Alkene epoxidation by hydrogen peroxide in the presence of titanium- substituted Keggin-type polyoxotungstates [PTi(x)W(12-x)O40]((3+2x)-) and [PTi(x)W(12-x)O(40-x)(O2)(x)]((3+2x)-) (x = 1 and 2)

Journal of Molecular Catalysis A: Chemical

Volumn 114, Issue 1-3, 1996, Pages 237-245

  Yamase, Toshihiro ^a   Ishikawa, Eri ^a   Asai, Yasushi ^a   Kanai, Santa ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Alkene epoxidation; involvement of OH; Peroxo Keggin type polyoxotungstates; Reaction kinetics; substituted Keggin type polyoxotungstates

Indexed keywords

EID: 0030599580     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(96)00323-8     Document Type: Article

References (24)

1. |1] C. Venturello, R. D'Aloisio, J.C.J. Bart and M. Ricci, J Mol. Catal. 32 (1985) 107.
2. [2] C. Venturello, E. Alneri and M. Ricci, J. Org. Chem. 48 (1980) 1604; C. Veniurello and R. D'Aloisio, J. Org. Chem. 53 (1988) 1553.
3. [2] C. Venturello, E. Alneri and M. Ricci, J. Org. Chem. 48 (1980) 1604; C. Veniurello and R. D'Aloisio, J. Org. Chem. 53 (1988) 1553.
4. [3] Y. Ishii, K. Yarnawaki, T. Yoshida, T. Ura and T. Ogawa, J. Org. Chem. 52 (1987) 1686, Y. Ishii, K. Yamawaki, T. Ura, H. Yamada, T. Yoshida and T. Ogawa, J. Org. Chem. 53 (1988) 3587; A.C. Dengel, W.P. Griffith, and B.C. Parkin, J. Chem. Soc. Dalton Trans. (1993) 2683.
5. [3] Y. Ishii, K. Yarnawaki, T. Yoshida, T. Ura and T. Ogawa, J. Org. Chem. 52 (1987) 1686, Y. Ishii, K. Yamawaki, T. Ura, H. Yamada, T. Yoshida and T. Ogawa, J. Org. Chem. 53 (1988) 3587; A.C. Dengel, W.P. Griffith, and B.C. Parkin, J. Chem. Soc. Dalton Trans. (1993) 2683.
6. [3] Y. Ishii, K. Yarnawaki, T. Yoshida, T. Ura and T. Ogawa, J. Org. Chem. 52 (1987) 1686, Y. Ishii, K. Yamawaki, T. Ura, H. Yamada, T. Yoshida and T. Ogawa, J. Org. Chem. 53 (1988) 3587; A.C. Dengel, W.P. Griffith, and B.C. Parkin, J. Chem. Soc. Dalton Trans. (1993) 2683.
7. [4] D.C. Duncan. R.C. Chambers, H. Hecht and C.L. Hill. J. Am. Chem. Soc. 117 (1995) 681.
8. [5] C. Aubry, G. Chottard, N. Platzer, J.-M. Brégeault, R Thouvenot, F. Chauveau, C. Huel and H. Ledon, Inorg. Chem. 30 (1991) 4409; L. Salles, C. Aubry, R. Thouvenot, F. Robert, C. Dorémieux-Morin, G. Chottard, H. Ledon, Y. Jeannin and J.-M. Brégeault, Inorg. Chem. 33 (1994) 871; M. Schwegler. M. Eloor and H. van Bekkum, Tetrahedron Lett. 29 (1988) 823.
9. [5] C. Aubry, G. Chottard, N. Platzer, J.-M. Brégeault, R Thouvenot, F. Chauveau, C. Huel and H. Ledon, Inorg. Chem. 30 (1991) 4409; L. Salles, C. Aubry, R. Thouvenot, F. Robert, C. Dorémieux-Morin, G. Chottard, H. Ledon, Y. Jeannin and J.-M. Brégeault, Inorg. Chem. 33 (1994) 871; M. Schwegler. M. Eloor and H. van Bekkum, Tetrahedron Lett. 29 (1988) 823.
10. [5] C. Aubry, G. Chottard, N. Platzer, J.-M. Brégeault, R Thouvenot, F. Chauveau, C. Huel and H. Ledon, Inorg. Chem. 30 (1991) 4409; L. Salles, C. Aubry, R. Thouvenot, F. Robert, C. Dorémieux-Morin, G. Chottard, H. Ledon, Y. Jeannin and J.-M. Brégeault, Inorg. Chem. 33 (1994) 871; M. Schwegler. M. Eloor and H. van Bekkum, Tetrahedron Lett. 29 (1988) 823.
11. [6] C.L. Hill and R.B. Brown, Jr., J. Am. Chem. Soc. 108 (1986) 536.
12. [7] C.L. Hill and C.M. Prosser-McCartha, Coord. Chem. Rev. 143 (1995) 407, and references therein.
13. [8] R. Neuman and M. Gara, J Am. Chem. Soc. 116 (1994) 5509.
14. [9] C.M. Tourné, G.F. Tourné and F. Zonnenvijlle, J. Chem. Soc. Dalton Tians. (1991) 143.
15. [10] P.T. Domaille and W.H. Knoth, Inorg. Chem. 22 (1983) 818.
16. [11] T. Ozeki and T. Yamase, Acta Crystallogr. C 47 (1991) 693.
17. [12] T. Yamase and M. Sugeta. Inorg. Chim. Acta 172 (1990) 131.
18. [13] T. Yamase, T. Ozeki and S. Motomura, Bull. Chem. Soc. Jpn. 65 (1992) 1453.
19. [14] W.H. Knoth, P.J. Domialle and D.C. Roe, Inorg. Chem. 22 (1983) 198.
20. [15] A.M. Khenkin and C.L. Hill, J. Am. Chem. Soc. 115 (1993) 8178.
21. [16] D.E. Katsoulis and M.T. Pope, J. Chem. Soc. Chem. Commun. (1986) 1186.
22. [17] R. Neuman and M. Gara, J. Am. Chem. Soc. 117 (1995) 5066.
23. [18] M.W. Dixieae and R.G. Finke, J. Mol. Catal. 69 (1991) 323.
24. [19] D. Dobos, Electrochemical Data (Elsevier, Amsterdam-Oxford-New York. 1975).