Intriguing role of a quaternary ammonium cation in the dissociation chemistry of Keggin polyoxometalate anions

Journal of the American Society for Mass Spectrometry

Volumn 23, Issue 2, 2012, Pages 366-374

  Cao, Jie ^a   Li, Chenchen ^b   Zhang, Zhengxiang ^b   Xu, Chong ^a   Yan, Jie ^a   Cui, Fengyun ^a   Hu, Changwen ^a  

^a BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

^b AGILENT TECHNOLOGIES   (China)

Author keywords

Electrospray ionization tandem mass spectrometry; Gas phase fragmentation; Keggin POM clusters; Non covalent complex; Tetrabutylammonium(TBA)

Indexed keywords

ELECTROSPRAY IONIZATION TANDEM MASS SPECTROMETRY; GAS-PHASE FRAGMENTATION; KEGGIN POM CLUSTERS; NON-COVALENT COMPLEXES; TETRABUTYLAMMONIUM;

AMMONIUM COMPOUNDS; DISSOCIATION; IONIZATION OF GASES; MASS SPECTROMETRY; MOLYBDENUM; NEGATIVE IONS; OXIDES; POSITIVE IONS; STOICHIOMETRY;

ELECTROSPRAY IONIZATION;

CARBON; CATION; NITROGEN; QUATERNARY AMMONIUM DERIVATIVE; TETRABUTYLAMMONIUM;

ARTICLE; CATION EXCHANGE; CHEMICAL COMPOSITION; CHEMICAL INTERACTION; CHEMICAL REACTION; CONTROLLED STUDY; COVALENT BOND; DISSOCIATION; ELECTROSPRAY MASS SPECTROMETRY; FRAGMENTATION REACTION; STOICHIOMETRY; TANDEM MASS SPECTROMETRY; THERMOSTABILITY;

EID: 84863032897     PISSN: 10440305     EISSN: 18791123     Source Type: Journal    
DOI: 10.1007/s13361-011-0296-4     Document Type: Article

References (32)

1. JM Daniel SD Friess S Rajagopalan S Wendt R Zenobi 2002 Quantitative determination of noncovalent binding interactions using soft ionization mass spectrometry Int. J. Mass Spectrom. 216 1 27 10.1016/S1387-3806(02)00585-7 1:CAS:528:DC%2BD38Xis1enur4%3D
2. Pope, M.T.: Heteropoly and Isopoly Oxometalates (Chapter 2, pp. 15-32). Springer-Verlag, Berlin (1983)
3. RG Finke MW Droege JC Cook KS Suslick 1984 Fast atom bombardment mass spectroscopy of polyoxoanions J. Am. Chem. Soc. 106 5750 5751 10.1021/ja00331a067 1:CAS:528:DyaL2cXmtF2is7s%3D
4. KS Suslick JC Cook B Rapko MW Droege RG Finke 1986 Characterization of very large polyoxoanions by fast atom bombardment mass spectroscopy (FABMS) Inorg. Chem. 25 241 243 10.1021/ic00222a029 1:CAS:528:DyaL28XpvVyjtw%3D%3D
5. 8- Inorg. Chem. 30 1788 1792 10.1021/ic00008a021 1:CAS:528:DyaK3MXit1Sjur8%3D
6. MJ Abrams CE Costello SN Shaikh J Zubieta 1991 Keggin polyoxotungstate derivatives containing technetium Inorg. Chim. Acta 180 9 11 10.1016/S0020-1693(00)83057-1 1:CAS:528:DyaK3MXlvFKksrY%3D
7. 8- Inorg. Chem. 32 6034 6039 10.1021/ic00078a022 1:CAS:528:DyaK2cXjvFehtA%3D%3D
8. R Colton JC Traeger 1992 The application of electrospray mass spectrometry to ionic inorganic and organometallic systems Inorg. Chim. Acta 201 153 155 10.1016/S0020-1693(00)85326-8 1:CAS:528:DyaK3sXhtFagsL4%3D
9. Deery, M.J.; Howarth, O.W.; Jennings, K.R. Application of electrospray ionisation mass spectrometry to the study of dilute aqueous oligomeric anions and their reactions. J. Chem. Soc.; Dalton Trans. 4783-4788 (1997) (Pubitemid 127789108)
10. CS Truebenbach M Houalla DM Hercules 2000 Characterization of isopoly metal oxyanions using electrospray time-of-flight mass spectrometry J. Mass Spectrom. 35 1121 1127 10.1002/1096-9888(200009)35:9<1121::AID-JMS40>3.0. CO;2-7 1:CAS:528:DC%2BD3cXnt1Cgu78%3D
11. F Sahureka RC Burns EI Nagy-Felsobuki 2003 Electrospray ionization mass spectroscopic characterisation of isopolyoxo-niobates and -tantalates Inorg.Chim. Acta 351 69 78 10.1016/S0020-1693(03)00058-6 1:CAS:528: DC%2BD3sXlsVCktbo%3D
12. 10-, a model five-spin frustrated cluster Inorg. Chem. 44 9795 9806 10.1021/ic0512633 1:CAS:528:DC%2BD2MXht1Wlt7fE
13. 29-. Chem. Commun. 4254-4256 (2007) (Pubitemid 47598746)
14. DL Long C Streb YF Song S Mitchell L Cronin 2008 Unraveling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion J. Am. Chem. Soc. 130 1830 1832 10.1021/ja075940z 1:CAS:528:DC%2BD1cXntVertg%3D%3D (Pubitemid 351238629)
15. 5- Inorg. Chem. 46 3502 3510 10.1021/ic062067e 1:CAS:528:DC%2BD2sXjsV2muro%3D
16. 5- polyoxometalate assembly Angew. Chem. Int. Ed. 47 4388 4391 10.1002/anie.200800431 1:CAS:528:DC%2BD1cXntFOgtLs%3D
17. DL Long YF Song EF Wilson P Kögerler SX Guo AM Bond JSJ Hargreaves L Cronin 2008 Capture of periodate in a W18O54 cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)]6- embedded with high-valent iodine Angew. Chem. Int. Ed. 47 4384 4387 10.1002/anie.200800041 1:CAS:528:DC%2BD1cXntFOhurk%3D
18. F Xu RA Scullion J Yan HN Miras C Busche A Scandurra B Pignataro DL Long L Cronin 2011 A Supramolecular heteropolyoxopalladate Pd15 cluster host encapsulating a Pd2 dinuclear guest: [PdII2{H7PdII15O10(PO4)10}]9- J. Am. Chem. Soc. 133 4684 4686 10.1021/ja1105514 1:CAS:528:DC%2BC3MXjt1yru7g%3D
19. 54- J. Am. Chem. Soc. 132 11410 11411 10.1021/ja104043s 1:CAS:528:DC%2BC3cXpslChu7w%3D
20. Lau, T.C.; Wang, J.; Guevremont, R.; Siu, K.W.M. Electrospray tandem mass spectrometry of polyoxoanions. J. Chem. Soc. Chem. Commun. 877-878 (1995)
21. MT Ma T Waters K Beyer R Palamarczuk PJS Richardt RAJ O'Hair AG Wedd 2009 Gas-phase fragmentation of polyoxotungstate anions Inorg. Chem. 48 598 606 10.1021/ic8016326 1:CAS:528:DC%2BD1cXhsFSjtbfO
22. TH Bray R Copping DK Shuh JK Gibson 2011 Electrospray ionization mass spectrometry of a cerium(III) phosphomolybdate complex: Condensed and gas-phase cluster chemistry Int. J. Mass Spectrom. 299 35 46 10.1016/j.ijms.2010.09.015 1:CAS:528:DC%2BC3cXhsVOgu73J
23. GJ Cao J Lin WH Fang ST Zheng GY Yang 2011 Open-framework aluminoborates co-templated by two types of primary amines Dalton Trans. 40 2940 2946 10.1039/c0dt01537g 1:CAS:528:DC%2BC3MXjtFantrY%3D
24. CP Pradeep DL Long L Cronin 2010 Cations in control: Crystal engineering polyoxometalate clusters using cation directed self-assembly Dalton Trans. 39 9443 9457 10.1039/c0dt00325e 1:CAS:528:DC%2BC3cXht1CltrrJ
25. J Yan DL Long HN Miras L Cronin 2010 Cation controlled assembly and transformation of mono- and bi-sulfite templated Dawson-type polyoxotungstates Inorg. Chem. 49 1819 1825 10.1021/ic9021646 1:CAS:528:DC%2BC3cXnsVyquw%3D%3D
26. (3+2x)- (x=1 and 2) J. of Mol. Catal. A Chem. 114 237 245 10.1016/S1381-1169(96)00323-8 1:CAS:528:DyaK28XntlOnsr8%3D (Pubitemid 27054127)
27. 2 catalysed by Ti(IV)-monosubstituted Keggin polyoxometalate J. Mol. Catal. A Chem. 232 173 178 10.1016/j.molcata.2005.01.036 1:CAS:528: DC%2BD2MXisVSjtbc%3D (Pubitemid 40392467)
28. C Li J Gao Z Jiang S Wang H Lu Y Yang F Jing 2005 Selective oxidations on recoverable catalysts assembled in emulsions Top. Catal. 35 169 175 10.1007/s11244-005-3821-5 1:CAS:528:DC%2BD2MXpt1Wgsrw%3D (Pubitemid 41197377)
29. ARS Ross MG Ikonomou JAJ Thompson KJ Orians 1998 Anal. Chem. 70 2225 2235 10.1021/ac9711908 1:CAS:528:DyaK1cXjsFeiu7c%3D
30. SG Penn F He MK Green CB Lebrilla 1997 The use of heated capillary dissociation and collision-induced dissociation to determine the strength of non-covalent bonding interactions in gas-phase peptide-cyclodextrin complex J. Am. Soc. Mass Spectrom. 8 244 252 10.1016/S1044-0305(96)00242-5 1:CAS:528:DyaK2sXhs12mu7w%3D (Pubitemid 27113753)
31. WM David JS Brodbelt 2003 Threshold dissociation energies of protonated amine/polyether complexes in a quadrupole ion trap J. Am. Soc. Mass Spectrom. 14 383 392 10.1016/S1044-0305(03)00070-9 1:CAS:528:DC%2BD3sXis12lu7k%3D (Pubitemid 36876039)
32. AG Kong SM Zhang DW Zhang LL Lü C Jin YK Shan 2005 Thermal decomposition behavior of metal-oxygen clusters with Keggin structure Chem. J. Chinese Universities 26 2002 2006 1:CAS:528:DC%2BD2MXht1KrtLnM (Pubitemid 41754056)