Simple preparative gas chromatographic method for isolation of menthol and menthone from peppermint oil, with quantitative GC-MS and 1H NMR assay

Journal of Separation Science

Volumn 35, Issue 3, 2012, Pages 416-423

  Park, Hae Eun ^a   Yang, Seung Ok ^a   Hyun, Sun Hee ^a   Park, Shin Jung ^a   Choi, Hyung Kyoon ^a   Marriott, Philip J ^a,b  

^a Chung Ang University   (South Korea)

^b MONASH UNIVERSITY   (Australia)

Author keywords

1H NMR; Deans Switch; Peppermint essential oil; Preparative GC; Quantitative cryogenic trapping

Indexed keywords

AREA RATIOS; CALIBRATION LINEARITY; CHLORONAPHTHALENES; CHROMATOGRAPHIC METHODS; CONSTANT VOLUMES; H NMR SPECTROSCOPY; INTERNAL STANDARDS; MENTHONE; NMR ANALYSIS; PREPARATIVE GC; QUANTITATIVE CRYOGENIC TRAPPING; REFERENCE SPECTRUM; STANDARD SOLUTIONS; TARGET COMPOUND;

CALIBRATION; CHROMATOGRAPHIC ANALYSIS; ESSENTIAL OILS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STANDARDS;

GAS CHROMATOGRAPHY;

CHLORONAPHTHALENE; MENTHONE; METHANOL; NAPHTHALENE DERIVATIVE; PEPPERMINT OIL; UNCLASSIFIED DRUG;

ARTICLE; CALIBRATION; CAPILLARY TUBE; CONTROLLED STUDY; GAS CHROMATOGRAPHY; ISOLATION AND PURIFICATION; MASS FRAGMENTOGRAPHY; MICROFLUIDIC ANALYSIS; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTITATIVE ASSAY; STANDARD;

CHROMATOGRAPHY, GAS; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; MAGNETIC RESONANCE SPECTROSCOPY; MENTHOL; PLANT OILS; PROTONS;

MENTHA X PIPERITA;

EID: 84862959444     PISSN: 16159306     EISSN: 16159314     Source Type: Journal    
DOI: 10.1002/jssc.201100670     Document Type: Article

References (20)

1. Davis, J. M., Giddings, J. C., Anal. Chem. 1983, 55, 418-424.
2. Bertsch, W., J. High Resolut. Chromatogr. 1999, 22, 647-665.
3. Grynbaum, M. D., Kreidler, D., Rehbein, J., Purea, A., Schuler, P., Schaal, W., Czesla, H., Webb, A., Schurig, V., Albert, K., Anal. Chem. 2007, 79, 2708-2713.
4. Blomberg, S., Roeraade, J., J. Chromatogr. A 1987, 394, 443-453.
5. Roeraade, J., Blomberg, S., Pietersma, H. D. J., J. Chromatogr. 1986, 356, 271-284.
6. Juza, M., Braun, E., Schurig, V., J. Chromatogr. A 1997, 769, 119-127.
7. Nojima, S., Schal, C., Webster, F. X., Santangelo, R. G., Roelofs, W. L., Science 2005, 307, 1104-1106.
8. Ruhle, C. P. G., Niere, J., Morrison, P. D., Jones, R. C., Caradoc-Davies, T., Canty, A. J., Gardiner, M. G., Tolhurst, V.-A., Marriott, P. J., Anal. Chem. 2010, 82, 4501-4509.
9. Schurig, V., Juza, M., Green, B. S., Horakh, J., Simon, A., Angew. Chem. Int. Ed. Engl. 1996, 35, 1680-1682.
10. Eyres, G. T., Urban, S., Morrison, P. D., Dufour, J.-P., Marriott, P. J., Anal. Chem. 2008, 80, 6293-6299.
11. Eyres, G. T., Urban, S., Morrison, P. D., Marriott, P. J., J. Chromatogr. A 2008, 1215, 168-176.
12. Rühle, C., Eyres, G. T., Urban, S., Dufour, J.-P., Morrison, P. D., Marriott, P. J., J. Chromatogr. A 2009, 1216, 5740-5747.
13. Deans, D., Chromatographia 1968, 1, 18-22.
14. Nojima, S., Apperson, C., Schal, C., J. Chem. Ecol. 2008, 34, 418-428.
15. Meinert, C., Brack, W., Chemosphere 2010, 78, 416-422.
16. Badings, H. T., de Jong, C., Dooper, R. P. M., J. High Resolut. Chromatogr. 1985, 8, 755-763.
17. Chin, S.-T., Maikhunthod, B., Marriott, P. J., Anal. Chem. 2011, 83, 6485-6492.
18. Schoenmakers, P., Marriott, P., Beens, J., LC-GC Europe 2003, June, 1-4.
19. Delort, E., Jaquier, A., Flavour Fragrance J. 2009, 24, 123-132.
20. Nojima, S., Kiemle, D. J., Webster, F. X., Apperson, C. S., Schal, C., PLoS One 2011, 6, e18178.