Synthesis, structure and dynamic stereochemistry of (O → Si)-chelate N-(trifluorosilylmethyl)-[N-(S)-(1-phenylethyl)]acetamide and 1-(trifluorosilylmethyl)-2-oxoperhydroazepine: Retention of the O → Si coordination in the adduct with KF and 18-crown-6

Journal of Organometallic Chemistry

Volumn 693, Issue 7, 2008, Pages 1309-1320

  Negrebetsky, Vadim V ^a   Taylor, Peter G ^b   Kramarova, Evgeniya P ^a   Shipov, Aleksander G ^a   Pogozhikh, Sergey A ^c   Ovchinnikov, Yuri E ^c   Korlyukov, Alexander A ^d   Bowden, Allen ^b   Bassindale, Alan R ^b   Baukov, Yuri I ^a  

^a PIROGOV RUSSIAN NATIONAL RESEARCH MEDICAL UNIVERSITY   (Russian Federation)

^b OPEN UNIVERSITY   (United Kingdom)

^c A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^d NOVOSIBIRSK STATE PEDAGOGICAL UNIVERSITY   (Russian Federation)

Author keywords

Dynamic NMR; Hexacoordination; Pentacoordination; Quantum chemical calculations; Stereochemical non rigidity; X ray diffraction study

Indexed keywords

HYDROLYSIS; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS (CHEMICAL);

HEXACOORDINATION; PENTACOORDINATION; QUANTUM-CHEMICAL CALCULATIONS; STEREOCHEMICAL NON-RIGIDITY; X-RAY DIFFRACTION STUDY;

STEREOCHEMISTRY;

EID: 40649098550     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.01.033     Document Type: Article

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