메뉴 건너뛰기




Volumn 37, Issue 15, 2012, Pages 11185-11194

Comparison of ethanol electro-oxidation on Pt/C and Pd/C catalysts in alkaline media

Author keywords

Alkaline media; Carbon supported Pd; Carbon supported Pt; Ethanol electro oxidation; Mechanism; Temperature

Indexed keywords

ALKALINE MEDIA; APPARENT ACTIVATION ENERGY; C-C BONDS; ETHANOL ELECTRO-OXIDATION; ETHANOL OXIDATION; HIGH TEMPERATURE; OVER POTENTIAL; PD/C CATALYST; POISONING EFFECTS; POTENTIODYNAMICS; POTENTIOSTATIC MEASUREMENTS; POTENTIOSTATIC METHODS; SELECTIVE OXIDATION; TAFEL SLOPES;

EID: 84863610405     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.04.132     Document Type: Article
Times cited : (206)

References (50)
  • 1
    • 0029546381 scopus 로고
    • Evaluation of ethanol, 1-propanol, and 2-propanol in a direct oxidation polymer-electrolyte fuel cell
    • J. Wang, S. Wasmus, and R.F. Savinell Evaluation of ethanol, 1-propanol, and 2-propanol in a direct oxidation polymer-electrolyte fuel cell Journal of the Electrochemical Society 142 1995 4218 4224
    • (1995) Journal of the Electrochemical Society , vol.142 , pp. 4218-4224
    • Wang, J.1    Wasmus, S.2    Savinell, R.F.3
  • 2
    • 0035394865 scopus 로고    scopus 로고
    • Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC)
    • C. Lamy, E.M. Belgsir, and J.M. Léger Electrocatalytic oxidation of aliphatic alcohols: application to the direct alcohol fuel cell (DAFC) Journal of Applied Electrochemistry 31 2001 799 809
    • (2001) Journal of Applied Electrochemistry , vol.31 , pp. 799-809
    • Lamy, C.1    Belgsir, E.M.2    Léger, J.M.3
  • 4
    • 34249309227 scopus 로고    scopus 로고
    • Catalysts for direct ethanol fuel cells
    • E. Antolini Catalysts for direct ethanol fuel cells Journal of Power Sources 170 2007 1 12
    • (2007) Journal of Power Sources , vol.170 , pp. 1-12
    • Antolini, E.1
  • 5
    • 56649085080 scopus 로고    scopus 로고
    • Preparation of alkaline anion exchange membranes based on functional poly(ether-imide) polymers for potential fuel cell applications
    • G. Wang, Y. Weng, D. Chu, D. Xie, and R. Chen Preparation of alkaline anion exchange membranes based on functional poly(ether-imide) polymers for potential fuel cell applications Journal of Membrane Science 326 2009 4 8
    • (2009) Journal of Membrane Science , vol.326 , pp. 4-8
    • Wang, G.1    Weng, Y.2    Chu, D.3    Xie, D.4    Chen, R.5
  • 6
    • 62649100634 scopus 로고    scopus 로고
    • Developing a polysulfone-based alkaline anion exchange membrane for improved ionic conductivity
    • G. Wang, Y. Weng, D. Chu, R. Chen, and D. Xie Developing a polysulfone-based alkaline anion exchange membrane for improved ionic conductivity Journal of Membrane Science 332 2009 63 68
    • (2009) Journal of Membrane Science , vol.332 , pp. 63-68
    • Wang, G.1    Weng, Y.2    Chu, D.3    Chen, R.4    Xie, D.5
  • 7
    • 0036922322 scopus 로고    scopus 로고
    • Comparison of PVDF- and FEP-based radiation-grafted alkaline anion-exchange membranes for use in low temperature portable DMFCs
    • T.N. Danks, R.C.T. Slade, and J.R. Varcoe Comparison of PVDF- and FEP-based radiation-grafted alkaline anion-exchange membranes for use in low temperature portable DMFCs Journal of Materials Chemistry 12 2002 3371 3373
    • (2002) Journal of Materials Chemistry , vol.12 , pp. 3371-3373
    • Danks, T.N.1    Slade, R.C.T.2    Varcoe, J.R.3
  • 8
    • 33645982898 scopus 로고    scopus 로고
    • Composite anion exchange membrane for alkaline direct methanol fuel cell: Structural and electrochemical characterization
    • A. Huang, C. Xia, C. Xiao, and L. Zhuang Composite anion exchange membrane for alkaline direct methanol fuel cell: structural and electrochemical characterization Journal of Applied Polymer Science 100 2006 2248 2251
    • (2006) Journal of Applied Polymer Science , vol.100 , pp. 2248-2251
    • Huang, A.1    Xia, C.2    Xiao, C.3    Zhuang, L.4
  • 9
    • 34547869264 scopus 로고    scopus 로고
    • Homogeneous blend membrane made from poly(ether sulphone) and poly(vinylpyrrolidone) and its application to water electrolysis
    • S. Lu, L. Zhuang, and J. Lu Homogeneous blend membrane made from poly(ether sulphone) and poly(vinylpyrrolidone) and its application to water electrolysis Journal of Membrane Science 300 2007 205 210
    • (2007) Journal of Membrane Science , vol.300 , pp. 205-210
    • Lu, S.1    Zhuang, L.2    Lu, J.3
  • 10
    • 78149459172 scopus 로고    scopus 로고
    • Self-crosslinked alkaline polymer electrolyte exceptionally stable at 90 [degree]C
    • J. Pan, Y. Li, L. Zhuang, and J. Lu Self-crosslinked alkaline polymer electrolyte exceptionally stable at 90 [degree]C Chemical Communications 46 2010 8597 8599
    • (2010) Chemical Communications , vol.46 , pp. 8597-8599
    • Pan, J.1    Li, Y.2    Zhuang, L.3    Lu, J.4
  • 11
    • 74349115454 scopus 로고    scopus 로고
    • High-performance alkaline polymer electrolyte for fuel cell applications
    • J. Pan, S. Lu, Y. Li, A. Huang, L. Zhuang, and J. Lu High-performance alkaline polymer electrolyte for fuel cell applications Advanced Functional Materials 20 2010 312 319
    • (2010) Advanced Functional Materials , vol.20 , pp. 312-319
    • Pan, J.1    Lu, S.2    Li, Y.3    Huang, A.4    Zhuang, L.5    Lu, J.6
  • 12
    • 72649086330 scopus 로고    scopus 로고
    • Ethanol electro-oxidation on Pt/C and PtSn/C catalysts in alkaline and acid solutions
    • L. Jiang, A. Hsu, D. Chu, and R. Chen Ethanol electro-oxidation on Pt/C and PtSn/C catalysts in alkaline and acid solutions International Journal of Hydrogen Energy 35 2010 365 372
    • (2010) International Journal of Hydrogen Energy , vol.35 , pp. 365-372
    • Jiang, L.1    Hsu, A.2    Chu, D.3    Chen, R.4
  • 13
    • 0035973868 scopus 로고    scopus 로고
    • The influence of the oxygen-containing species on the electrooxidation of the C1-C4 alcohols at some platinum single crystal surfaces in alkaline solution
    • A.V. Tripkovic, K.D. Popovic, and J.D. Lovic The influence of the oxygen-containing species on the electrooxidation of the C1-C4 alcohols at some platinum single crystal surfaces in alkaline solution Electrochimica Acta 46 2001 3163 3173
    • (2001) Electrochimica Acta , vol.46 , pp. 3163-3173
    • Tripkovic, A.V.1    Popovic, K.D.2    Lovic, J.D.3
  • 14
    • 70449474722 scopus 로고    scopus 로고
    • Ethanol electro-oxidation on platinum in alkaline media
    • S.C.S. Lai, and M.T.M. Koper Ethanol electro-oxidation on platinum in alkaline media Physical Chemistry Chemical Physics 11 2009 10446 10456
    • (2009) Physical Chemistry Chemical Physics , vol.11 , pp. 10446-10456
    • Lai, S.C.S.1    Koper, M.T.M.2
  • 16
  • 19
    • 35948971712 scopus 로고    scopus 로고
    • Investigation of the ethanol electro-oxidation in alkaline membrane electrode assembly by differential electrochemical mass spectrometry
    • Rao V. Hariyanto, C. Cremers, and U. Stimming Investigation of the ethanol electro-oxidation in alkaline membrane electrode assembly by differential electrochemical mass spectrometry Fuel Cells 7 2007 417 423
    • (2007) Fuel Cells , vol.7 , pp. 417-423
    • Hariyanto, R.V.1    Cremers, C.2    Stimming, U.3
  • 20
    • 77958153438 scopus 로고    scopus 로고
    • Electrochemical oxidation of C2 alcohols at platinum electrodes in acidic and alkaline environment
    • D. Bayer, S. Berenger, M. Joos, C. Cremers, and J. Tübke Electrochemical oxidation of C2 alcohols at platinum electrodes in acidic and alkaline environment International Journal of Hydrogen Energy 35 2010 12660 12667
    • (2010) International Journal of Hydrogen Energy , vol.35 , pp. 12660-12667
    • Bayer, D.1    Berenger, S.2    Joos, M.3    Cremers, C.4    Tübke, J.5
  • 21
    • 59849114887 scopus 로고    scopus 로고
    • Mechanism study of the ethanol oxidation reaction on palladium in alkaline media
    • Z.X. Liang, T.S. Zhao, J.B. Xu, and L.D. Zhu Mechanism study of the ethanol oxidation reaction on palladium in alkaline media Electrochimica Acta 54 2009 2203 2208
    • (2009) Electrochimica Acta , vol.54 , pp. 2203-2208
    • Liang, Z.X.1    Zhao, T.S.2    Xu, J.B.3    Zhu, L.D.4
  • 22
    • 77958104386 scopus 로고    scopus 로고
    • In situ FTIR spectroscopic studies of electrooxidation of ethanol on Pd electrode in alkaline media
    • Z.Y. Zhou, Q. Wang, J.L. Lin, N. Tian, and S.G. Sun In situ FTIR spectroscopic studies of electrooxidation of ethanol on Pd electrode in alkaline media Electrochimica Acta 55 2010 7995 7999
    • (2010) Electrochimica Acta , vol.55 , pp. 7995-7999
    • Zhou, Z.Y.1    Wang, Q.2    Lin, J.L.3    Tian, N.4    Sun, S.G.5
  • 23
    • 71549126543 scopus 로고    scopus 로고
    • An in situ Fourier transform infrared spectroelectrochemical study on ethanol electrooxidation on Pd in alkaline solution
    • X. Fang, L. Wang, P.K. Shen, G. Cui, and C. Bianchini An in situ Fourier transform infrared spectroelectrochemical study on ethanol electrooxidation on Pd in alkaline solution Journal of Power Sources 195 2010 1375 1378
    • (2010) Journal of Power Sources , vol.195 , pp. 1375-1378
    • Fang, X.1    Wang, L.2    Shen, P.K.3    Cui, G.4    Bianchini, C.5
  • 24
    • 70149094210 scopus 로고    scopus 로고
    • First-principles considerations on catalytic activity of Pd toward ethanol oxidation
    • G. Cui, S. Song, P.K. Shen, A. Kowal, and C. Bianchini First-principles considerations on catalytic activity of Pd toward ethanol oxidation The Journal of Physical Chemistry C 113 2009 15639 15642
    • (2009) The Journal of Physical Chemistry C , vol.113 , pp. 15639-15642
    • Cui, G.1    Song, S.2    Shen, P.K.3    Kowal, A.4    Bianchini, C.5
  • 25
    • 77953523685 scopus 로고    scopus 로고
    • Density functional theory studies of the structure sensitivity of ethanol oxidation on palladium surfaces
    • E.D. Wang, J.B. Xu, and T.S. Zhao Density functional theory studies of the structure sensitivity of ethanol oxidation on palladium surfaces The Journal of Physical Chemistry C 114 2010 10489 10497
    • (2010) The Journal of Physical Chemistry C , vol.114 , pp. 10489-10497
    • Wang, E.D.1    Xu, J.B.2    Zhao, T.S.3
  • 26
    • 79960557588 scopus 로고    scopus 로고
    • Highly active rhodium/carbon nanocatalysts for ethanol oxidation in alkaline medium
    • Y. Suo, and I.M. Hsing Highly active rhodium/carbon nanocatalysts for ethanol oxidation in alkaline medium Journal of Power Sources 196 2011 7945 7950
    • (2011) Journal of Power Sources , vol.196 , pp. 7945-7950
    • Suo, Y.1    Hsing, I.M.2
  • 27
    • 34447344487 scopus 로고    scopus 로고
    • Electrocatalysis of oxygen reduction and small alcohol oxidation in alkaline media
    • J.S. Spendelow, and A. Wieckowski Electrocatalysis of oxygen reduction and small alcohol oxidation in alkaline media Physical Chemistry Chemical Physics 9 2007 2654 2675
    • (2007) Physical Chemistry Chemical Physics , vol.9 , pp. 2654-2675
    • Spendelow, J.S.1    Wieckowski, A.2
  • 30
    • 77950948354 scopus 로고    scopus 로고
    • Alkaline polymer electrolyte fuel cells: Principle, challenges, and recent progress
    • D. Tang, J. Pan, S. Lu, L. Zhuang, and J. Lu Alkaline polymer electrolyte fuel cells: principle, challenges, and recent progress SCIENCE CHINA Chemistry 53 2010 357 364
    • (2010) SCIENCE CHINA Chemistry , vol.53 , pp. 357-364
    • Tang, D.1    Pan, J.2    Lu, S.3    Zhuang, L.4    Lu, J.5
  • 32
    • 70349096793 scopus 로고    scopus 로고
    • Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells
    • C. Bianchini, and P.K. Shen Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells Chemical Reviews 109 2009 4183 4206
    • (2009) Chemical Reviews , vol.109 , pp. 4183-4206
    • Bianchini, C.1    Shen, P.K.2
  • 33
    • 77953117492 scopus 로고    scopus 로고
    • Direct electrodeposition of tetrahexahedral Pd nanocrystals with high-index facets and high catalytic activity for ethanol electrooxidation
    • N. Tian, Z.Y. Zhou, N.F. Yu, L.Y. Wang, and S.G. Sun Direct electrodeposition of tetrahexahedral Pd nanocrystals with high-index facets and high catalytic activity for ethanol electrooxidation Journal of the American Chemical Society 132 2010 7580 7581
    • (2010) Journal of the American Chemical Society , vol.132 , pp. 7580-7581
    • Tian, N.1    Zhou, Z.Y.2    Yu, N.F.3    Wang, L.Y.4    Sun, S.G.5
  • 34
    • 37349040122 scopus 로고    scopus 로고
    • 4)-promoted Pd/C electrocatalysts for alcohol electrooxidation in alkaline media
    • 4)-promoted Pd/C electrocatalysts for alcohol electrooxidation in alkaline media Electrochimica Acta 53 2008 2610 2618
    • (2008) Electrochimica Acta , vol.53 , pp. 2610-2618
    • Xu, C.1    Tian, Z.2    Shen, P.3    Jiang, S.P.4
  • 35
    • 58649101319 scopus 로고    scopus 로고
    • Carbon-supported PdM (M=Au and Sn) nanocatalysts for the electrooxidation of ethanol in high pH media
    • Q. He, W. Chen, S. Mukerjee, S. Chen, and F. Laufek Carbon-supported PdM (M=Au and Sn) nanocatalysts for the electrooxidation of ethanol in high pH media Journal of Power Sources 187 2009 298 304
    • (2009) Journal of Power Sources , vol.187 , pp. 298-304
    • He, Q.1    Chen, W.2    Mukerjee, S.3    Chen, S.4    Laufek, F.5
  • 36
    • 78049281413 scopus 로고    scopus 로고
    • Carbon-supported bimetallic PdIr catalysts for ethanol oxidation in alkaline media
    • S.Y. Shen, T.S. Zhao, and J.B. Xu Carbon-supported bimetallic PdIr catalysts for ethanol oxidation in alkaline media Electrochimica Acta 55 2010 9179 9184
    • (2010) Electrochimica Acta , vol.55 , pp. 9179-9184
    • Shen, S.Y.1    Zhao, T.S.2    Xu, J.B.3
  • 37
    • 77950900199 scopus 로고    scopus 로고
    • Performance of carbon nanofiber supported Pd-Ni catalysts for electro-oxidation of ethanol in alkaline medium
    • T. Maiyalagan, and K. Scott Performance of carbon nanofiber supported Pd-Ni catalysts for electro-oxidation of ethanol in alkaline medium Journal of Power Sources 195 2010 5246 5251
    • (2010) Journal of Power Sources , vol.195 , pp. 5246-5251
    • Maiyalagan, T.1    Scott, K.2
  • 38
    • 80052269976 scopus 로고    scopus 로고
    • y/C electrocatalysts for ethanol electrooxidation reaction in alkaline media
    • y/C electrocatalysts for ethanol electrooxidation reaction in alkaline media Electrochimica Acta 56 2011 7703 7711
    • (2011) Electrochimica Acta , vol.56 , pp. 7703-7711
    • Li, G.1    Jiang, L.2    Jiang, Q.3    Wang, S.4    Sun, G.5
  • 39
    • 79961243936 scopus 로고    scopus 로고
    • The beneficial role of the cometals Pd and Au in the carbon-supported PtPdAu catalyst toward promoting ethanol oxidation kinetics in alkaline fuel cells: Temperature effect and reaction mechanism
    • J. Datta, A. Dutta, and S. Mukherjee The beneficial role of the cometals Pd and Au in the carbon-supported PtPdAu catalyst toward promoting ethanol oxidation kinetics in alkaline fuel cells: temperature effect and reaction mechanism The Journal of Physical Chemistry C 115 2011 15324 15334
    • (2011) The Journal of Physical Chemistry C , vol.115 , pp. 15324-15334
    • Datta, J.1    Dutta, A.2    Mukherjee, S.3
  • 40
    • 79953660586 scopus 로고    scopus 로고
    • Carbon supported Pd-Sn and Pd-Ru-Sn nanocatalysts for ethanol electro-oxidation in alkaline medium
    • R.M. Modibedi, T. Masombuka, and M.K. Mathe Carbon supported Pd-Sn and Pd-Ru-Sn nanocatalysts for ethanol electro-oxidation in alkaline medium International Journal of Hydrogen Energy 36 2011 4664 4672
    • (2011) International Journal of Hydrogen Energy , vol.36 , pp. 4664-4672
    • Modibedi, R.M.1    Masombuka, T.2    Mathe, M.K.3
  • 41
    • 70349492141 scopus 로고    scopus 로고
    • High activity PtRu/C catalysts synthesized by a modified impregnation method for methanol electro-oxidation
    • L. Ma, C. Liu, J. Liao, T. Lu, W. Xing, and J. Zhang High activity PtRu/C catalysts synthesized by a modified impregnation method for methanol electro-oxidation Electrochimica Acta 54 2009 7274 7279
    • (2009) Electrochimica Acta , vol.54 , pp. 7274-7279
    • Ma, L.1    Liu, C.2    Liao, J.3    Lu, T.4    Xing, W.5    Zhang, J.6
  • 42
    • 0027593351 scopus 로고
    • An examination of the electrochemical behavior of palladium electrodes in acid
    • L.D. Burke, and J.K. Casey An examination of the electrochemical behavior of palladium electrodes in acid Journal of the Electrochemical Society 140 1993 1284 1291
    • (1993) Journal of the Electrochemical Society , vol.140 , pp. 1284-1291
    • Burke, L.D.1    Casey, J.K.2
  • 43
    • 0036378409 scopus 로고    scopus 로고
    • The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electrochemical deposition from lyotropic liquid crystalline phases
    • P.N. Bartlett, B. Gollas, S. Guerin, and J. Marwan The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electrochemical deposition from lyotropic liquid crystalline phases Physical Chemistry Chemical Physics 4 2002 3835 3842
    • (2002) Physical Chemistry Chemical Physics , vol.4 , pp. 3835-3842
    • Bartlett, P.N.1    Gollas, B.2    Guerin, S.3    Marwan, J.4
  • 44
    • 0027592763 scopus 로고
    • An examination of the electrochemical behavior of palladium in base
    • L.D. Burke, and J.K. Casey An examination of the electrochemical behavior of palladium in base Journal of the Electrochemical Society 140 1993 1292 1298
    • (1993) Journal of the Electrochemical Society , vol.140 , pp. 1292-1298
    • Burke, L.D.1    Casey, J.K.2
  • 45
    • 10944261984 scopus 로고    scopus 로고
    • Ethanol electrooxidation on a carbon-supported Pt catalyst: Reaction kinetics and product yields
    • 19413-24
    • H. Wang, Z. Jusys, and R.J. Behm Ethanol electrooxidation on a carbon-supported Pt catalyst: reaction kinetics and product yields The Journal of Physical Chemistry B 108 2004 19413-24
    • (2004) The Journal of Physical Chemistry B , vol.108
    • Wang, H.1    Jusys, Z.2    Behm, R.J.3
  • 46
    • 64549123449 scopus 로고    scopus 로고
    • Ethanol electrooxidation on a carbon-supported Pt catalyst at elevated temperature and pressure: A high-temperature/high-pressure DEMS study
    • S. Sun, M.C. Halseid, M. Heinen, Z. Jusys, and R.J. Behm Ethanol electrooxidation on a carbon-supported Pt catalyst at elevated temperature and pressure: a high-temperature/high-pressure DEMS study Journal of Power Sources 190 2009 2 13
    • (2009) Journal of Power Sources , vol.190 , pp. 2-13
    • Sun, S.1    Halseid, M.C.2    Heinen, M.3    Jusys, Z.4    Behm, R.J.5
  • 47
    • 55049115207 scopus 로고    scopus 로고
    • Surface structure effects on the electrochemical oxidation of ethanol on platinum single crystal electrodes
    • F. Colmati, G. Tremiliosi-Filho, E.R. Gonzalez, A. Berna, E. Herrero, and J.M. Feliu Surface structure effects on the electrochemical oxidation of ethanol on platinum single crystal electrodes Faraday Discussions 140 2009 379 397
    • (2009) Faraday Discussions , vol.140 , pp. 379-397
    • Colmati, F.1    Tremiliosi-Filho, G.2    Gonzalez, E.R.3    Berna, A.4    Herrero, E.5    Feliu, J.M.6
  • 48
    • 0001482343 scopus 로고
    • Absorption of organic substances on platinum electrodes
    • V.S. Bagotzky, and Y.B. Vassiliev Absorption of organic substances on platinum electrodes Electrochimica Acta 11 1966 1439 1461
    • (1966) Electrochimica Acta , vol.11 , pp. 1439-1461
    • Bagotzky, V.S.1    Vassiliev, Y.B.2
  • 50
    • 0023133069 scopus 로고
    • Different views regarding the kinetics and mechanisms of oxygen reduction at Pt and Pd electrodes
    • D.B. Sepa, M.V. Vojnovic, L.M. Vracar, and A. Damjanovic Different views regarding the kinetics and mechanisms of oxygen reduction at Pt and Pd electrodes Electrochimica Acta 32 1987 129 134
    • (1987) Electrochimica Acta , vol.32 , pp. 129-134
    • Sepa, D.B.1    Vojnovic, M.V.2    Vracar, L.M.3    Damjanovic, A.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.