K inetic study of oxygen adsorption over nanosized Au/γ-Al 2O 3 supported catalysts under selective CO oxidation conditions

Molecules

Volumn 17, Issue 5, 2012, Pages 4878-4895

  Gavril, Dimitrios ^a   Georgaka, Aglaia ^a,b   Karaiskakis, George ^a  

^a UNIVERSITY OF PATRAS   (Greece)

^b HELLENIC OPEN UNIVERSITY   (Greece)

Author keywords

Au Al 2O 3; Carbon monoxide; Catalysts; Inverse gas chromatography; Nanoparticles; Oxygen; PROX; Rate constants; Reversed flow inverse gas chromatography; SCO

Indexed keywords

ALUMINUM OXIDE; CARBON MONOXIDE; GOLD; HYDROGEN; NANOMATERIAL; OXYGEN;

ADSORPTION; ARTICLE; CATALYSIS; CHEMISTRY; GAS CHROMATOGRAPHY; KINETICS; OXIDATION REDUCTION REACTION; SURFACE PROPERTY; TEMPERATURE; THERMODYNAMICS;

ADSORPTION; ALUMINUM OXIDE; CARBON MONOXIDE; CATALYSIS; CHROMATOGRAPHY, GAS; GOLD; HYDROGEN; KINETICS; NANOSTRUCTURES; OXIDATION-REDUCTION; OXYGEN; SURFACE PROPERTIES; TEMPERATURE; THERMODYNAMICS;

EID: 84861485178     PISSN: None     EISSN: 14203049     Source Type: Journal    
DOI: 10.3390/molecules17054878     Document Type: Article

References (70)

1. Haruta, M. Preparation and environmental applications of supported gold catalysts. Now Future 1992, 7, 13-20.
2. Hutchings, G.J. Catalysis: A golden future. Gold Bull. 1996, 29, 123-130.
3. Haruta, M. Size and support dependency in the catalysis by gold. Catal. Today 1997, 36, 153-166.
4. Thompson, D.T. New advances in gold catalysis. Gold Bull. 1998, 31, 111-118; 1999, 32, 12-19.
5. Bond, G.C.; Thompson, D.T. Catalysis by gold. Cat. Rev. Sci. Eng. 1999, 41, 319-388.
6. Bond, G.C.; Thompson, D.T. Gold catalysed oxidation of carbon monoxide. Gold Bull. 2000, 33, 41-50.
7. Haruta, M.; Date, M. Advances in the catalysis of Au nanoparticles. Appl. Catal. A Gen. 2001, 222, 427-437.
8. Thompson, D.T. A golden future for catalysis. Chem. Br. 2001, 37, 43-44.
9. Haruta, M. Catalysis of gold nanoparticles deposited on metal oxides. Cattech 2002, 6, 102-115.
10. Hutchings, G.J. Gold catalysis in chemical processing. Catal. Today 2002, 72, 11-17.
11. Cortie, M.B.; van der Lingen, E. Catalytic gold nanoparticles. Mater. Forum 2002, 26, 1-14.
12. Haruta, M. When gold is not noble: Catalysis by nanoparticles. Chem. Record 2003, 3, 75-87.
13. Thompson, D.T. Perspective on industrial and scientific aspects of gold catalysis. Appl. Catal. A Gen. 2003, 243, 201-205.
14. Cameron, D.; Holliday, R.; Thompson, D. Gold's future role in fuel cell systems. J. Power Sources 2003, 118, 298-303.
15. Hashmi, A.S.K. Homogeneous catalysis by gold. Gold Bull. 2004, 37, 51-65.
16. Hutchings, G.J. Catalysts: Golden opportunities. Chem. Eng. 2004, 2004, 34-36.
17. Pattrick, G.; van der Lingen, E.; Corti, C.W.; Holliday, R.J.; Thompson, D.T. The potential for use of gold in automotive pollution control technologies: A short review. Topics Catal. 2004, 30-31, 273-279.
18. Thompson, D.T. Catalysis by gold/platinum group metals. Plat. Metals Rev. 2004, 48, 169-172.
19. Corti, C.W.; Holliday, R.J.; Thompson, D.T. Commercial aspects of gold catalysis. Appl. Catal. A Gen. 2005, 291, 253-261.
20. Hutchings, G.J. Catalysis by gold. Catal. Today 2005, 100, 55-61.
21. Hashmi, A.S.K. The catalysis gold rush: New claims. Angew Chem. Int. Ed. 2005, 44, 6990-6993.
22. Bond G.C.; Thompson, D.T. Status of catalysis by gold following an AURICAT workshop. Appl. Catal. A Gen. 2006, 302, 1-4.
23. Thompson, D.T. An overview of gold-catalysed oxidation processes. Topics Catal. 2006, 38, 231-240.
24. Carabineiro, S.A.C.; Thompson, D.T. Catalytic Applications for Gold Nanotechnology. In Nanocatalysis; Heiz, U., Landman, U., Eds.; Springer-Verlag: Berlin/Heidelberg, Germany, 2007; pp. 377-489.
25. Hashmi, A.S.K.; Hutchings, G.J. Gold catalysis. Angew Chem. Int. Ed. 2006, 45, 7896-7936.
26. Della Pina, C.; Falletta, E.; Rossi, M. Update on selective oxidation using gold. Chem. Soc. Rev. 2012, 41, 350-369.
27. Liu, Z.-P.; Hu, P.; Alavi, A. Catalytic role of gold in gold-based catalysts: A density functional theory study on the CO oxidation on gold. J. Am. Chem. Soc. 2002, 124, 14770-14779.
28. Hussain, A.; Gracia, J.; Niemantsverdriet, J.W.; Nieuwenhuys, B.E. The beneficial effect of hydrogen on CO oxidation over Au catalysts. A computationalstudy. Molecules 2011, 16, 9582-9599.
29. Kandoi, S.; Gokhale, A.A.; Grabow, L.C.; Dumesic, J.A.; Mavrikakis, M. Why Au and Cu are more selective than Pt for preferential oxidation of CO at low temperature. Catal. Lett. 2004, 93, 93-100.
30. Piccolo, L.; Daly, H.; Valcarcel, A.; Meunier, F.C. Promotional effect of H2 on CO oxidation over Au/TiO2 studied by operando infrared spectroscopy. Appl. Catal. B-Environ. 2009, 86, 190-195.
31. Chen M.S.; Goodman, D.W. The structure of catalytically active Au OnTitania. Science 2004, 306, 252-255.
32. Carretin, S.; Concepcion, P.; Corma, A.; Lopez-Nieto, J.M.; Puntes, V.F. Nanocrystalline CeO2 increases the activity of Au for CO oxidation by two orders of magnitude. Angew. Chem. Int. Ed. 2004, 43, 2538-2540.
33. Lopez, N.; Janssens, T.V.J.; Clausen, B.S.; Xu, Y.; Mavrikakis, M.; Bligaard, T.; Nørskov, J.K. On the origin of the catalytic activity of nanometer gold particles for low temperature CO oxidation. J. Catal. 2004, 223, 232-235.
34. Schumacher, B.; Denkwitz, Y.; Plzak, V.; Kinne, M.; Behm, R.J. Kinetics, mechanism and the influence of H2 on the CO oxidation reaction on a Au/TiO2 catalyst. J. Catal. 2004, 224, 449-462.
35. Rossignol, C.; Arrii, S.; Morfin, F.; Piccolo, L.; Caps, V.; Rousset, J.L. Selective oxidation of CO over model gold-based catalysts in the presence of H2. J. Catal. 2005, 230, 476-483.
36. Guzman, J.; Carrettin, S.; Corma, A. Spectroscopic evidence for the supply of reactive oxygen during CO oxidation catalyzed by gold supported on nanocrystalline CeO2. J. Am. Chem. Soc. 2005, 127, 3286-3287.
37. Remediakis, I.N.; Lopez, N.; Nørskov, J.K. CO oxidation on rutile-supported Au nanoparticles. Angew. Chem. Int. Ed. 2005, 44, 1824-1826.
38. Hernandez, N.C.; Sanz J.F.; Rodriguez, J.A. Unravelling the origin of the high-catalytic activity of supported Au: A density-functional theory-based interpretation. J. Am. Chem. Soc. 2006, 128, 15600-15601.
39. Weiher, N.; Beesley, A.M.; Tsapatsaris, N.; Delannoy, L.; Louis, C.; van Bokhoven, J.A.; Schroeder, S.L.M. Activation of oxygen by metallic gold in Au/TiO2 catalysts. J. Am. Chem. Soc. 2007, 129, 2240-2241.
40. Janssens, T.V.W.; Clausen, B.S.; Hvolbaek, B.; Falsig, H.; Christensen, C.H.; Bligaard, T.; Nørskov, J.K. Insights into the reactivity of supported Au nanoparticles: Combining theory and experiments. Top. Catal. 2007, 44, 15-26.
41. Fu, Q.; Kudriavtseva, S.; Saltsburg, H.; Flytzani-Stephanopoulos, M. Gold-ceria catalysts for low-temperature water-gas shift reaction. Chem. Eng. J. 2003, 93, 41-53.
42. Fu, Q.; Saltsburg, H.; Flytzani-Stephanopoulos, M. Active non-metallic Au and Pt species on ceria-based water-gas shift catalysts. Science 2003, 301, 935-938.
43. Gonzalez-Arellano, C.; Corma, A.; Iglesias, M.; Sanchez, F. Enantioselective hydrogenation of alkenes and imines by a gold catalyst. Chem. Commun. 2005, 27, 3451-3453.
44. Hashmi, A.S.K. Gold-catalyzed synthesis of N,O-heterocycles. Pure Appl. Chem. 2010, 82, 657-668.
45. Milone, C.; Tropeano, M.L.; Guline, G.; Neri, G.; Ingoglia, R.; Galvagno, S. Selective liquid phase hydrogenation of citral on Au/Fe2O3 catalysts. Chem. Commun. 2002, 868-869.
46. Tabakova, T.; Idakiev, V.; Tenchev, K.; Boccuzzi, F.; Manzoli, M.; Chiorino, A. Pure hydrogen production on a new gold-thoria catalyst for fuel cell applications. Appl. Catal. B 2006, 63, 94-103.
47. Bowker, M.; Millard, L.; Greaves, J.; James, D.; Soares, J. Photocatalysis by Au nanoparticles: Reforming of methanol. Gold Bull. 2004, 37, 170-173.
48. Grisel, R.J.H.; Nieuwenhuys, B.E. Selective oxidation of CO, over supported Au catalysts. J. Catal. 2001, 199, 48-59.
49. Molina, L.M.; Hammer, B. Active role of oxide support during CO oxidation at Au/MgO. Phys. Rev. Lett. 2003, 90, 206102-206105.
50. Mavrikakis, M.; Stoltze, P.; Norskov, J.K. Making gold less noble. Catal. Lett. 2000, 64, 101-106.
51. Oh, S.H.; Sinkevitch, S. Carbon monoxide removal from hydrogen-rich fuel cell feedstreams by selective catalytic oxidation. J. Catal. 1993, 142, 254-262.
52. Kahlich, M.J.; Gasteiger, H.A.; Behm, R.J. Kinetics of the selective CO oxidation in H2-Rich gas on Pt/Al2O3. J. Catal. 1997, 171, 93-105.
53. Grisel, R.J.H. Supported gold catalysts for environmental. Applications. PhD Thesis, Leiden University, Leiden, The Netherlands, 2002.
54. Georgaka, A.; Gavril, D.; Loukopoulos, V.; Karaiskakis, G.; Nieuwenhuys, B.E. H2 and CO2 coadsorption effects in CO adsorption over nanosized Au/?-Al2O3 catalysts. J. Chromatogr. A 2008, 1205, 128-136.
55. Gavril, D.; Georgaka, A.; Loukopoulos, V.; Karaiskakis, G.; Nieuwenhuys, B.E. On the mechanism of selective CO oxidation on nanosized Au/?-Al2O3 catalysts. Gold Bull. 2006, 39, 192-199.
56. Molina, L.M.; Hammer, B. Some recent theoretical advances in the understanding of the catalytic activity of Au. Appl. Catal. A Gen. 2005, 291, 21-31.
57. Karaiskakis, G.; Gavril, D. Determination of diffusion coefficients by gas chromatography. J. Chromatogr. A 2004, 1037, 147-189.
58. Rashid, K.A.; Gavril, D.; Karaiskakis, G. A new gas chromatographic methodology for the estimation of the composition of binary gas mixtures. J. Chrom. Sci. 2003, 41, 123-132.
59. Gavril, D.; Rashid, K.A.; Karaiskakis, G. Determination of collision cross sectional parameters from experimentally measured gas diffusion coefficients. Fluid Phase Equil. 2004, 218, 177-188.
60. Gavril, D.; Rashid, K.A.; Karaiskakis, G. Study of the mechanism of the interaction of vinylchloride with water by reversed-flow gas chromatography. J. Chromatogr. A 2001, 919, 349-356.
61. Rashid, K.A.; Gavril, D.; Katsanos, N.A.; Karaiskakis, G. Flux of gases across the air-water interface studied by reversed flow gas chromatography. J. Chromatogr. A 2001, 934, 31-49.
62. Gavril, D.; Rashid, K.?.; Karaiskakis, G. Study of the evaporation of pollutant liquids under the influence of surfactants by reversed-flow inverse gas chromatography. AIChE J. 2006, 52, 2381-2390.
63. Gavril, D.; Gabriel, A. Investigation of the determination of diffusion coefficients of gases into liquids from reversed-flow gas chromatography. Instrum. Sci. Technol. 2006, 34, 435-454.
64. Gavril, D.; Loukopoulos, V.; Karaiskakis, G. Study of CO dissociative adsorption over Pt and Rh catalysts by inverse gas chromatography. Chromatographia 2004, 59, 721-729.
65. Gavril, D.; Loukopoulos, V.; Georgaka, A.; Gabriel, A.; Karaiskakis, G. Inverse gas chromatographic investigation of the effect of hydrogen in carbon monoxide adsorption over silica supported Rh and Pt-Rh alloy catalysts, under hydrogen-rich conditions. J. Chromatogr. A 2005, 1087, 158-168.
66. Gavril, D. Reversed flow gas chromatography: A tool for instantaneous monitoring of the concentrations of reactants and products in heterogeneous catalytic processes. J. Liq. Chrom. Rel. Technol. 2002, 25, 2079-2099.
67. Gavril, D.; Koliadima, A.; Karaiskakis, G. Adsorption studies of gases on Pt-Rh bimetallic catalysts by reversed-flow gas chromatography. Langmuir 1999, 15, 3798-3806.
68. Gavril, D. An inverse gas chromatographic tool for the measurement of local isotherms on heterogeneous surfaces. Instrum. Sci. Technol. 2002, 30, 409-425.
69. Loukopoulos, V.; Gavril, D.; Karaiskakis, G. An inverse gas chromatographic instrumentation for the study of carbon monoxide's adsorption on Rh/SiO2, under hydrogen-rich conditions. Instrum. Sci. Technol. 2003, 31, 165-181.
70. Gavril, D.; Neuwenhuys, B.E. Investigation of the surface heterogeneity of solids from reversed-flow inverse gas chromatography. J. Chromatogr. A 2004, 1045, 161-172.