Synthesis, coordination behavior, and reduction chemistry of cymantrenyl-1,3-bis(2,3,4,5-tetraphenyl)borole

Chemistry - A European Journal

Volumn 18, Issue 27, 2012, Pages 8430-8436

  Braunschweig, Holger ^a   Damme, Alexander ^a   Gamon, Daniela ^a   Kelch, Hauke ^a   Krummenacher, Ivo ^a   Kupfer, Thomas ^a   Radacki, Krzysztof ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

aromaticity; boroles; cymantrene; electrochemistry; reduction

Indexed keywords

ANTHRACENE; CHEMICAL BONDS; COORDINATION REACTIONS; ELECTROCHEMISTRY; MAGNESIUM COMPOUNDS; MANGANESE COMPOUNDS; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL);

AROMATICITIES; BONDING INTERACTIONS; BOROLES; CHEMICAL REDUCTION; COORDINATION BEHAVIOR; CYMANTRENE; LEWIS ACID-BASE ADDUCTS; SPECTROSCOPIC STUDIES;

REDUCTION;

EID: 84862743739     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201200284     Document Type: Article

References (34)

1. J. J. Eisch, J. E. Galle, S. Kozima, J. Am. Chem. Soc. 1986, 108, 379
2. J. J. Eisch, N. K. Hota, S. J. Kozima, J. Am. Chem. Soc. 1969, 91, 4575
3. J. J. Eisch, J. E. Galle, J. Am. Chem. Soc. 1975, 97, 4436
4. J. J. Eisch, J. E. Galle, J. Organomet. Chem. 1977, 127, C 9
5. J. J. Eisch, J. E. Galle, B. Shafi, A. L. Rheingold, Organometallics 1990, 9, 2342
6. P. J. Fagan, E. G. Burns, J. C. Calabrese, J. Am. Chem. Soc. 1988, 110, 2979
7. H. Braunschweig, T. Kupfer, Chem. Commun. 2011, 47, 10903.
8. K. Ansorg, H. Braunschweig, C.-W. Chiu, B. Engels, D. Gamon, M. Hügel, T. Kupfer, K. Radacki, Angew. Chem. 2011, 123, 2885
9. Angew. Chem. Int. Ed. 2011, 50, 2833
10. H. Braunschweig, F. Breher, C.-W. Chiu, D. Gamon, D. Nied, K. Radacki, Angew. Chem. 2010, 122, 9159
11. Angew. Chem. Int. Ed. 2010, 49, 8975
12. H. Braunschweig, C.-W. Chiu, J. Wahler, K. Radacki, T. Kupfer, Chem. Eur. J. 2010, 16, 12229
13. H. Braunschweig, S. Ghosh, T. Kupfer, K. Radacki, J. Wahler, Chem. Eur. J. 2011, 17, 4081
14. H. Braunschweig, C.-W. Chiu, A. Damme, K. Ferkinghoff, K. Kraft, K. Radacki, J. Wahler, Organometallics 2011, 30, 3210
15. H. Braunschweig, T. Kupfer, Chem. Commun. 2008, 4487.
16. C. Fan, W. E. Piers, M. Parvez, Angew. Chem. 2009, 121, 2999
17. Angew. Chem. Int. Ed. 2009, 48, 2955
18. C. Fan, W. E. Piers, M. Parvez, R. McDonald, Organometallics 2010, 29, 5132
19. C. Fan, L. G. Mercier, W. E. Piers, M. Parvez, J. Am. Chem. Soc. 2010, 132, 9604.
20. H. Braunschweig, I. Fernández, G. Frenking, T. Kupfer, Angew. Chem. 2008, 120, 1977
21. Angew. Chem. Int. Ed. 2008, 47, 1951.
22. H. Braunschweig, A. Damme, D. Gamon, T. Kupfer, K. Radacki, Inorg. Chem. 2011, 50, 4250.
23. G. E. Herberich, B. Buller, B. Hessner, W. Oschmann, J. Organomet. Chem. 1980, 195, 253
24. C.-W. So, D. Watanabe, A. Wakamiya, S. Yamaguchi, Organometallics 2008, 27, 3496.
25. H. Braunschweig, M. Kraft, S. Schwarz, F. Seeler, S. Stellwag, Inorg. Chem. 2006, 45, 5275
26. H. Braunschweig, H. Bera, S. Stellwag, S. Schwarz, Y. Hemberger, Z. Anorg. Allg. Chem. 2007, 633, 2314
27. K. Kunz, H. Vitze, M. Bolte, H.-W. Lerner, M. Wagner, Organometallics 2007, 26, 4663
28. U. D. Eckersberger, M. Weber, M. Bolte, H.-W. Lerner, M. Wagner, Organometallics 2010, 29, 5301.
29. H. Braunschweig, C.-W. Chiu, D. Gamon, M. Kaupp, I. Krummenacher, T. Kupfer, K. Kraft, R. Müller, K. Radacki, Chem. Eur. J. submitted.
30. J. S. Merola, R. A. Gentille, G. B. Ansell, M. A. Modrick, S. Zeritz, Organometallics 1982, 1, 1731.
31. W. E. Geiger, Organometallics 2007, 26, 5738-5765, and references therein.
32. For literature values, see:, I. Noviandri, K. N. Brown, D. S. Fleming, P. F. Gulyas, P. A. Lay, A. F. Masters, L. Phillips, J. Phys. Chem. B 1999, 103, 6713.
33. U. D. Eckersberger, K. Kunz, M. Bolte, H.-W. Lerner, M. Wagner, Organometallics 2008, 27, 764.
34. G. Sheldrick, Acta Crystallogr. Sect. A 2008, 64, 112-122.