메뉴 건너뛰기




Volumn 3, Issue 12, 2012, Pages 1644-1648

Non-ergodic electron transfer in mixed-valence charge-transfer complexes

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; ARRHENIUS; BOLTZMANN FACTORS; CHARGE TRANSFER COMPLEX; ELECTRON TRANSFER; ERGODICITY; FREQUENCY FACTORS; FUNCTIONAL FORMS; MIXED VALENCE; RATE INCREASE; RELAXATION FREQUENCY; SELF-EXCHANGE; SOLVENT RELAXATION; TEMPERATURE DEPENDENCE; THERMAL BATH;

EID: 84863673996     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz300630t     Document Type: Article
Times cited : (8)

References (38)
  • 2
    • 34547275473 scopus 로고
    • Brownian motion in a field of force and the diffusion model of chemical reactions
    • Kramers, H. A. Brownian Motion in a Field of Force and the Diffusion Model of Chemical Reactions. Physica 1940, 7, 284-304.
    • (1940) Physica , vol.7 , pp. 284-304
    • Kramers, H.A.1
  • 3
    • 7044277745 scopus 로고
    • Broken ergodicity
    • Palmer, R. G. Broken Ergodicity. Adv. Phys. 1982, 31, 669-735.
    • (1982) Adv. Phys. , vol.31 , pp. 669-735
    • Palmer, R.G.1
  • 5
    • 0001540218 scopus 로고
    • Relaxation processes and chemical kinetics
    • Skinner, J. L.; Wolynes, P. G. Relaxation Processes and Chemical Kinetics. J. Chem. Phys. 1978, 69, 2143-2150.
    • (1978) J. Chem. Phys. , vol.69 , pp. 2143-2150
    • Skinner, J.L.1    Wolynes, P.G.2
  • 6
    • 33748274620 scopus 로고
    • Nonequilibrium solvation dynamics in solution reactions
    • van der Zwan, G.; Hynes, J. T. Nonequilibrium Solvation Dynamics in Solution Reactions. J. Chem. Phys. 1983, 78, 4174-4185.
    • (1983) J. Chem. Phys. , vol.78 , pp. 4174-4185
    • Van Der Zwan, G.1    Hynes, J.T.2
  • 7
    • 33847079599 scopus 로고
    • Dynamical effects in electron transfer reactions
    • Sumi, H.; Marcus, R. A. Dynamical Effects in Electron Transfer Reactions. J. Chem. Phys. 1986, 84, 4894-4914.
    • (1986) J. Chem. Phys. , vol.84 , pp. 4894-4914
    • Sumi, H.1    Marcus, R.A.2
  • 8
    • 0013610799 scopus 로고
    • Dynamic solvent effects on outer-sphere electron transfer
    • Rips, I.; Jortner, J. Dynamic Solvent Effects on Outer-Sphere Electron Transfer. J. Chem. Phys. 1987, 87, 2090-2104.
    • (1987) J. Chem. Phys. , vol.87 , pp. 2090-2104
    • Rips, I.1    Jortner, J.2
  • 9
    • 0040727620 scopus 로고    scopus 로고
    • Interplay between ultrafast polar solvation and vibrational dynamics in electron transfer reactions: Role of the high-frequency vibrational modes
    • Bagchi, B.; Gayathri, N. Interplay between Ultrafast Polar Solvation and Vibrational Dynamics in Electron Transfer Reactions: Role of the High-Frequency Vibrational Modes. Adv. Chem. Phys. 1999, 107, 1-80.
    • (1999) Adv. Chem. Phys. , vol.107 , pp. 1-80
    • Bagchi, B.1    Gayathri, N.2
  • 10
    • 65149103659 scopus 로고    scopus 로고
    • Nonergodic activated kinetics in polar media
    • Matyushov, D. V. Nonergodic Activated Kinetics in Polar Media. J. Chem. Phys. 2009, 130, 164522.
    • (2009) J. Chem. Phys. , vol.130 , pp. 164522
    • Matyushov, D.V.1
  • 11
    • 33746346173 scopus 로고    scopus 로고
    • Dynamical arrest of electron transfer in liquid crystalline solvents
    • Kapko, V.; Matyushov, D. V. Dynamical Arrest of Electron Transfer in Liquid Crystalline Solvents. J. Phys. Chem. B 2006, 110, 13184-13194.
    • (2006) J. Phys. Chem. B , vol.110 , pp. 13184-13194
    • Kapko, V.1    Matyushov, D.V.2
  • 12
    • 0010884753 scopus 로고
    • On the theory of oxidation-reduction reactions involving electron transfer. I
    • Marcus, R. A. On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I. J. Chem. Phys. 1956, 24, 966-978.
    • (1956) J. Chem. Phys. , vol.24 , pp. 966-978
    • Marcus, R.A.1
  • 13
    • 0030218268 scopus 로고    scopus 로고
    • Contemporary issues in electron transfer research
    • Barbara, P. F.; Meyer, T. J.; Ratner, M. A. Contemporary Issues in Electron Transfer Research. J. Phys. Chem. 1996, 100, 13148-13168.
    • (1996) J. Phys. Chem. , vol.100 , pp. 13148-13168
    • Barbara, P.F.1    Meyer, T.J.2    Ratner, M.A.3
  • 14
    • 84962436329 scopus 로고    scopus 로고
    • Control of electron transfer kinetics: Models for medium reorganization and donor-acceptor coupling
    • Newton, M. D. Control of Electron Transfer Kinetics: Models for Medium Reorganization and Donor-Acceptor Coupling. Adv. Chem. Phys. 1999, 106, 303-375.
    • (1999) Adv. Chem. Phys. , vol.106 , pp. 303-375
    • Newton, M.D.1
  • 15
    • 85022816016 scopus 로고
    • Outer-sphere electron transfer in polar solvents
    • Zusman, L. D. Outer-Sphere Electron Transfer in Polar Solvents. Chem. Phys. 1980, 49, 295-304.
    • (1980) Chem. Phys. , vol.49 , pp. 295-304
    • Zusman, L.D.1
  • 16
    • 0011526199 scopus 로고    scopus 로고
    • Electron transfer - From isolated molecules to biomolecules
    • Bixon, M.; Jortner, J. Electron Transfer - from Isolated Molecules to Biomolecules. Adv. Chem. Phys. 1999, 106, 35-202.
    • (1999) Adv. Chem. Phys. , vol.106 , pp. 35-202
    • Bixon, M.1    Jortner, J.2
  • 17
    • 0039932944 scopus 로고
    • Reorganization energy of electron transfer in polar liquids: Dependence on the reactant size, temperature, and pressure
    • Matyushov, D. V. Reorganization Energy of Electron Transfer in Polar Liquids: Dependence on the Reactant Size, Temperature, And Pressure. Chem. Phys. 1993, 174, 199-218.
    • (1993) Chem. Phys. , vol.174 , pp. 199-218
    • Matyushov, D.V.1
  • 18
    • 33746892603 scopus 로고    scopus 로고
    • Solvent reorganization entropy of electron transfer in polar solvents
    • Ghorai, P. K.; Matyushov, D. V. Solvent Reorganization Entropy of Electron Transfer in Polar Solvents. J. Phys. Chem. A 2006, 110, 8857-8863.
    • (2006) J. Phys. Chem. A , vol.110 , pp. 8857-8863
    • Ghorai, P.K.1    Matyushov, D.V.2
  • 19
    • 0000760120 scopus 로고    scopus 로고
    • A failure of continuum theory: Temperature dependence of the solvent reorganization energy of electron transfer in highly polar solvents
    • Vath, P.; Zimmt, M. B.; Matyushov, D. V.; Voth, G. A. A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents. J. Phys. Chem. B 1999, 103, 9130-9140.
    • (1999) J. Phys. Chem. B , vol.103 , pp. 9130-9140
    • Vath, P.1    Zimmt, M.B.2    Matyushov, D.V.3    Voth, G.A.4
  • 20
    • 33646263349 scopus 로고    scopus 로고
    • Activation entropy of electron transfer reactions
    • Milischuk, A. A.; Matyushov, D. V.; Newton, M. D. Activation Entropy of Electron Transfer Reactions. Chem. Phys. 2006, 324, 172-194.
    • (2006) Chem. Phys. , vol.324 , pp. 172-194
    • Milischuk, A.A.1    Matyushov, D.V.2    Newton, M.D.3
  • 21
    • 39049112900 scopus 로고    scopus 로고
    • Electron transfer at the class II/III borderline of mixed valency: Dependence of rates on solvent dynamics and observation of a localized-to-delocalized transition in freezing solvents
    • Glover, S. D.; Lear, B. J.; Salsman, J. C.; Londergan, C. H.; Kubiak, C. P. Electron Transfer at the Class II/III Borderline of Mixed Valency: Dependence of Rates on Solvent Dynamics and Observation of a Localized-to-Delocalized Transition in Freezing Solvents. Philos. Trans. R. Soc., A 2008, 366, 177-185.
    • (2008) Philos. Trans. R. Soc., A , vol.366 , pp. 177-185
    • Glover, S.D.1    Lear, B.J.2    Salsman, J.C.3    Londergan, C.H.4    Kubiak, C.P.5
  • 22
    • 79957981419 scopus 로고    scopus 로고
    • Persistence of the three-state description of mixed valency at the localization-to-delocalization transition
    • Glover, S. D.; Kubiak, C. P. Persistence of the Three-State Description of Mixed Valency at the Localization-to-Delocalization Transition. J. Am. Chem. Soc. 2011, 133, 8721-8731.
    • (2011) J. Am. Chem. Soc. , vol.133 , pp. 8721-8731
    • Glover, S.D.1    Kubiak, C.P.2
  • 23
    • 0035470233 scopus 로고    scopus 로고
    • The localizedto-delocalized transition in mixed-valence chemistry
    • Demadis, K. D.; Hartshorn, C. M.; Meyer, T. J. The Localizedto- Delocalized Transition in Mixed-Valence Chemistry. Chem. Rev. 2001, 101, 2655-2686.
    • (2001) Chem. Rev. , vol.101 , pp. 2655-2686
    • Demadis, K.D.1    Hartshorn, C.M.2    Meyer, T.J.3
  • 24
    • 0000776899 scopus 로고
    • Intervalence-transfer absorption. Part 2. Theoretical considerations and spectroscopic data
    • Hush, N. Intervalence-Transfer Absorption. Part 2. Theoretical Considerations and Spectroscopic Data. Prog. Inorg. Chem. 1967, 8, 391-444.
    • (1967) Prog. Inorg. Chem. , vol.8 , pp. 391-444
    • Hush, N.1
  • 25
    • 28444444500 scopus 로고    scopus 로고
    • Dynamical arrest of electron transfer reorganization in supercooled water
    • Ghorai, P. K.; Matyushov, D. V. Dynamical Arrest of Electron Transfer Reorganization in Supercooled Water. J. Am. Chem. Soc. 2005, 127, 16390-16391.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 16390-16391
    • Ghorai, P.K.1    Matyushov, D.V.2
  • 26
    • 32644451777 scopus 로고    scopus 로고
    • Solvent reorganization energy in solvents above the glass transition
    • Ghorai, P. K.; Matyushov, D. V. Solvent Reorganization Energy in Solvents above the Glass Transition. J. Phys. Chem. B 2006, 110, 1866-1871.
    • (2006) J. Phys. Chem. B , vol.110 , pp. 1866-1871
    • Ghorai, P.K.1    Matyushov, D.V.2
  • 27
    • 34248339214 scopus 로고    scopus 로고
    • Energetics of electron transfer reactions in soft condensed media
    • Matyushov, D. V. Energetics of Electron Transfer Reactions in Soft Condensed Media. Acc. Chem. Res. 2007, 40, 294-301.
    • (2007) Acc. Chem. Res. , vol.40 , pp. 294-301
    • Matyushov, D.V.1
  • 28
    • 0029403121 scopus 로고
    • Subpicosecond measurements of polar solvation dynamics: Coumarin-153 revisited
    • Horng, M. L.; Gardecki, J. A.; Papazyan, A.; Maroncelli, M. Subpicosecond Measurements of Polar Solvation Dynamics: Coumarin-153 Revisited. J. Phys. Chem. 1995, 99, 17311-17337.
    • (1995) J. Phys. Chem. , vol.99 , pp. 17311-17337
    • Horng, M.L.1    Gardecki, J.A.2    Papazyan, A.3    Maroncelli, M.4
  • 29
    • 0003092065 scopus 로고
    • Collective orientational relaxation in dense dipolar liquids
    • Bagchi, B.; Chandra, A. Collective Orientational Relaxation in Dense Dipolar Liquids. Adv. Chem. Phys. 1991, 80, 1-126.
    • (1991) Adv. Chem. Phys. , vol.80 , pp. 1-126
    • Bagchi, B.1    Chandra, A.2
  • 31
    • 0009071257 scopus 로고
    • Formation of glasses from liquids and biopolymers
    • Angell, C. A. Formation of Glasses from Liquids and Biopolymers. Science 1995, 267, 1924-1935.
    • (1995) Science , vol.267 , pp. 1924-1935
    • Angell, C.A.1
  • 32
    • 0001309564 scopus 로고    scopus 로고
    • Electron transfer in frozen media
    • Chen, P.; Meyer, T. J. Electron Transfer in Frozen Media. Inorg. Chem. 1996, 35, 5520-5524.
    • (1996) Inorg. Chem. , vol.35 , pp. 5520-5524
    • Chen, P.1    Meyer, T.J.2
  • 33
    • 0001625289 scopus 로고    scopus 로고
    • Medium effects on charge transfer in metal complexes
    • Chen, P.; Meyer, T. J. Medium Effects on Charge Transfer in Metal Complexes. Chem. Rev. 1998, 98, 1439-1477.
    • (1998) Chem. Rev. , vol.98 , pp. 1439-1477
    • Chen, P.1    Meyer, T.J.2
  • 34
    • 33749354315 scopus 로고    scopus 로고
    • Colloquium: The glass transition and elastic models of glass-forming liquids
    • Dyre, J. C. Colloquium: The Glass Transition and Elastic Models of Glass-Forming Liquids. Rev. Mod. Phys. 2006, 78, 953-972.
    • (2006) Rev. Mod. Phys. , vol.78 , pp. 953-972
    • Dyre, J.C.1
  • 36
    • 0000101233 scopus 로고    scopus 로고
    • Molecular mechanism of capillary condensation of acetonitrile vapor on Mcm-41 with the aid of a time-correlation function analysis of IR spectroscopy
    • Tanaka, H.; Iiyama, T.; Uekawa, N.; Suzuki, T.; Matsumoto, A.; Grün, M.; Unger, K. K.; Kaneko, K. Molecular Mechanism of Capillary Condensation of Acetonitrile Vapor on Mcm-41 with the Aid of a Time-Correlation Function Analysis of IR Spectroscopy. Chem. Phys. Lett. 1998, 293, 541-546.
    • (1998) Chem. Phys. Lett. , vol.293 , pp. 541-546
    • Tanaka, H.1    Iiyama, T.2    Uekawa, N.3    Suzuki, T.4    Matsumoto, A.5    Grün, M.6    Unger, K.K.7    Kaneko, K.8
  • 38
    • 0033409037 scopus 로고    scopus 로고
    • Energy surfaces, reorganization energies, and coupling elements in electron transfer
    • Brunschwig, B. S.; Sutin, N. Energy Surfaces, Reorganization Energies, and Coupling Elements in Electron Transfer. Coord. Chem. Rev. 1999, 187, 233-254.
    • (1999) Coord. Chem. Rev. , vol.187 , pp. 233-254
    • Brunschwig, B.S.1    Sutin, N.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.