Extraction of Co(II) and Ni(II) from concentrated HCl solutions using Alamine 336

Hydrometallurgy

Volumn 96, Issue 1-2, 2009, Pages 148-153

  Sayar, N A ^a   Filiz, M ^b   Sayar, A A ^c  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

^b KIRKLARELI UNIVERSITY   (Turkey)

^c MARMARA UNIVERSITY   (Turkey)

Author keywords

Alamine 336; Chloride media; Cobalt; Nickel; Solvent extraction

Indexed keywords

AMINES; AROMATIC HYDROCARBONS; CHLORINE COMPOUNDS; COBALT; EXTRACTIVE METALLURGY; HYDROCHLORIC ACID; METAL RECOVERY; NICKEL; NICKEL ALLOYS; SMELTING; SOLUTIONS; SOLVENT EXTRACTION; SOLVENTS; TRANSITION METALS; XYLENE;

ALAMINE 336; CHLORIDE MEDIA; LOADING FACTORS; METAL CONCENTRATIONS; SEPARATING AGENTS; SEPARATION FACTORS; SINGLE STAGES; SOLVENT MIXTURES; VOLUME PERCENTAGES;

EXTRACTION;

EID: 58149136402     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2008.09.005     Document Type: Article

References (35)

1. ® 301 binary extractant systems in cobalt/nickel recovery from acidic sulphate solutions. Hydrometallurgy 77 (2005) 203-218
2. Brunette J.P., Lakkis M., Goetz-Grandmont G., and Leroy M.J.F. Extraction of cobalt(II) and nickel(II) with mixtures of 1-phenyl-3-methyl-4-benzoyl-pyrazol-5-one (HPMBP) and tri-n-octylamine (TOA). Polyhedron 1 5 (1982) 461-466
3. Bryan S.E., and Good M.L. Extraction of group VIII metals by long chain alkyl amines-III. Liquid ion-exchange behaviour of the oxalate complexes of iron, cobalt and nickel. J. Inorg. Nucl. Chem. 21 (1961) 339-347
4. Burkin A.R., and Preston J.S. α-substituted oxime extractants-II. Extraction of Cu(II),Ni(II),Co(II) and Fe(II) by aliphatic α- hydroxyiminoketones and α-dioximes. J. Inorg. Nucl. Chem. 37 (1975) 2187-2195
5. Cheng C.Y. Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime. Hydrometallurgy 84 (2006) 109-117
6. Darvishi D., Haghshenas D.F., Alamdari E.K., Sadrnezhaad S.K., and Halali M. Synergistic effect of Cyanex 272 and Cyanex 302 on separation of cobalt and nickel by D2EHPA. Hydrometallurgy 77 (2005) 227-238
7. Devi N.B., Nathsarma K.C., and Chakravortty V. Separation and recovery of cobalt(II) and nickel(II) from sulphate solutions using sodium salts of D2EHPA, PC88A and Cyanex 272. Hydrometallurgy 49 (1998) 47-61
8. Dreisinger D.B., and Cooper C.W. The solvent extraction separation of cobalt and nickel using 2-ethyl-hexylphosphonic acid mono-2-ethylhexyl ester. Hydrometallurgy 12 (1984) 1-20
9. Filiz M., Sayar N.A., and Sayar A.A. Extraction of cobalt(II) from aqueous hydrochloric acid solutions into Alamine 336-m-xylene mixtures. Hydrometallurgy 81 (2006) 167-173
10. Gerhard N.I., Plant A.A., Petrova V.A., and Tagirov R.K. Solvent extraction of molybdenum (VI), tungsten (VI) and rhenium by diisododecylamine from leach liquors. Hydrometallurgy 60 (2001) 1-5
11. Lister M.W., and Rosenblum P. Some equilibrium constants of transition metal halides. Can. J. Chem. 38 (1960) 1827-1836
12. Moore G.E., and Kraus K.A. Anionic exchange studies. IV. Cobalt and nickel in hydrochloric acid solutions. J. Am. Chem. Soc. 74 3 (1952) 843-844
13. Nagaosa Y., and Binghua Y. Extraction equilibria of some transition metal ions by bis(2-ethylhexyl)phosphinic acid. Talanta 44 (1997) 327-337
14. Osseo-Asare K., and Renninger D.R. Synergic extraction of nickel and cobalt by LIX 63-dinonylnaphthalene sulfonic acid mixtures. Hydrometallurgy 13 (1984) 45-62
15. Owusu G. Selective extractions of Zn and Cd from Zn-Cd-Co-Ni sulphate solution using di-2-ethylhexyl phosphoric acid extractant. Hydrometallurgy 47 (1998) 205-215
16. Park K.H., Reddy B.R., Junk S.H., and Mohapatra D. Transfer of cobalt and nickel from sulphate solutions to spent electrolyte through solvent extraction and stripping. Sep. Purif. Technol. 51 (2006) 265-271
17. Plant A.A., Iatsenko N.A., and Petrova V.A. Solvent extraction of molybdenum (VI) by diisododecylamine from sulphuric acid solution. Hydrometallurgy 48 (1998) 83-90
18. Preston J.S. Alpha- substituted oxime extractants-I. Extraction of Cu(II),Ni(II),Co(II) and Fe(III) by aliphatic alpha-hydroxyoximes. J. Inorg. Nucl. Chem. 37 (1975) 1235-1242
19. Preston J.S. Solvent extraction of cobalt and nickel by organophosphorus acids. I. Comparison of phosphoric, phosphonic and phosphinic acid systems. Hydrometallurgy 9 (1982) 115-133
20. Przeszlakowski S., and Wydra H. Extraction of nickel, cobalt and other metals [Cu,Zn,Fe(III) ] with a commercial β-diketone extractant. Hydrometallurgy 8 (1982) 49-64
21. Reddy B.R., Priya D.N., Rao S.V., and Radhika P. Solvent extraction and separation of Cd(II), Ni(II) and Co(II) from chloride leach liquors of spent Ni-Cd batteries using commercial organophosphorus extractants. Hydrometallurgy 77 (2005) 253-261
22. Rice N.M., and Nedved M. The extraction of nickel from ammoniacal media and its separation from copper, cobalt and zinc using hydroxyoxime extractants. Hydrometallurgy 3 (1978) 35-54
23. Ritcey, G.M., Lucas, B.H., 1974. Some aspects of the extraction of metal from acidic solutions by kelex 100. CIM Bulletin, February, 87-92.
24. Ritcey, G.M., Ashbrook, A.W., Lucas, B.H., 1975. Development of a solvent extraction process for the separation of cobalt from nickel. CIM Bulletin, January, 111-123.
25. Saji J., Rao T.P., Iyer C.S.P., and Reddy M.L.P. Extraction of iron (III) from acidic chloride solutions by Cyanex 923. Hydrometallurgy 49 (1998) 289-296
26. Sarangi K., Reddy B.R., and Das R.P. Extraction studies of cobalt(II) and nickel(II) from chloride solutions using Na-Cyanex 272. Separation of Co(II)/Ni(II) by sodium salts of D2EHPA, PC-88A and Cyanex 272 and their mixtures. Hydrometallurgy 52 (1999) 253-265
27. Sayar N.A., Filiz M., and Sayar A.A. Extraction of Zn(II) from aqueous hydrochloric acid solutions into Alamine 336 m-xylene systems. Modelling considerations to predict optimum operational conditions. Hydrometallurgy 86 (2007) 27-36
28. Sayar N.A., Sayar A.A., and Filiz M. Simulation- and optimisation-oriented modelling considerations for the extraction of Ni(II) from its acidic aqueous chloride solutions into Alamine 336-m-xylene system. Hydrometallurgy (2008) 10.1016/j.hydromet.2008.06.11
29. Tait B.K. Cobalt-nickel separation: the extraction of cobalt(II) and nickel(II) by Cyanex 301, Cyanex 302 and Cyanex 272. Hydrometallurgy 32 (1993) 365-372
30. Thakur N.V. Extraction studies of base metals (Mn,Cu,Co and Ni) using the extractant 2-ethylhexyl 2-ethylhexyl phosphonic acid, PC-88A. Hydrometallurgy 48 (1998) 125-131
31. Tsakiridis P.E., and Agatzini S.L. Simultaneous solvent extraction of cobalt and nickel in the presence manganese and magnesium from sulphate solutions by Cyanex 301. Hydrometallurgy 72 (2004) 269-278
32. Tsakiridis P.E., and Leonardou S.A. Process for the recovery of cobalt and nickel in the presence of magnesium from sulphate solutions by Cyanex 272 and Cyanex 302. Miner. Eng. 17 (2004) 913-923
33. Ulusoy E., and Sayar A.A. Extraction of ferric cations from aqueous HCl media into xylene-Alamine 336 system. Chim. Acta Turc. 3 (1984) 531-541
34. Yoshizuka K., Sakomoto Y., Baba Y., and Inoue K. Distribution equilibria in the adsorption of cobalt(II) and nickel(II) on levextrel resin containing cyanex 272. Hydrometallurgy 23 (1990) 309-318
35. Zhou T., and Pesic B. A pyridine-based chelating solvent extraction system for selective extraction of nickel and cobalt. Hydrometallurgy 46 (1997) 37-53