Rates of water exchange on the [Fe 4(OH) 2(hpdta) 2(H 2O) 4] 0 molecule and its implications for geochemistry

Inorganic Chemistry

Volumn 51, Issue 12, 2012, Pages 6731-6738

  Panasci, Adele F ^a   Ohlin, C André ^a,b   Harley, Stephen J ^a,c   Casey, William H ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b MONASH UNIVERSITY   (Australia)

^c LAWRENCE LIVERMORE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FERROUS ION; WATER;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; SYNTHESIS;

FERROUS COMPOUNDS; MODELS, MOLECULAR; WATER;

EID: 84862527674     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic300370q     Document Type: Article

References (36)

1. 2 functional groups on a nanometer-size aqueous cluster and bulk solution Inorg. Chem. 2007, 46 (17) 7087-7092
2. Schmitt, W.; Anson, C. E.; Sessoli, R.; van Veen, M.; Powell, A. K. Biomimetic hydrolytic activation by Fe(III) aggregates: structures, reactivity and properties of novel oxo-bridged iron complexes J. Inorg. Biochem. 2002, 91 (1) 173-189 (Pubitemid 34727769)
3. Grant, M.; Jordan, R. B. Kinetics of solvent water exchange on iron(III) Inorg. Chem. 1981, 20 (1) 55-60
4. Mizuno, M.; Funahashi, S.; Nakasuka, N.; Tanaka, M. Water exchange of the (o -phenylenediamine- N, N, N ′, N ′-tetraacetato)ferrate(III) complex in aqueous solution as studied by variable-temperature, -pressure, and -frequency oxygen-17 NMR techniques Inorg. Chem. 1991, 30 (7) 1550-1553
5. Kumar, P.; Kumar, M.; Ramanathan, A.; Tsujimura, M. Tracing the factors responsible for arsenic enrichment in groundwater of the middle Gangetic Plain, India: A source identification perspective Environmental Geochemistry and Health 2010, 32 (2) 129-146
6. Rustad, J. R. Elementary reactions in polynuclear ions and aqueous-mineral interfaces: A new geology Adv. Inorg. Chem. 2010, 62, 391-436
7. Wang, J.; Rustad, J. R.; Casey, W. H. Calculation of water-exchange rates on aqueous polynuclear clusters and at oxide-water interfaces Inorg. Chem. 2007, 46 (8) 2962-2964
8. Swaddle, T. W.; Merbach, A. E. High-pressure oxygen-17 Fourier transform nuclear magnetic resonance spectroscopy. Mechanism of water exchange on iron(III) in acidic aqueous solution Inorg. Chem. 1981, 20 (12) 4212-4216
9. 17O NMR study Angew. Chem., Int. Ed. 2001, 40 (9) 1678-1680 (Pubitemid 32441077)
10. Ostrich, I. J.; Liu, G.; Dodgen, H. W.; Hunt, J. P. Oxygen-17 nuclear magnetic resonance study of water exchange on water-soluble iron(III) porphyrins Inorg. Chem. 1980, 19 (3) 619-621
11. III complexes: synthesis, molecular structure, reactivity, and magnetic properties Inorg. Chem. 2007, 46 (3) 756-766
12. Schmitt, W.; Hill, J. P.; Juanico, M. P.; Caneschi, A.; Costantino, F.; Anson, C. E.; Powell, A. K. Supramolecular coordination assemblies of dinuclear FeIII complexes Angew. Chem., Int. Ed. 2005, 44 (27) 4187-4192 (Pubitemid 40982721)
13. Murugesu, M.; Clerac, R.; Wernsdorfer, W.; Anson, C. E.; Powell, A. K. Hierarchical assembly of [Fe13] oxygen-bridged clusters into a close-packed superstructure Angew. Chem., Int. Ed. 2005, 44 (41) 6678-6682 (Pubitemid 41532209)
14. Powell, G., W.; Lancashire, H., N.; Brechin, E., K.; Collison, D.; Heath, S., L.; Mallah, T.; Wernsdorfer, W. Building molecular minerals: all ferric pieces of molecular magnetite Angew. Chem., Int. Ed. 2004, 43 (43) 5772-5 (Pubitemid 39532031)
15. Schmitt, W.; Anson, C. E.; Pilawa, B.; Powell, A. K. Investigation of the hydrolytic build-up of iron(III)-oxo-aggregates Z. Anorg. Allg. Chem. 2002, 628 (11) 2443-2457
16. Schmitt, W.; Murugesu, M.; Goodwin, J. C.; Hill, J. P.; Mandel, A.; Bhalla, R.; Anson, C. E.; Heath, S. L.; Powell, A. K. Strategies for producing cluster-based magnetic arrays Polyhedron 2001, 20 (11-14) 1687-1697 (Pubitemid 32619492)
17. Panasci, A. F.; McAlpin, J. G.; Ohlin, C. A.; Christensen, S.; Fettinger, J. C.; Britt, R. D.; Rustad, J. R.; Casey, W. H. Cooperation between bound waters and hydroxyls in controlling isotope-exchange rates Geochim. Cosmochim. Acta 2012, 78 (1) 18-27
18. Catalano, J. G.; Fenter, P.; Park, C. Water ordering and surface relaxations at the hematite (110)-water interface Geochim. Cosmochim. Acta 2009, 73 (8) 2242-2251
19. Schmitt, W.; Jordan, P. A.; Henderson, R. K.; Moore, G. R.; Anson, C. E.; Powell, A. K. Synthesis, structures and properties of hydrolytic Al(III) aggregates and Fe(III) analogues formed with iminodiacetate-based chelating ligands Coord. Chem. Rev. 2002, 228 (2) 115-126
20. Schmitt, W.; Anson, C. E.; Pilawa, B.; Powell, A. K. Untersuchung von hydrolysereaktionen zum aufbau von eisen(III)-oxo-aggregaten Z. Anorg. Allg. Chem. 2002, 628 (11) 2443-2457
21. Ballard, L.; Reiner, C.; Jonas, J. High-resolution NMR probe for experiments at high pressures J. Magn. Reson., Ser. A 1996, 123 (1) 81-86 (Pubitemid 126751995)
22. 17 in aqueous solutions of paramagnetic cations and the lifetime of water molecules in the first coordination sphere J. Chem. Phys. 1962, 37, 307-20
23. Harley, S. J.; Ohlin, C. A.; Casey, W. H. Geochemical kinetics via the Swift-Connick equations and solution NMR Geochim. Cosmochim. Acta 2011, 75, 3711-3725
24. Frans, S. D.; Harris, J. M. Reiterative least-squares spectral resolution of organic acid/base mixtures Anal. Chem. 1984, 56, 466-470 (Pubitemid 14526107)
25. Baes, C. F.; Mesmer, R. E. The Hydrolysis of Cations; Wiley: New York, 1976.
26. Ohlin, C. A.; Villa, E. M.; Rustad, J., R.; Casey, W. H. The dissolution of insulating oxides at the molecular scale Nat. Mater. 2010, 9, 11-19
27. Richens, D. Structure-property relationships in polynuclear μ-O bridged aqua clusters: effect of M-μ-O bond covalency Comments on Inorganic Chemistry 2005, 26 (5-6) 217-232 (Pubitemid 41780071)
28. Gorun, S. M.; Lippard, S. J. Magnetostructural correlations in magnetically coupled (μ-oxo)diiron(III) complexes Inorg. Chem. 1991, 30, 1625-1630
29. Richens, D. T. The Chemistry of Aqua Ions. John Wiley: New York, 1997; p 592 pp.
30. Helm, L.; Merbach, A. E. Inorganic and bioinorganic solvent exchange mechanisms Chem. Rev. 2005, 105 (6) 1923-1959 (Pubitemid 40947946)
31. Swaddle, T. W. Volumes of activation and mechanistic assignments in octahedral substitution Inorg. Chem. 1980, 19 (10) 3203-3205
32. Swaddle, T. W. On the mechanism of octahedral substitution Comments on Inorganic Chemistry 1991, 12 (4) 237-58
33. Hubbard, C. D.; Van Eldik, R. Mechanistic information on some inorganic and bioinorganic reactions from volume profile analysis Inorg. Chim. Acta 2010, 363, 2357-2374
34. Schneppensieper, T.; Seibig, S.; Zahl, A.; Tregloan, P.; van Eldik, R. Influence of chelate effects on the water-exchange mechanism of polyaminecarboxylate complexes of iron(III) Inorg. Chem. 2001, 40 (15) 3670-3676 (Pubitemid 32861726)
35. Ducommun, Y.; Newman, K. E.; Merbach, A. E. High-pressure oxygen-17 NMR evidence for a gradual mechanistic changeover from Ia to Id for water exchange on divalent octahedral metal ions going from manganese(II) to nickel(II) Inorg. Chem. 1980, 19, 3696-3703
36. 2 Inorg. Chem. 2007, 46 (13) 5361-5371