Quantitative localized proton-promoted dissolution kinetics of calcite using scanning electrochemical microscopy (SECM)

Journal of Physical Chemistry C

Volumn 116, Issue 28, 2012, Pages 14892-14899

  McGeouch, Carrie Anne ^a   Peruffo, Massimo ^a   Edwards, Martin A ^a,b   Bindley, Lucy A ^a   Lazenby, Robert A ^a   Mbogoro, Michael M ^a   McKelvey, Kim ^a,b   Unwin, Patrick R ^a  

^a UNIVERSITY OF WARWICK   (United Kingdom)

^b UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CALCITE DISSOLUTION; CHEMICAL SPECIES; CLEAVAGE SURFACES; CRYSTAL SURFACES; DISSOLUTION KINETICS; ETCH PITS; FINITE ELEMENT MODELS; FIRST ORDER; ICELANDS; INTERFACIAL CONCENTRATIONS; INTERFACIAL FLUXES; KEY REACTIONS; LOCAL MEASUREMENT; MICROSCOPIC SCALE; MOVING BOUNDARIES; PROBE SIZE; PROTON CONCENTRATIONS; PROTON FLUX; PT-DISK; RATE CONSTANT K; RATE MEASUREMENTS; SCANNING ELECTROCHEMICAL MICROSCOPY; TIME-DEPENDENT; ULTRAMICROELECTRODES; WHITE-LIGHT INTERFEROMETRY;

ANALYTIC EQUIPMENT; CALCITE; DISLOCATIONS (CRYSTALS); DISSOLUTION; KINETICS; MICROELECTRODES; MIRRORS; PLATINUM; POINT DEFECTS; RATE CONSTANTS; SCANNING ELECTRON MICROSCOPY; SCANNING PROBE MICROSCOPY; SURFACE DEFECTS;

PROTONS;

EID: 84863909563     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp301382e     Document Type: Article

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