Proton-conducting composite membranes derived from ferroxane-polyvinyl alcohol complex

Environmental Engineering Science

Volumn 29, Issue 2, 2012, Pages 124-132

  Zhang, Liwei ^a   Chae, So Ryong ^b   Lin, Shihong ^c   Wiesner, Mark R ^c  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b UNIVERSITY OF SYDNEY   (Australia)

^c Duke University   (United States)

Author keywords

ferroxane PVA composite membrane; proton conductivity; proton exchange membrane; tensile force resistance

Indexed keywords

ELECTROLYTE MATERIAL; LEPIDOCROCITE; PROTON EXCHANGE MEMBRANE; PROTON EXCHANGE MEMBRANES; TENSILE FORCES;

ACETIC ACID; CERAMIC MEMBRANES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROGEN; IRON COMPOUNDS; IRON OXIDES; MEMBRANES; NANOPARTICLES; PROTON CONDUCTIVITY; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); PROTONS;

COMPOSITE MEMBRANES;

ACETIC ACID; ALCOHOL; ELECTROLYTE; FERRIC HYDROXIDE; HYDROGEN; IRON OXIDE; NANOPARTICLE; POLYVINYL ALCOHOL;

ARTICLE; CERAMICS; INFRARED SPECTROSCOPY; MICROBIAL FUEL CELL; NANOFABRICATION; PROTON TRANSPORT;

EID: 84863081719     PISSN: 10928758     EISSN: 15579018     Source Type: Journal    
DOI: 10.1089/ees.2011.0270     Document Type: Article

References (24)

1. Barbir, F. (2005). PEM Fuel Cells: Theory and Practice. Boston: Elsevier Academic Press.
2. Davies, S., and Morgan, J. (1989). Manganese (Ii) oxidationkinetics on metal-oxide surfaces. J. Colloid Interface Sci. 129, 63.
3. Gu, B.H., Schmitt, J., Chen, Z.H., Liang, L.Y., and Mccarthy J.F. (1994). Adsorption and desorption of natural organic-matter on iron-oxide-mechanisms and models. Environ. Sci. Technol. 28, 38.
4. Hansmann, D.D., and Anderson, M.A. (1985). Using electrophoresis in modeling sulfate, selenite, and phosphate adsorption onto goethite. Environ. Sci. Technol. 19, 544.
5. Ilcin, M., Hola, O., Bakajova, B., and Kucerik J. (2010). FT-IR study of gamma-radiation induced degradation of polyvinyl alcohol (PVA) and PVA/humic acids blends. J. Radioanal. Nucl. Chem. 283, 9.
6. Kern, W., and Schulz, R.C. (1957). Synthetische makromolekulare Stoffe mit reaktiven Gruppen. Angew. Chem. 69, 153.
7. Kickelbick, G. (2007). Hybrid Materials: Synthesis, Characterization, and Applications. Weinheim: Wiley-VCH.
8. Lee, C.H., Park, H.B., Lee, Y.M., and Lee, R.D. (2005). Importance of proton conductivity measurement in polymer electrolyte membrane for fuel cell application. Ind. Eng. Chem. Res. 44, 7617.
9. Lovgren, L., Sjoberg, S., and Schindler, P.W. (1990). Acid-base reactions and Al(Iii) complexation at the surface of goethite. Geochimica Et Cosmochimica Acta 54, 1301.
10. O'Hayre, R.P. (2006). Fuel Cell Fundamentals. Hoboken: John Wiley & Sons.
11. Refait, P., and Genin, J. (1993). The oxidation of ferrous hydroxide in chloride-containing aqueous-media and pourbaix diagrams of green rust one. Corros. Sci. 34, 797.
12. Rose, J., Cortalezzi-Fidalgo, M.M, Moustier, S., Magnetto, C., Jones, C.D., Barron, A.R., Wiesner, M.R., and Bottero, J.Y. (2002). Synthesis and characterization of carboxylate-FeOOH nanoparticles (ferroxanes) and ferroxane-derived ceramics. Chem. Mater. 14, 621.
13. Rudnik, E. (2008). Compostable Polymer Materials. Oxford: Elsevier Press.
14. Sakurada, I. (1985). Polyvinyl Alcohol Fibers. New York: Marcel Dekker Press.
15. Sethuraman, V.A., Weidner, J.W., Haug, A.T., Motupally, S., and Protsailo, L.V. (2008). Hydrogen peroxide formation rates in a PEMFC anode and cathode-effect of humidity and temperature. J. Electrochem. Soc. 155, B50.
16. Sigg, L., and Stumm, W. (1981). The interaction of anions and weak acids with the hydrous goethite (alpha-FeOOH) surface. Colloids Surf. 2, 101.
17. Somasundaran, P. (2006). Encyclopedia of Surface and Colloid Science, 2nd edition. New York: Taylor & Francis.
18. Sone, Y., Ekdunge, P., and Simonsson, D. (1996). Proton conductivity of Nafion 117 as measured by a four-electrode AC impedance method. J. Electrochem. Soc. 143, 1254.
19. Staudinger, H., and Zapf, F. (1940). Über makromolekulare Verbindungen 256. Mitteilung: Über das Glykogenxanthogenat. J. Für Praktische Chem. 157, 1.
20. Torrent, J., Barron, V., and Schwertmann, U. (1990). Phosphate adsorption and desorption by goethites differing in crystal morphology. Soil Sci. Soc. Am. J. 54, 1007.
21. Tsui, E.M., Cortalezzi, M.M., and Wiesner, M.R. (2007). Proton conductivity and methanol rejection by ceramic membranes derived from ferroxane and alumoxane precursors. J. Membr. Sci. 306, 8.
22. Tsui, E.M., and Wiesner, M.R. (2008). Fast proton-conducting ceramic membranes derived from ferroxane nanoparticleprecursors as fuel cell electrolytes. J. Membr. Sci. 318, 79.
23. Upadhyay, D.J., and Bhat, N.V. (2004). Pervaporation studies of gaseous plasma treated PVA membrane. J. Membr. Sci. 239, 255.
24. Waite, T.D., and Morel, F. (1984). Photoreductive dissolution of colloidal iron-oxide-effect of citrate. J. Colloid Interface Sci. 102, 121.