Photolysis of n -butyl nitrite and isoamyl nitrite at 355 nm: A time-resolved Fourier transform infrared emission spectroscopy and ab initio study

Journal of Chemical Physics

Volumn 130, Issue 17, 2009, Pages

  Ji, Min ^a   Zhen, Junfeng ^a   Zhang, Qun ^a   Chen, Yang ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

Author keywords

[No Author keywords available]

Indexed keywords

355 NM LASERS; AB INITIO STUDIES; AB-INITIO CALCULATIONS; ALKYL NITRITES; EMISSION SPECTRUMS; FTIR; METHYL GROUPS; PHOTODISSOCIATION DYNAMICS; ROTATIONAL TEMPERATURES; TEMPORAL PROFILES; TIME-DEPENDENT DENSITY FUNCTIONAL THEORIES; TIME-RESOLVED FOURIER TRANSFORM INFRARED; UV ABSORPTION SPECTRUM; VIBRATIONAL DISTRIBUTIONS;

ATOMIC SPECTROSCOPY; DENSITY FUNCTIONAL THEORY; DYNAMICS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; HYDROCARBONS; LIGHT ABSORPTION; MOLECULAR SPECTROSCOPY; PHOTODISSOCIATION; PHOTOLYSIS; SPECTRUM ANALYSIS;

EMISSION SPECTROSCOPY;

EID: 65549112548     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3129806     Document Type: Article

References (36)

1. R. P. Wayne, Chemistry of Atmosphere, 3rd ed. (Oxford University Press, New York, 2000).
2. X. -F. Yue, J. -L. Sun, C. -H. Zhou, S. -B. Cheng, H. -M. Yin, and K. -L. Han, Chem. Phys. Lett. 0009-2614 452, 14 (2008), and references therein. 10.1016/j.cplett.2007.12.025
3. G. W. King and D. Moule, Can. J. Chem. 0008-4042 40, 2057 (1962). 10.1139/v62-316
4. R. C. Mitchell and J. P. Simons, Discuss. Faraday Soc. 0014-7664 44, 208 (1967). 10.1039/df9674400208
5. R. Vasudev, R. N. Zare, and R. N. Dixon, Chem. Phys. Lett. 0009-2614 96, 399 (1983). 10.1016/0009-2614(83)80716-7
6. F. Lahmani, C. Lardeux, and D. Solgadi, Chem. Phys. Lett. 0009-2614 102, 523 (1983). 10.1016/0009-2614(83)87458-2
7. M. Hippler, F. A. H. Al-Janabi, and J. Pfab, Chem. Phys. Lett. 0009-2614 192, 173 (1992). 10.1016/0009-2614(92)85448-J
8. H. Ihm, K. Scheer, H. Celio, and J. M. White, Langmuir 0743-7463 17, 786 (2001). 10.1021/la001144u
9. R. Vasudev, R. N. Zare, and R. N. Dixon, J. Chem. Phys. 0021-9606 80, 4863 (1984). 10.1063/1.446508
10. R. N. Dixon and H. Rieley, J. Chem. Phys. 0021-9606 91, 2308 (1989). 10.1063/1.457038
11. F. Reiche, B. Abel, R. D. Beck, and T. R. Rizzo, J. Chem. Phys. 0021-9606 112, 8885 (2000) 10.1063/1.481502; F. Reiche, B. Abel, R. D. Beck, and T. R. Rizzo, J. Chem. Phys. 0021-9606 116, 10267 (2002). 10.1063/1.1471236
12. F. Lahmani, C. Lardeux, and D. Solgadi, Chem. Phys. Lett. 0009-2614 129, 24 (1986). 10.1016/0009-2614(86)80162-2
13. U. Brühlmann, M. Dubs, and J. R. Huber, J. Chem. Phys. 0021-9606 86, 1249 (1987). 10.1063/1.452214
14. J. W. Winniczek, R. L. Dubs, J. R. Appling, V. McKoy, and M. G. White, J. Chem. Phys. 0021-9606 90, 949 (1989). 10.1063/1.456120
15. H. -M. Yin, J. -L. Sun, Y. -M. Li, K. -L. Han, G. -Z. He, and S. -L. Cong J. Chem. Phys. 0021-9606 118, 8248 (2003). 10.1063/1.1565311
16. D. Schwartz-Lavi, I. Bar, and S. Rosenwaks, Chem. Phys. Lett. 0009-2614 128, 123 (1986). 10.1016/0009-2614(86)80309-8
17. D. Schwartz-Lavi and S. Rosenwaks, J. Chem. Phys. 0021-9606 88, 6922 (1988). 10.1063/1.454389
18. H. Finke, H. Spiecker, and P. Andresen, J. Chem. Phys. 0021-9606 110, 4777 (1999). 10.1063/1.478364
19. K. J. Castle, J. Abbott, X. Peng, and W. Kong, Chem. Phys. Lett. 0009-2614 318, 565 (2000). 10.1016/S0009-2614(00)00079-8
20. X. -F. Yue, J. -L. Sun, H. -M. Yin, Q. Wei, and K. -L. Han, J. Phys. Chem. A 1089-5639 113, 3303 (2009). 10.1021/jp810731d
21. P. R. Griffiths and J. A. de Haseth, Fourier Transform Infrared Spectroscopy (Wiley, New York, 1986).
22. J. J. Sloan and E. J. Kruus, in Time-resolved Spectroscopy, Advances in Spectroscopy, edited by, R. J. H. Clark, and, R. E. Hester, (Wiley, New York, 1989).
23. H. L. Welsh, C. Cumming, and E. J. Stansbury, J. Opt. Soc. Am. 0030-3941 41, 712 (1951). 10.1364/JOSA.41.000712
24. R. E. Murphy, F. Cook, and H. Sakai, J. Opt. Soc. Am. 0030-3941 65, 600 (1975). 10.1364/JOSA.65.000600
25. G. V. Hartland, W. Xie, and H. L. Dai, Rev. Sci. Instrum. 0034-6748 63, 3261 (1992). 10.1063/1.1143815
26. O. Benoist D'azy, F. Lahmani, C. Lardeux, and D. Solgadi, Chem. Phys. 0301-0104 94, 247 (1985). 10.1016/0301-0104(85)85080-1
27. G. Herzberg, Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecules (Van Nostrand, Princeton, 1950).
28. U. Brühlmann and J. R. Huber, Chem. Phys. Lett. 0009-2614 143, 199 (1988). 10.1016/0009-2614(88)87037-4
29. J. M. Brown, A. R. H. Cole, and F. R. Honey, Mol. Phys. 0026-8976 23, 287 (1972). 10.1080/00268977200100291
30. J. Calvert and J. Pitts, Photochemistry (Wiley, New York, 1966), p. 455.
31. M. J. Frisch, G. W. Trucks, H. B. Schlegel, GAUSSIAN 03 (Gaussian Inc., Wallingford, CT, 2004).
32. R. P. McLaughlin, W. A. Donald, D. Jitjai, and Y. Zhang, Spectrochim. Acta, Part A 0584-8539 67, 178 (2007). 10.1016/j.saa.2006.06.042
33. The calculated potential energy curves shown in Fig. exhibit repulsive nature, which do not contradict the divisive vibrational structure of the UV absorption spectra shown in Fig.. For detailed discussions in this regard, refer to Refs..
34. V. Engel, R. Schinke, S. Hennig, and H. Metiu, J. Chem. Phys. 0021-9606 92, 1 (1990). 10.1063/1.458463
35. W. Zhao, I. Lee, S. K. Kim, and J. M. White, J. Phys. Chem. B 1089-5647 108, 14276 (2004). 10.1021/jp049829g
36. X. Wang, Y. Wang, C. Lv, M. Kubo, and A. Miyamoto, J. Photochem. Photobiol., A 1010-6030 187, 119 (2007). 10.1016/j.jphotochem.2006.10.004