Utilizing the inherent electrolysis in a chip-based nanoelectrospray emitter system to facilitate selective ionization and mass spectrometric analysis of metallo alkylporphyrins

Analytical and Bioanalytical Chemistry

Volumn 403, Issue 2, 2012, Pages 335-343

  Van Berkel, Gary J ^a   Kertesz, Vilmos ^a,b  

^a OAK RIDGE NATIONAL LABORATORY   (United States)

^b SZÉCHENYI ISTVÁN UNIVERSITY   (Hungary)

Author keywords

Electrochemistry; Electrospray; Gilsonite; Oxidation; Porphyrins

Indexed keywords

ALKYL CHAIN LENGTHS; ANALYTES; ELECTROCHEMICAL REACTIONS; ELECTROSPRAYS; GILSONITE; IONIC FORMS; IONIC SPECIES; MASS SPECTRA; MASS SPECTROMETRIC ANALYSIS; MASS SPECTROMETRIC DETECTION; MODEL COMPOUND; MOLECULAR RADICAL CATIONS; NANO-ELECTROSPRAY EMITTER; NANOELECTROSPRAY IONIZATION; NATURALLY OCCURRING; NEUTRAL LOSS; PORPHYRIN MACROCYCLE; POTENTIAL LIMITS; PRODUCT ION SPECTRA; PROTONATED MOLECULES; REDOX POTENTIALS; SELECTIVE IONIZATION; STRUCTURE ELUCIDATION; SURFACE COATINGS; VANADYL;

COBALT; COBALT COMPOUNDS; ELECTROCHEMISTRY; ELECTROLYSIS; HYDROCARBONS; IONIZATION; IONS; MASS SPECTROMETERS; MASS SPECTROMETRY; NICKEL COMPOUNDS; OXIDATION; PORPHYRINS; REDOX REACTIONS; VANADIUM COMPOUNDS;

PIPE;

METAL; PORPHYRIN;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROLYSIS; ELECTROSPRAY MASS SPECTROMETRY; INSTRUMENTATION; METHODOLOGY;

ELECTROLYSIS; METALS; MOLECULAR STRUCTURE; PORPHYRINS; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION;

EID: 84861233243     PISSN: 16182642     EISSN: 16182650     Source Type: Journal    
DOI: 10.1007/s00216-011-5676-x     Document Type: Article

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