Rate analysis of chemical-looping with oxygen uncoupling (CLOU) for solid fuels

Energy and Fuels

Volumn 26, Issue 7, 2012, Pages 4395-4404

  Sahir, Asad H ^a   Sohn, Hong Yong ^b   Leion, Henrik ^c   Lighty, Joann S ^a  

^a Department of Electrical and Computer Engineering   (United States)

^b UNIVERSITY OF UTAH   (United States)

^c CHALMERS UNIVERSITY OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ANALYSIS; COPPER OXIDES; DECOMPOSITION; FLUIDIZED BED COMBUSTION; FLUIDIZED BEDS; METALS; OXIDE MINERALS; OXYGEN;

CHEMICAL LOOPING; CHEMICAL-LOOPING COMBUSTION; COMBUSTION OF SOLID FUELS; ENERGY PENALTIES; GASEOUS OXYGEN; GASIFICATION REACTION; PRIMARY MECHANISM; PROCESS MODELING;

FUELS;

EID: 84863963825     PISSN: 08870624     EISSN: 15205029     Source Type: Journal    
DOI: 10.1021/ef300452p     Document Type: Article

References (28)

1. Adanez, J.; Abad, A.; Garcia-Labiano, F.; Gayan, P.; de Diego, L. F. Progress in Chemical-Looping Combustion and Reforming Technologies Prog. Energy Combust. Sci. 2012, 38 (2) 215-282
2. Fan, L. S., Chemical Looping Systems for Fossil Energy Conversions; Wiley-AIChE: Hoboken, NJ, 2010.
3. Moghtaderi, B. Review of the Recent Chemical Looping Process Developments for Novel Energy and Fuel Applications Energy Fuels 2011, 26 (1) 15-40
4. Mattisson, T.; Lyngfelt, A.; Leion, H. Chemical-Looping with Oxygen Uncoupling for Combustion of Solid Fuels Int. J. Greenhouse Gas Control 2009, 3 (1) 11-19
5. 2 with Petroleum Coke Fuel 2009, 88 (4) 683-690
6. Leion, H.; Mattisson, T.; Lyngfelt, A. Using Chemical-Looping with Oxygen Uncoupling (CLOU) for Combustion of Six Different Solid Fuels Energy Procedia 2009, 1 (1) 447-453
7. Eyring, E. M.; Konya, G.; Lighty, J. S.; Sahir, A. H.; Sarofim, A. F.; Whitty, K. Chemical Looping with Copper Oxide as Carrier and Coal as Fuel Oil Gas Sci. Technol. Rev. IFP Energies nouvelles 2011, 66 (2) 209-221
8. 4-Supported CuO Oxygen Carriers in Chemical-Looping Combustion (CLC) and Chemical-Looping with Oxygen Uncoupling (CLOU) Energy Fuels 2011, 25 (11) 5493-5502
9. Adanez-Rubio, I.; Gayan, P.; Garcia-Labiano, F.; De Diego, L. F.; Adanez, J.; Abad, A. Development of CuO-Based Oxygen-Carrier Materials Suitable for Chemical-Looping with Oxygen Uncoupling (CLOU) process Energy Proc. 2011, 4, 417-424
10. th Continuously Operating Unit Using a Cu-Based Oxygen Carrier Int. J. Greenhouse Gas Control 2012, 6, 189-200
11. Leion, H.; Mattisson, T.; Lyngfelt, A. The Use of Petroleum Coke As Fuel in Chemical-Looping Combustion Fuel 2007, 86 (12-13) 1947-1958
12. 2O to CuO at 600-1050°C Oxid. Met. 2004, 62 (3-4) 207-222
13. Prisedsky, V. V.; Vinogradov, V. M. Fragmentation of Diffusion Zone in High-Temperature Oxidation of Copper J. Solid State Chem. 2004, 177 (11) 4258-4268
14. Sohn, H. Y. The Law of Additive Reaction Times in Fluid-Solid Reactions Metall. Trans. B 1978, 9 (1) 89-96
15. Sohn, H. Y.; Szekely, J. A Structural Model for Gas-Solid Reactions with a Moving Boundary-III. A General Dimensionless Representation of the Irreversible Reaction between a Porous Solid and a Reactant Gas Chem. Eng. Sci. 1972, 27 (4) 763-778
16. Szekely, J.; Evans, J. W.; Sohn, H. Y. Gas-Solid Reactions; Academic Press: New York, 1976.
17. Sohn, H. The Influence of Chemical Equilibrium on Fluid-Solid Reaction Rates and the Falsification of Activation Energy Metall. Mater. Trans. B 2004, 35 (1) 121-131
18. Sohn, H. Y.; Emami, S. Kinetics of Dehydrogenation of the Mg-Ti-H Hydrogen Storage System Int. J. Hydrogen Energy 2011, 36 (14) 8344-8350
19. Pankratz, L. B. Thermodynamic Properties of Elements and Oxides-Bulletin 672; U.S. Department of the Interior, Bureau of Mines: Washington, DC, 1982.
20. 2O Int. J. Energy Res. 1989, 13 (1) 63-73
21. Sohn, H. Y. The Effects of Reactant Starvation and Mass Transfer in the Rate Measurement of Fluid-Solid Reactions with Small Equilibrium Constants Chem. Eng. Sci. 2004, 59 (20) 4361-4368
22. Sahir, A. H.; Lighty, J. S.; Sohn, H. Y. Kinetics of Copper Oxidation in the Air Reactor of a Chemical Looping Combustion System Using the Law of Additive Reaction Times Ind. Eng. Chem. Res. 2011, 50 (23) 13330-13339
23. Sohn, H. Y.; Sohn, H. J. The Effect of Bulk Flow Due to Volume Change in the Gas Phase on Gas-Solid Reactions: Initially Nonporous Solids Ind. Eng. Chem. Process Des. Dev. 1980, 19 (2) 237-242
24. Hurt, R. H.; Mitchell, R. E. Unified High-Temperature Char Combustion Kinetics for a Suite of Coals of Various Rank Symp. (Int.) Combust. 1992, 24 (1) 1243-1250
25. Wang, H. Reduction Kinetics of Iron Ore Concentrate Particles Relevant to a Novel Green Ironmaking Process. Ph.D. Dissertation, University of Utah, Salt Lake City, UT, 2011.
26. Wang, H.; Sohn, H. Y. Complete Rate Expression for the Hydrogen Reduction of Iron Ore Concentrate Relevant to a Novel Ironmaking Process, Metall. Mater. Trans. B 2012, submitted for publication.
27. Smith, K. L.; Smoot, L. D.; Fletcher, T. H.; Pugmire, R. J. The Structure and Reaction Processes of Coal; Plenum Press: New York, 1994.
28. Marín-Sánchez, J. E.; Rodríguez-Toral, M. A. An Estimation of Cogeneration Potential by Using Refinery Residuals in Mexico Energy Policy 2007, 35 (11) 5876-5891