Manganese and ceria sorbents for high temperature sulfur removal from biomass-derived syngas - The impact of steam on capacity and sorption mode

Fuel

Volumn 97, Issue , 2012, Pages 612-620

  Cheah, Singfoong ^a   Parent, Yves O ^b   Jablonski, Whitney S ^a   Vinzant, Todd ^a   Olstad, Jessica L ^a  

^a NATIONAL RENEWABLE ENERGY LABORATORY   (United States)

^b Chemical Engineering Consulting Services LLC   (United States)

Author keywords

Biofuel; Ceria; Desulfurization; Hot gas clean up; Sulfur sorbent

Indexed keywords

DRY CONDITION; ELECTRICITY GENERATION; GASIFICATION PRODUCTS; HIGH TEMPERATURE; HOT GAS; SOLID STATE TRANSFORMATIONS; SPACE VELOCITIES; SPECTROSCOPIC CHARACTERIZATION; SURFACE CHEMISORPTION; SYN-GAS; SYNGAS COMPOSITION; TURBINE OPERATION;

BIOFUELS; CERIUM COMPOUNDS; CHEMISORPTION; COAL GASIFICATION; ELECTRIC GENERATORS; HYDROGEN SULFIDE; MANGANESE; SORBENTS; STEAM; SULFUR; SYNTHESIS GAS;

DESULFURIZATION;

EID: 84861197459     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2012.03.007     Document Type: Article

References (62)

1. G.W. Huber, S. Iborra, and A. Corma Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering Chem Rev 106 9 2006 4044 4098
2. 2S from hot fuel gas streams by rare earth oxides Science 312 5779 2006 1508 1510
3. S. Cheah, S. Czernik, R.M. Baldwin, K. Magrini-Bair, and J.E. Hensley Catalysts and sorbents for thermochemical conversion of biomass to renewable biofuels - Material development needs G. Wicks, J. Simon, R. Zidan, E. Lara-Curzio, T. Adams, J. Zayas, A. Karkamkar, R. Sindelar, B. Garcia-Diaz, Materials challenges in alternative and renewable energy: ceramic transactions, cocoa beach 2011 Wiley and The American Ceramic Society FL 349 362
4. R. Farrauto, S. Hwang, L. Shore, W. Ruettinger, J. Lampert, and T. Giroux New material needs for hydrocarbon fuel processing: generating hydrogen for the PEM fuel cell Ann Rev Mater Res 33 2003 1 27
5. D.L. Carpenter, R.L. Bain, R.E. Davis, A. Dutta, C.J. Feik, and K.R. Gaston Pilot-Scale gasification of corn stover, switchgrass, wheat Straw, and wood: 1. Parametric study and comparison with literature Ind Eng Chem Res 49 4 2010 1859 1871
6. S. Cheah, D.L. Carpenter, and K.A. Magrini-Bair Review of mid- to high-temperature sulfur sorbents for desulfurization of biomass- and coal-derived syngas Energy Fuels 23 11 2009 5291 5307
7. F.N. Cayan, M.J. Zhi, S.R. Pakalapati, I. Celik, N.Q. Wu, and R. Gemmen Effects of coal syngas impurities on anodes of solid oxide fuel cells J Power Sources 185 2 2008 595 602
8. EG&G Technical Services I. Fuel Cell Handbook, Morgantown, WV:National Energy Technology Laboratory; 2004.
9. R.P. Gupta, and W.S. O'Brien Desulfurization of hot syngas containing hydrogen chloride vapors using zinc titanate sorbents Ind Eng Chem Res 39 3 2000 610 619
10. O. Borg, N. Hammer, B.C. Enger, R. Myrstad, O.A. Lindvåg, and S. Eri Effect of biomass-derived synthesis gas impurity elements on cobalt Fischer-Tropsch catalyst performance including in situ sulphur and nitrogen addition J Catal 279 1 2011 163 173
11. 2S removal from steam-containing gas mixtures with ZnO for fuel cell application. 1. ZnO particles and extrudates Energy Fuels 18 2004 576 583
12. Huber GW. Breaking the chemical and engineering barriers to lignocellulosic biofuels: next generation hydrocarbon biorefineries. Amherst and Washington DC:University of Massachusetts and National Science Foundation, Chemical, Bioengineering, Environmental, and Transport Systems Division; 2008. p. 180.
13. S.K. Gangwal, S.M. Harkins, M.C. Woods, S.C. Jain, and S.J. Bossart Bench-scale testing of high-temperature desulfurization sorbents Environ Progr 8 4 1989 265 269
14. 2S removal from fuel gases by regenerable zinc oxide-titanium dioxide sorbents Ind Eng Chem Res 28 1989 535 541
15. S. Lew, A.F. Sarofim, and M. Flytzani-Stephanopoulos Sulfidation of zinc titanate and zinc-oxide solids Ind Eng Chem Res 31 8 1992 1890 1899
16. 2 and CO Appl Surf Sci 45 2 1990 131 139
17. 2S removal from coal gas at elevated temperature and pressure in fluidized bed with zinc titanate sorbents. 1. Cyclic tests Energy Fuels 9 3 1995 429 434
18. 2S removal from coal gas at elevated temperature and pressure in fluidized bed with zinc titanate sorbents. 2. Sorbent durability Energy Fuels 9 5 1995 782 787
19. J.H. Swisher, J. Yang, and R.P. Gupta Attrition-resistant zinc titanate sorbent for sulfur Ind Eng Chem Res 34 12 1995 4463 4471
20. 2S Ind Eng Chem Res 34 4 1995 1102 1106
21. 2 addition Ind Eng Chem Res 38 3 1999 958 963
22. 2O in oxidative regeneration of ZnS formed from high-temperature desulfurization ZnO sorbent Ind Eng Chem Res 39 10 2000 3844 3848
23. 2S sorption by calcined limestone Ind Eng Chem Res 34 7 1995 2334 2342
24. 2S sorption by uncalcined limestone Ind Eng Chem Res 34 7 1995 2324 2333
25. T.T. Akiti, K.P. Constant, L.K. Doraiswamy, and T.D. Wheelock A regenerable calcium-based core-in-shell sorbent for desulfurizing hot coal gas Ind Eng Chem Res 41 3 2002 587 597
26. C.A.P. Zevenhoven, K.P. Yrjas, and M.M. Hupa Product layer development during sulfation and sulfidation of uncalcined limestone particles at elevated pressures Ind Eng Chem Res 37 7 1998 2639 2646
27. R. Ben-Slimane, and M.T. Hepworth Desulfurization of hot coal-derived fuel gases with manganese-based regenerable sorbents. 1. Loading (sulfidation) tests Energy Fuels 8 1994 1175 1183
28. R. Ben-Slimane, and M.T. Hepworth Desulfurization of hot coal-derived fuel gases with manganese-based regenerable sorbents. 2. Regeneration and multicycle tests Energy Fuels 8 1994 1184 1191
29. R. Ben-Slimane, and M.T. Hepworth Desulfurization of hot coal-derived fuel gases with manganese-based regenerable sorbents. 3. Fixed-bed testing Energy Fuels 9 2 1995 372 378
30. M. Danielewski The kinetics and mechanism of manganese sulfidation Oxid Metals 25 1-2 1986 51 82
31. 3 used for high-temperature desulfurization of fuel gases Fuel 75 3 1996 373 378
32. Z.J. Li, and M. Flytzani-Stephanopoulos Cu-Cr-O and Cu-Ce-O regenerable oxide sorbents for hot gas desulfurization Ind Eng Chem Res 36 1 1997 187 196
33. Kay DAR, Wilson WG. Methods of desulphurizing iron and steel and gases, such as stack gases and the like. 1978; USPTO, 4084,960.
34. D.A.R. Kay, and W.G. Wilson The use of cerium oxides in gaseous desulfurization J Metals 40 11 1988 57
35. x) removal J Alloys Compd 193 1-2 1993 11 16
36. Y. Zeng, S. Zhang, F.R. Groves, and D.P. Harrison High temperature gas desulfurization with elemental sulfur production Chem Eng Sci 54 15-16 1999 3007 3017
37. Y. Zeng, S. Kaytakoglu, and D.P. Harrison Reduced cerium oxide as an efficient and durable high temperature desulfurization sorbent Chem Eng Sci 55 21 2000 4893 4900
38. M. Kobayashi, and M. Flytzani-Stephanopoulos Reduction and sulfidation kinetics of cerium oxide and Cu-modified cerium oxide Ind Eng Chem Res 41 13 2002 3115 3123
39. Z. Wang, and M. Flytzani-Stephanopoulos Cerium oxide-based sorbents for regenerative hot reformate gas desulfurization Energy Fuels 19 5 2005 2089 2097
40. C. Higman, and M. van der Burgt Gasification 2nd ed. 2008 Gulf Professional Publishing, an imprint of Elsevier Burlington, MA
41. W. Torres, S.S. Pansare, and J.G. Goodwin Jr. Hot gas removal of tars, ammonia, and hydrogen sulfide from biomass gasification gas Catal Rev - Sci Eng 49 2007 407 456
42. H. He, R.J. Gorte, and J.M. Vohs Highly sulfur tolerant Cu-ceria anodes for SOFCs Electrochem Solid-State Lett 8 6 2005 A279 A280
43. 2 J Catal 240 1 2006 1 7
44. 3 acceptors Ind Eng Chem Res 32 1 1993 139 149
45. S. Cheah, J.L. Olstad, W.S. Jablonski, and K.A. Magrini-Bair Regenerable manganese-based sorbent for cleanup of simulated biomass-derived syngas Energy Fuels 25 1 2011 379 387
46. W.J.W. Bakker, F. Kapteijn, and J.A. Moulijn A high capacity manganese-based sorbent for regenerative high temperature desulfurization with direct sulfur production. Conceptual process application to coal gas cleaning Chem Eng J 96 1-3 2003 223 235
47. Parent YO, Magrini K, Landin SM, Ritland MA. Attrition Resistant Fluidizable Reforming Catalyst. 2011; USPTO, US 7915,196 B2.
48. M. Zinkevich, D. Djurovic, and F. Aldinger Thermodynamic modeling of the cerium-oxygen system Solid State Ion 177 2006 989 1001
49. D.R. Mullins, and T.S. McDonald Adsorption and reaction of hydrogen sulfide on thin-film cerium oxide Surf Sci 601 21 2007 4931 4938
50. McBride BJ, Gordon S, Reno MA. Thermodynamic data for fifty reference elements, John H. Glenn Research Center at Lewis Field, Cleveland, USA:National Aeronautics and Space Administration; 1993.
51. I. Barin Thermochemical data of pure substances 1993 VCH Verlags Gesellschaft Weinheim
52. I. Barin, and G. Platzki Thermochemical data of pure substances 3rd ed. 1995 VCH Verlags Gesellschaft Weinheim and New York
53. G. Belov, V. Iorish, and V. Yungman IVTANTHERMO database on thermodynamic properties and related software Calphad 23 2 1999 173 180
54. I. Barin, O. Knacke, and O. Kubaschewski Thermodynamic properties of inorganic substances 1973 Springer-Verlag Berlin and New York
55. O. Knacke, O. Kubaschewski, and K. Hesselman Thermochemical properties of inorganic substances 2nd ed. 1991 Springer-Verlag Berlin
56. Lidin RA, Andreyeva LL, Molochko VA. Constants of Inorganic Substances: A Handbook Rev Sub ed.:Begell House 1995.
57. S.G.T. Europe Landolt-börnstein thermodynamic properties of inorganic materials 1999 Springer-Verlag Berlin-Heidelberg
58. I. Barin Thermochemical data of pure substances 1989 VCH Verlags Gesellschaft Weinheim
59. Fabricius G, Sundholm G, Liukkonen S. Fysikaalisen kemian taulukoita: Otatieto; 1994.
60. Malcolm C. NIST-JANAF Thermochemical Tables, 4th ed.:Washington, D.C.: American Chemical Society; Woodbury, N.Y.: American Institute of Physics for the National Institute of Standards and Technology; 1998.
61. Malcolm C. NIST-JANAF Thermochemical Tables, 3rd ed.:Springer-Verlag; 1985.
62. Dutta A, Cheah S, Bain R, Feik C, Magrini-Bair K, Phillips S. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification. Ind Eng Chem Res, submitted for publication.