Active Site Transformation During the Induction Period of Ethylene Polymerization over the Phillips CrO x/SiO 2 Catalyst

ChemCatChem

Volumn 4, Issue 6, 2012, Pages 872-881

  Zhong, Lei ^a   Liu, Zhen ^a   Cheng, Ruihua ^a   Tang, Siyang ^a   Qiu, Pengyuan ^a   He, Xuelian ^a   Terano, Minoru ^b   Liu, Boping ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b JAPAN ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY   (Japan)

Author keywords

Adsorption; Heterogeneous catalysis; Metathesis; Reaction mechanisms; Spin crossover

Indexed keywords

1-BUTENE; 1-HEXENE; ACCELERATION EFFECTS; ACTIVE SITE; CLUSTER MODELS; ELECTRONIC DONATION; ETHYLENE POLYMERIZATION; INDUCTION PERIODS; INITIATION MECHANISM; METATHESIS; PHILLIPS; PHILLIPS CATALYSTS; POLYETHYLENE PRODUCTION; REACTION MECHANISM; RESEARCH EFFORTS; RING EXPANSION; SPIN CROSSOVERS; SPIN STATE; STERIC HINDRANCES;

ADSORPTION; BUTENES; CATALYSIS; CHROMIUM COMPOUNDS; COORDINATION REACTIONS; DESORPTION; ETHYLENE; FORMALDEHYDE; MOLECULES; POLYMERIZATION; PROPYLENE;

CATALYST ACTIVITY;

EID: 84861539958     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201100278     Document Type: Article

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