A unified kinetic model for phenol photocatalytic degradation over TiO 2 photocatalysts

Chemical Engineering Science

Volumn 78, Issue , 2012, Pages 186-203

  Moreira, Jesus ^a   Serrano, Benito ^b   Ortiz, Aaron ^a   de Lasa, Hugo ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

^b UNIVERSIDAD AUTÓNOMA DE ZACATECAS   (Mexico)

Author keywords

Adsorption constants; Kinetics; Langmuir Hinshelwood; Parameter estimation; Photocatalysis; Reaction engineering

Indexed keywords

ADSORPTION CONSTANT; BENZOQUINONES; CROSS CORRELATIONS; INTERMEDIATE SPECIE; KINETIC MODELS; LANGMUIR-HINSHELWOOD; LANGMUIR-HINSHELWOOD KINETICS; OBJECTIVE PARAMETERS; PHOTO CATALYTIC DEGRADATION; PHOTOCONVERSION; REACTION ENGINEERING; REACTION NETWORK; SERIES-PARALLEL; TIO;

ADSORPTION; ENZYME KINETICS; FORMIC ACID; KETONES; KINETIC THEORY; PARAMETER ESTIMATION; PHENOLS; PHOTOCATALYSIS; PHOTOCATALYSTS; PHOTODEGRADATION; REACTION KINETICS; TITANIUM DIOXIDE;

KINETICS;

EID: 84861975310     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2012.04.033     Document Type: Article

References (54)

1. Alfano O.M., Bahnemann D., Cassano O.M., Dillert R., Goslich R. Photocatalysis in water environments using artificial and solar light. Catal. Today 2000, 58:199-230.
2. Ahmed S., Rasul M.G., Martens W.N., Brown R., Hashib M.A. Advances in heterogeneous photocatalytic degradation of phenols and dyes in wastewaters: a review. Water Air Soil Pollut. 2011, 215:3-29.
3. 2). Desalination 2004, 166:355-362.
4. Bellobono I.R., Bianchi R., de Martini G., Tozzi P.M., Bonardi M.L., Groppi F., Rossi M. Nonlinear modeling of data in photomineralization kinetics of organic micropollutants by photocatalytic membranes immobilizing titanium dioxide in membrane reactors. J. Chem. 2008, 22:425-435.
5. Bellobono I.R., Scotti R., D'Arienzo M., Mrazzoni F., Bianchi R., Stanescu R., Costache C., Bobirica L., Cobzaru G., Tozzi P.M., Rossi M., Bonardi M.L., Groppi F., Gini L. Nonlinear modeling of kinetic data obtained from photocatalytic mineralization of 2,4-dichlorophenol on a titanium dioxide membrane. Int. J. Photoenergy 2009, 631768:1-10.
6. 2/ACF. Trans. Nonferrous Met. Soc. China 2003, 13:452-456.
7. 2 by inorganic ions. J. Photochem. Photobiol. A: Chem. 1997, 108:37-44.
8. Chong M.N., Jin B., Chow C.W.K., Saint C. Recent developments in photocatalytic water treatment technology: a review. Water Res. 2010, 44:2997-3027.
9. Colmenares J.C., Aramendia M.A., Marinas A., Marinas J.M., Urbano F.J. Synthesis, characterization and photocatalytic activity of different metal-doped titania systems. Appl. Catal. A: Gen. 2006, 306:120-127.
10. de Lasa H., Serrano B., Salaices M. Photocatalytic Reaction Engineering 2005, Springer, New York.
11. El Solh T., Jarosch K., de Lasa H. Catalytic dry reforming of methane in a CREC Riser simulator kinetic modeling and model discrimination. Ind. Eng. Chem. Res. 2003, 42:2507-2515.
12. Fujishima A., Zhang X. Titanium dioxide photocatalysis: present situation and future approaches. C. R. Chim. 2006, 9:750-760.
13. 2 photocatalysis and related surface phenomena. Surf. Sci. Rep. 2008, 63:515-582.
14. Gaya U.I., Abdullaha A.H. Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: a review of fundamentals, progress and problems. J. Photochem. Photobiol. C: Photochem. Rev. 2008, 9:1-12.
15. Gora A., Toepfer B., Puddu V., Li Puma G. Photocatalytic oxidation of herbicides in single-component and multicomponent systems: reaction kinetics analysis. Appl. Catal. B: Environ. 2006, 65:1-10.
16. He Z., Xie L., Tu J., Song S., Lie W., Liu Z., Fan J., Liu Q., Chen J. Visible light-induced degradation of phenol over iodine-doped titanium dioxide modified with platinum: role of platinum and the reaction mechanism. J. Phys. Chem. C 2010, 114:526-532.
17. Herrmann J.M. Heterogeneous photocatalysis: fundamentals and applications to the removal of various types of aqueous pollutants. Catal. Today 1999, 53:115-129.
18. Hernandez-Alonso M.D., Coronado J.M., Maira A.J., Soria J., Loddob V., Augugliaro V. Ozone enhanced activity of aqueous titanium dioxide suspensions for photocatalytic oxidation of free cyanide ions. Appl. Catal. B: Environ. 2002, 39:257-267.
19. 2. J. Photochem. Photobiol. A: Chem. 2003, 159:61-70.
20. 2 photocatalysis in a helical reactor. Global NEST J. 2008, 10:404-418.
21. 2 surfaces: principles, mechanisms, and selected results. Chem. Rev. 1995, 95:735-758.
22. Li Puma G. Dimensionless analysis of photocatalytic reactors using suspended solid photocatalysts. Chem. Eng. Res. Des. 2005, 83:820-826.
23. Li Puma G., Toepfer B., Gora A. Photocatalytic oxidation of multicomponent systems of herbicides: scale-up of laboratory kinetics rate data to plant scale. Catal. Today 2007, 124:124-132.
24. Mehrvar M., Anderson W.A., Moo-Young M., Reilly P.M. Non-linear parameter estimation for a dynamic model in photocatalytic reaction engineering. Chem. Eng. Sci. 2000, 55:4885-4891.
25. 2 aqueous dispersions. Appl. Catal. B: Environ. 2009, 88:50-58.
26. Moreira del Rio, J., 2011. Photocatalytic Degradation of Phenolic Compounds in Water: Irradiation and Kinetic Modeling. Ph.D. Thesis. The University of Western Ontario.
27. 2 slurry reactor using Monte Carlo simulations and macroscopic balance. Ind. Eng. Chem. Res. 2010, 49:10524-10534.
28. 2 absorption and scattering coefficients using Monte Carlo method and macroscopic balances in a photo-CREC unit. Chem. Eng. Sci. 2011, 66(23):5813-5821.
29. Ortiz-Gomez, A., 2006. Enhanced Mineralization of Phenol and Other Hydroxylated Compounds in a Photocatalytic Process Assisted with Ferric Ions. Ph.D. Thesis. The University of Western Ontario.
30. Ortiz-Gomez A., Serrano-Rosales B., de Lasa H. Enhanced mineralization of phenol and other hydroxylated compounds in a photocatalytic process assisted with ferric ions. Chem. Eng. Sci. 2008, 63:520-557.
31. Ortiz-Gomez A., Serrano-Rosales B., Moreira-del-Rio J., de-Lasa H. Mineralization of phenol in an improved photocatalytic process assisted with ferric ions: reaction network and kinetic modeling. Advances in chemical engineering Volume 36: Photocatalytic Technologies 2009, 69-108. Elsevier, New York. H. de Lasa, B. Serrano Rosales (Eds.).
32. Ortiz-Gomez A., Serrano-Rosales B., Salaices M., de Lasa H. Photocatalytic oxidation of phenol: reaction network, kinetic modeling, and parameter estimation. Ind. Eng. Chem. Res. 2007, 46:7394-7409.
33. Pareek V. Light intensity distribution in a dual-lamp photoreactor. Int. J. Chem. React. Eng. 2005, 3:1-11.
34. Pareek V.K., Adesina A.A. Light intesity distribution in a photocatalytic reactor using finite volume. AIChE J. 2004, 50:1273-1288.
35. Ray A.K., Chen D., Li F. Effect of mass transfer and catalyst layer thickness on photocatalytic reaction. AIChE J. 2000, 46:1034-1045.
36. 2 surface. Appl. Surf. Sci. 2000, 167:51-58.
37. Rota F., Cavassi M., Niego D., Gorlani R., Vianelli L., Tatti L., Bruzzi P., Moroni A., Bellobono I.R. Mathematical modelling of photomineralization of phenols in aqueous solution, by photocatalytic membranes immobilizing titanium dioxide. Chemesphere 1996, 33:2159-2173.
38. Salaices-Arredondo, M., 2002. Photocatalysis in Slurry Reactors Radiation Transmission and Kinetic, Modeling. Ph.D. Thesis. The University of Western Ontario.
39. 2 slurry reactor. Chem. Eng. J. 2002, 90:219-229.
40. Salaices M., Serrano B., de Lasa H.I. Photocatalytic conversion of phenolic compounds in slurry reactors. Chem. Eng. Sci. 2004, 59:3-15.
41. Selvam K., Muruganandham M., Muthuvel I., Swaminathan M. The influence of inorganic oxidants and metal ions on semiconductor sensitized photodegradation of 4-fluorophenol. Chem. Eng. J. 2007, 128:51-57.
42. Serpone N. Brief introductory remarks on heterogeneous photocatalysis. Sol. Energy Mater. Sol. Cells 1995, 38:369-379.
43. Serrano B., de Lasa H. Photocatalytic degradation of water organic pollutants. Kinetic modeling and energy efficiency. Ind. Eng. Chem. Res. 1997, 36:4705-4711.
44. Serrano B., Ortiz A., Moreira J., de Lasa H.I. Energy efficiency in photocatalytic reactors for the full span of reaction times. Ind. Eng. Chem. Res. 2009, 48:9864-9876.
45. Serrano B., Ortiz A., Moreira J., de Lasa H.I. Photocatalytic thermodynamic efficiency factors. Practical limits in photocatalytic reactors. Ind. Eng. Chem. Res. 2010, 49:6824-6833.
46. 2. Appl. Catal. B: Environ. 2004, 51:67-76.
47. 2: an attempt to solve the reaction mechanism. J. Mol. Catal. A: Chem. 2004, 213:225-230.
48. Tatti L., Niego D., Rota F., Bruzzi P., Moroni A., Bellobono I.R., Bonardi M., Bianchi M., Mantau H. Mathematical modelling of pilot-plant photomineralization of chlrorophenols in aqueous solution, by photocatalytic membranes immobilizing titanium dioxide. Chemosphere 1997, 34:41-49.
49. Trillas M., Pujol M., Domenech.X. Phenol photodegradation over titanium dioxide. J. Chem. Technol. Biotechnol. 1992, 55:85-90.
50. 2 photocatalysts. Appl. Catal. B: Environ. 2006, 63:215-221.
51. Vinu R., Madras G. Environmental remediation by photocatalysis. J. Indian Inst. Sci. 2010, 90:189-230.
52. 2-photocatalyzes degradation of acetophenone under different light intensities. J. Photochem. Photobiol. A: Chem. 2000, 133:67-71.
53. Zalazar C.S., Romero R.L., Martín C.A., Cassano A.E. Photocatalytic intrinsic eaction kinetics I: mineralization of dichloroacetic acid. Chem. Eng. Sci. 2005, 60:5240-5254.
54. 2. Ind. Eng. Chem. Res. 2006, 45:3503-3511.