Sequential energy and electron transfer in polynuclear complex sensitized TiO 2 nanoparticles

Journal of Physical Chemistry Letters

Volumn 3, Issue 11, 2012, Pages 1543-1548

  Verma, Sandeep ^a   Kar, Prasenjit ^b   Banerjee, Tanmay ^b   Das, Amitava ^b   Ghosh, Hirendra N ^a  

^a BHABHA ATOMIC RESEARCH CENTRE   (India)

^b CSIR CENTRAL SALT AND MARINE CHEMICALS RESEARCH INSTITUTE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE RECOMBINATION REACTIONS; CORE ACTIVITY; CORE PART; ELECTRON-TRANSFER; ELECTRONIC COUPLING; FUNCTIONALIZED; INTRAMOLECULAR ENERGY TRANSFER; POLYNUCLEAR COMPLEXES; POSITIVE CHARGES; TIME DOMAIN; TIO; TRANSIENT ABSORPTION SPECTROSCOPIES; TRINUCLEAR COMPLEX; ULTRA-FAST;

ENERGY TRANSFER; EXCITATION ENERGY; NANOPARTICLES; OSMIUM;

TITANIUM DIOXIDE;

EID: 84861843623     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz3005305     Document Type: Article

References (25)

1. Pullerits, T.; Sundström, V. Photosynthetic Light-Harvesting Pigment-Protein Complexes: Toward Understanding How and Why Acc. Chem. Res. 1996, 29, 381-389
2. Wasielewski, M. R. Energy, Charge, and Spin Transport in Molecules and Self-Assembled Nanostructures Inspired by Photosynthesis J. Org. Chem. 2006, 71, 5051-5066
3. Gust, D; Moore, A. T.; Moore, A. L. Molecular Mimicry of Photosynthetic Energy and Electron Transfer Acc. Chem. Res. 1993, 26, 198-205
4. Karlsson, S.; Boixel, J.; Pellegrin, Y.; Blart, E.; Becker, H. -C.; Odobel, F.; Hammarström, L. Accumulative Charge Separation Inspired by Photosynthesis J. Am. Chem. Soc. 2010, 132, 17977-17979
5. Wasielewski, M. R. Photoinduced Electron Transfer in Supramolecular Systems for Artificial Photosynthesis Chem. Rev. 1992, 92, 435-461
6. Balzani, V.; Juris, A.; Venturi, M. Luminescent and Redox-Active Polynuclear Transition Metal Complexes Chem. Rev. 1996, 96, 759-833
7. D'Alessandro, D. M.; Keene, F. R. Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium Chem. Rev. 2006, 106, 2270-2298
8. Campagna, S.; Pietro, C. D.; Loiseau, F.; Maubert, B.; McClenaghan, N.; Passalacqua, R.; Puntoriero, F.; Ricevuto, V.; Serroni, S. Recent Advances in Luminescent PolymetallicDendrimers Containing the 2,3-Bis(2′-pyridyl) Pyrazine Bridging Ligand Coord. Chem. Rev. 2002, 229, 67-74
9. Serroni, S.; Juris, A.; Venturi, M.; Campagna, S.; Resino, I. R.; Denti, G.; Credi, A.; Balzani, V. Polynuclear Metal Complexes of Nanometre Size. A Versatile Synthetic Strategy Leading to Luminescent and Redox-Active Dendrimers Made of an Osmium(II)-Based Core and Ruthenium(II)-Based Units in The Branches J. Mater. Chem. 1997, 7, 1227-1236
10. Richter, M. M.; Brewer, K. J. Investigation of The Spectroscopic, Electrochemical, and Spectroelectrochemical Properties Of Osmium (II) Complexes Incorporating Polyazine Bridging Ligands: Formation of The Os/Os And Os/Ru Mixed-Valence Complexes Inorg. Chem. 1993, 32, 2827-2834
11. Molecular Level Artificial Photosynthetic Materials (Progress in Inorganic Chemistry); Meyer, G. J., Ed.; John Wiley & Sons: New York, 1996; Vol. 44.
12. Bignozzi, C. A.; Argazzi, R.; Kleverlaan, C. J. Molecular and Supramolecular Sensitization of Nanocrystalline Wide Band-Gap Semiconductors with Mononuclear and Polynuclear Metal Complexes Chem. Soc. Rev. 2000, 29, 87-96
13. Balzani, V.; Campagna, S.; Denti, G.; Juris, A.; Serroni, S.; Venturi, M. Designing Dendrimers Based on Transition-Metal Complexes. Light-Harvesting Properties and Predetermined Redox Patterns Acc. Chem. Res. 1998, 31, 26-34
14. Denti, G.; Serroni, S.; Campagna, S.; Ricevuto, V.; Balzani, V. Made-to-Order Control of the Direction of Electronic Energy Transfer in Tetranuclear Luminescent Metal Complexes Coord. Chem. Rev. 1991, 111, 227-236
15. Denti, G.; Campagna, S.; Serroni, S.; Ciano, M.; Balzani, V. Decanuclear Homo- and Heterometallic Polypyridine Complexes: Syntheses, Absorption Spectra, Luminescence, Electrochemical Oxidation, and Intercomponent Energy Transfer J. Am. Chem. Soc. 1992, 114, 2944-2950
16. 2 J. Am. Chem. Soc. 1998, 120, 5480-5487
17. Baudin, H. B.; Davidsson, J.; Serroni, S.; Juris, A.; Balzani, V.; Campagna, S.; Hammarström, L. Ultrafast Energy Transfer in Binuclear Ruthenium-Osmium Complexes as Models for Light-Harvesting Antennas J. Phys. Chem. A 2002, 106, 4312-4319
18. Puntoriero, F.; Serroni, S.; Galletta, M.; Juris, A.; Licciardello, A.; Chiorboli, C.; Campagna, S.; Scandola, F. A New Heptanuclear Dendritic Ruthenium (II) Complex Featuring Photoinduced Energy Transfer Across High-Energy Subunits ChemPhysChem 2005, 6, 129-138
19. 2 Surfaces: An Ultrafast Time-Resolved Absorption Study Chem. Eur. J. 2010, 16, 611-619
20. 2 Nanoparticle Surface Sensitized by New Catechol Derivatives of Os(II)-Polypyridyl Complexes: Monitoring by Charge-Transfer Emission J. Phys. Chem. C 2008, 112, 2918-2926
21. 2 Photoelectrodes J. Phys. Chem. B 2004, 108, 15640-15651
22. Verma, S.; Gupta, A.; Sainis, J. K.; Ghosh, H. N. Employing a Photosynthetic Antenna Complex to Interfacial Electron Transfer on ZnO Quantum Dot J. Phys. Chem. Lett. 2011, 2, 858-862
23. Bhasikuttan, A. C.; Suzuki, M.; Nakashima, S.; Okada, T. Ultrafast Fluorescence Detection in Tris(2,2′-bipyridine)ruthenium(II) Complex in Solution: Relaxation Dynamics Involving Higher Excited States J. Am. Chem. Soc. 2002, 124, 8398-8405
24. 2+ J. Phys. Chem. A 1999, 103, 8440-8446
25. 2 (Anatase) Electrodes J. Phys. Chem. B 1999, 103, 7860-7868