A. Vahed, and J.P. Duterque Development of the Goro nickel process Proceedings of ALTA Nickel/Cobalt Conference, May 16-18, 2005 2005 ALTA Metallurgical Services Perth, Australia
5. K.R. Barnard, and M.D. Urbani The effect of organic acids on LIX63 stability under harsh strip conditions and isolation of a diketone degradation product Hydrometallurgy 89 2007 40 51
6. K.R. Barnard, G.L. Nealon, M.I. Ogden, and B.W. Skelton Crystallographic determination of three Ni-α-hydroxyoxime-carboxylic acid synergist complexes Solvent Extr. Ion Exch. 28 2010 778 792
7. C.Y. Cheng Purification of synthetic laterite leach solution by solvent extraction using D2EHPA Hydrometallurgy 56 2000 369 386
8. C.Y. Cheng Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime Hydrometallurgy 84 2006 109 117
9. Cheng, C.Y.; Urbani, M.D.; 2005. Solvent extraction process for separation cobalt and /or nickel from impurities in leach solutions. WO Patent No 2005/ 073416 A1.
10. C.Y. Cheng, G. Boddy, W. Zhang, M. Godfrey, D.J. Robinson, Y. Pranolo, Z. Zhu, and W. Wang Recovery of nickel and cobalt from laterite leach solutions using direct solvent extraction: part 1 - selection of a synergistic SX system Hydrometallurgy 104 2010 45 52
11. C.Y. Cheng, G. Boddy, W. Zhang, M. Godfrey, D.J. Robinson, Y. Pranolo, Z. Zhu, L. Zeng, and W. Wang Recovery of nickel and cobalt from laterite leach solutions using direct solvent extraction: part 2 - semi- and fully-continuous tests Hydrometallurgy 104 2010 53 60
12. G.P. Demopoulos, Z. Li, L. Becze, G. Moldoveanu, T.C. Cheng, and B. Harris New technologies for HCl regeneration in chloride hydrometallurgy Solvent Extr. Ion Exch. 61 2 2008 89 98
13. M. Filiz, N.A. Sayar, and A.A. Sayar Extraction of cobalt(II) from aqueous hydrochloric acid solutions into Alamine 336-m-xylene system Hydrometallurgy 81 2006 27 36
14. D.S. Flett, and D.W. West Extraction of metal ions by LIX63/carboxylic acid mixtures J.G. Gregory, B. Evans, P.C. Weston, Proceedings of International Solvent Extraction Conference, Vol. 1 ISEC 1971, The Hague, Netherlands, April 19-23, 1971 1971 Published by Society of Chemical Industry London 214 223 Paper 40
15. G.B. Harris, and C. White Recent developments in the high-strength chloride leaching of base metal sulphide ores ALTA Ni/Co 2008, Perth, WA, June 2008 2008
16. G.B. Harris, J. Magee, and R. Valls Beyond PAL: the Chesbar option, AAL ALTA Nickel/Cobalt 2003, Perth, Australia, May 2003 2003
17. Harris, G.B.; Lakshmanan, V. I.; Sridhar, R.; 2004. Process for the recovery of value metals from material containing base metal oxides. US Patent No 2004/0228783 A1.
18. G.B. Harris, C. White, M. Jansen, and D. Pursell New approach to the high concentration chloride leaching of nickel laterites ALTA Ni/Co 2006, Perth, WA, May 2006 2006
19. Jones, D.L.; 1996. Chloride assisted hydrometallurgical extraction of metal. WO Patent No 96/41026.
20. Krebs, D.; Hyvarinen, O.; Dreisinger, D.; 2007. Processing nickel sulphide ore or concentrates with sodium chloride. PCT WO 2007/039663 A1.
21. G. Kyuchoukov, and J. Szymanowski Extraction of copper(II) and zinc(II) from chloride media with mixed reagents J. Radioanal. Nucl. Chem. 246 3 2000 675 692
22. G. Kyuchoukov, S. Zhivkova, A. Borowiak-Resterna, and J. Szymanowski Separation of copper(II) and zinc(II) from chloride solutions with alkyl-8-hydroxyquinoline in various stages of extraction: stripping Ind. Eng. Chem. Res. 39 2000 3896 3900
23. P. Kyung-Ho, M. Debasish, and B.R. Reddy A study on the acidified ferric chloride leaching of a complex (Cu-Ni-Co-Fe) matte Sep. Purif. Technol. 2006 51 2006 332 337
24. C.W. McDonald, and N. Butt Solvent extraction studies of zinc with Alamine 336 in aqueous chloride and bromide media Sep. Sci. Technol. 13 1 1978 39 46
25. I. Mihaylov, E. Krause, D.F. Colton, Y. Okita, J.P. Duterque, and J.J. Perraud The development of a novel hydrometallurgical process for nickel and cobalt recovery from Goro laterite ore CIM Bull. 93 2000 124 130
26. G.C. Ritcey Solvent Extraction: Principles and Applications to Process Metallurgy, Vol. 2 2nd edition 2006 279 392
27. C. Ryszard, and S. Jan Copper extraction from chloride solution by solvating and chelating extractants Solvent Extr. Ion Exch. 19 3 2001 441 456
28. N.A. Sayar, M. Filiz, and A.A. Sayar Extraction of Zn(II) from aqueous acid solutions into Alamine 336-m-xylene system. Modelling considerations to predict optimum operational conditions Hydrometallurgy 86 2007 27 36
29. N.A. Sayar, M. Filiz, and A.A. Sayar Extraction of Co(II) and Ni(II) from concentrated HCl solutions using Alamine 336 Hydrometallurgy 96 2009 148 153
30. Z. Zhu, W. Zhang, and C.Y. Cheng A synergistic solvent extraction system for separating copper from iron in high chloride concentration solutions Hydrometallurgy 113-114 2012 155 159