Far-UV photochemical bond cleavage of n -amyl nitrite: Bypassing a repulsive surface

Journal of Physical Chemistry A

Volumn 116, Issue 2, 2012, Pages 810-819

  Minitti, Michael P ^a,c   Zhang, Yao ^a   Rosenberg, Martin ^b   Brogaard, Rasmus Y ^b   Deb, Sanghamitra ^a   Sølling, Theis I ^b   Weber, Peter M ^a  

^a BROWN UNIVERSITY   (United States)

^b UNIVERSITY OF COPENHAGEN   (Denmark)

^c SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND CLEAVAGES; DEEP-UV; DISSOCIATION REACTIONS; HOMOLYTIC BONDS; INTERNAL CONVERSIONS; MASS SPECTRA; MULTIPHOTON IONIZATION; PHOTO-INDUCED; PHOTOELECTRON SPECTRUM; PUMP-PROBE; REPULSIVE SURFACES; RISETIMES; TIME-RESOLVED;

DISSOCIATION; MASS SPECTROMETRY; PHOTOELECTRON SPECTROSCOPY; PHOTOIONIZATION; POTENTIAL ENERGY; POTENTIAL ENERGY SURFACES; PULSE GENERATORS; QUANTUM CHEMISTRY;

EXCITED STATES;

AMYL NITRITE; FREE RADICAL; NITRIC OXIDE; PENTOXYL;

ARTICLE; CHEMISTRY; KINETICS; MASS SPECTROMETRY; PHOTOLYSIS; QUANTUM THEORY; SURFACE PROPERTY; ULTRAVIOLET RADIATION; X RAY PHOTOELECTRON SPECTROSCOPY;

AMYL NITRITE; FREE RADICALS; KINETICS; MASS SPECTROMETRY; NITRIC OXIDE; PENTOXYL; PHOTOELECTRON SPECTROSCOPY; PHOTOLYSIS; QUANTUM THEORY; SURFACE PROPERTIES; ULTRAVIOLET RAYS;

EID: 84862954667     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp209727g     Document Type: Article

References (57)

1. Sølling, T. I.; Hammerum, S.; Vulpius, V. Int. J. Mass Spectrom. 2011, 306, 175
2. Sølling, T. I.; Diau, E. W.-G.; Kötting, C.; De Feyter, S.; Zewail, A. H. ChemPhysChem 2002, 3, 79
3. Rusteika, N.; Møller, K. B.; Sølling, T. I. Chem. Phys. Lett. 2008, 461, 193
4. Brogaard, R. Y.; Sølling, T. I.; Møller, K. B. J. Phys. Chem. A 2010, 115, 556
5. Imre, D.; Kinsey, J. L.; Sinha, A.; Krenos, J. J. Phys. Chem. 1984, 88, 3956
6. Dantus, M.; Rosker, M. J.; Zewail, A. H. J. Chem. Phys. 1988, 89, 6128
7. Rose, T. S.; Rosker, M. J.; Zewail, A. H. J. Chem. Phys. 1989, 91, 7415
8. Kötting, C.; Diau, E. W.-G.; Sølling, T. I.; Zewail, A. H. J. Phys. Chem. A 2002, 106, 7530
9. Brogaard, R. Y.; Møller, K. B.; Sølling, T. I. J. Phys. Chem. A 2008, 112, 10481
10. Yue, X.-F.; Sun, J.-L.; Zhou, C.-H.; Cheng, S.-B.; Yin, H.-M.; Han, K.-L. Chem. Phys. Lett. 2008, 452, 14
11. Wayne, R. P. Chemistry of Atmospheres, 3 rd ed.; Oxford University Press: Oxford, U.K., 2000.
12. Wang, C.; Shemesh, L. G.; Deng, W.; Lilien, M. D.; Dibble, T. S. J. Phys. Chem. A 1999, 103, 8207
13. Schinke, R. Photodissociation Dynamics; Cambridge University Press: Cambridge, U.K., 1993.
14. Mestdagh, J. M.; Berdah, M.; Dimicoli, I.; Mons, M.; Meynadier, P.; d'Oliveira, P.; Piuzzi, F.; Visticot, J. P.; Jouvet, C.; Lardeux-Dedonder, C.; Martrenchard-Barra, S.; Soep, B.; Solgadi, D. J. Chem. Phys. 1995, 103, 1013
15. Rosenberg, M.; Minitti, M. P.; Rusteika, N.; Bisgaard, C. Z.; Deb, S.; Weber, P. M.; Sølling, T. I. J. Phys. Chem. A. 2010, 114, 7021
16. Rosenberg, M.; Sølling, T. I. Chem. Phys. Lett. 2010, 484, 113
17. Style, D. W. G.; Ward, J. C. Trans. Faraday Soc. 1953, 49, 999
18. Ohbayashi, K.; Akimoto, H.; Tanaka, I. J. Phys. Chem. 1977, 81, 798
19. Finke, H.; Spiecker, H.; Andresen, P. J. Chem. Phys. 1999, 110, 4777
20. Kim, B.; Thantu, N.; Weber, P. M. J. Chem. Phys. 1992, 97, 5384
21. Schick, C. P.; Weber, P. M. J. Phys. Chem. A 2001, 105, 3725
22. Cheng, W.; Kuthirummal, N.; Gosselin, J. L.; Sølling, T. I.; Weinkauf, R.; Weber, P. M. J. Phys. Chem. A 2005, 109, 1920
23. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar, S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.; Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz, J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez, C.; Pople, J. A. Gaussian 03, revision C.02; Gaussian, Inc.: Wallingford, CT, 2003.
24. Curtiss, L. A.; Redfern, P. C.; Raghavachari, K.; Rassolov, V.; Pople, J. A. J. Chem. Phys. 1999, 110, 4703
25. Nicolaides, A.; Rauk, A.; Glukhovtsev, M. N.; Radom, L. J. Phys. Chem. 1996, 100, 17460
26. Ji, M.; Zhen, J.; Zhang, Q.; Chen, Y. J. Chem. Phys. 2009, 130, 174314
27. Schick, C. P.; Carpenter, S. D.; Weber, P. M. J. Phys. Chem. A 1999, 103, 10470
28. Schultz, J. C.; Houle, F. A.; Beauchamp, J. L. J. Am. Chem. Soc. 1984, 106, 3917
29. Cheng, W.; Evans, C. L.; Kuthirummal, N.; Weber, P. M. Chem. Phys. Lett. 2001, 349, 405
30. Freund, R. S. In Rydberg States of Atoms and Molecules; Stebbings, R. F.; Dunning, F. B., Eds.; Cambridge University Press: New York, 1983; pp 355-390.
31. Minitti, M. P.; Cardoza, J. D.; Weber, P. M. J. Phys. Chem. A 2006, 110, 10212
32. Minitti, M. P.; Weber, P. M. Phys. Rev. Lett. 2007, 98, 253004
33. Kim, B.; Schick, C. P.; Weber, P. M. J. Chem. Phys. 1995, 103, 6903
34. Vrakking, M. J. J.; Lee, Y. T. Phys. Rev. A 1995, 51, R894
35. Kobayashi, T.; Takami, M. RIKEN Rev. 1997, 15, 83
36. Herzberg, G. Spectra of Diatomic Molecules; Van Nostrand: New York, 1950.
37. Schwartz-Lavi, D.; Rosenwaks, S. J. Chem. Phys. 1988, 88, 6922
38. Williams, J. M.; Hamill, W. H. J. Chem. Phys. 1968, 49, 4467
39. Yonei, T.; Hashimoto, K.; Arai, M.; Tamura, M. Energy Fuels 2003, 17, 725
40. Ihm, H.; Scheer, K.; Celio, H.; White, J. M. Langmuir 2001, 17, 786
41. Ebata, T.; Yanagishita, H.; Obi, K.; Tanaka, I. Chem. Phys. 1982, 69, 27
42. Freed, K. F.; Nitzan, A. Energy Storage and Redistribution in Molecules; Hinze, J., Ed.; Plenum: New York, 1983; p 467.
43. Freed, K. F.; Nitzan, A. J. Chem. Phys. 1980, 73, 4765
44. Freed, K. F. Acc. Chem. Res. 1977, 11, 74
45. Weber, P. M.; Thantu, N. Chem. Phys. Lett. 1992, 197, 556
46. Thantu, N.; Weber, P. M. Z. Phys. D. 1993, 28, 191
47. Thantu, N.; Weber, P. M. Chem. Phys. Lett. 1993, 214, 276
48. Bao, J.; Weber, P. M. J. Phys. Chem. Lett. 2010, 1, 224
49. Bao, J.; Minitti, M. P.; Weber, P. M. J. Phys. Chem. A 2011, 115, 1508
50. Bao, J.; Weber, P. M. J. Am. Chem. Soc. 2011, 133, 4164
51. Bühler, C. C.; Minitti, M. P.; Deb, S.; Bao, J.; Weber, P. M. J. Phys B: At., Mol. Opt. Phys., 2011, DOI: 10.1155/2011/637593.
52. Keller, B. A.; Felder, P.; Huber, J. R. J. Phys. Chem. 1987, 91, 1114
53. Keller, B. A.; Felder, P.; Huber, J. R. Chem. Phys. Lett. 1986, 124, 135
54. Effenhauser, C. S.; Felder, P.; Huber, J. R. J. Phys. Chem. 1990, 94, 296
55. Farmanara, P.; Stert, V.; Radloff, W. Chem. Phys. Lett. 1999, 303, 521
56. Tuck, A. F. J. Chem. Soc., Faraday Trans. II 1977, 73, 689
57. August, J.; Brouard, M.; Docker, M. P.; Milne, C. J.; Simons, J. P.; Lavi, R.; Rosenwaks, S.; Schwartz-Lavi, D. J. Phys. Chem. 1988, 92, 5485