Ligand-site exchange in intramolecular complexes of silicon: Substituent effects

Journal of Physical Organic Chemistry

Volumn 25, Issue 8, 2012, Pages 658-666

  Kuznetsova, Olga V ^a   Egorochkin, Alexey N ^a   Negrebetsky, Vadim V ^b   Khamaletdinova, Nadiya M ^a   Domratcheva Lvova, Lada G ^c  

^a G A RAZUVAEV INSTITUTE OF ORGANOMETALLIC CHEMISTRY   (Russian Federation)

^b PIROGOV RUSSIAN NATIONAL RESEARCH MEDICAL UNIVERSITY   (Russian Federation)

^c UNIVERSIDAD MICHOACANA DE SAN NICOLÁS DE HIDALGO   (Mexico)

Author keywords

hypervalent silicon compounds; ligand site exchange; linear free energy relationships; substituent effects

Indexed keywords

COORDINATION BONDS; CORRELATION ANALYSIS; DONOR CENTERS; HYPERVALENT SILICON COMPOUNDS; INTERCONVERSIONS; INTRAMOLECULAR COMPLEXES; INTRAMOLECULAR COORDINATION; LIGAND EXCHANGES; LIGAND-SITE EXCHANGE; LINEAR FREE ENERGY RELATIONSHIPS; LITERATURE DATA; NON-RIGIDITY; NUCLEOPHILIC SUBSTITUTIONS; ORGANOELEMENT COMPOUNDS; POLARIZABILITIES; POLARIZABILITY EFFECTS; RESONANCE EFFECT; SI ATOMS; SILICON ATOMS; STERIC EFFECT; SUBSTITUENT EFFECT;

ATOMS; CHARGE TRANSFER; FREE ENERGY; ISOMERS; LIGANDS; POLARIZATION; SILICON COMPOUNDS;

SILICON;

EID: 84863833847     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1958     Document Type: Article

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