A new approach to the side chain formation of 24-alkyl-22-hydroxy steroids: Application to the preparation of early brassinolide biosynthetic precursors

Steroids

Volumn 77, Issue 7, 2012, Pages 780-790

  Hurski, Alaksiej L ^a   Zhabinskii, Vladimir N ^a   Khripach, Vladimir A ^a  

^a INSTITUTE OF BIOORGANIC CHEMISTRY   (Belarus)

Author keywords

(22S) 22 Hydroxycampesterol; 6 Deoxocathasterone; Brassinosteroids; Cathasterone; Deuterium labeling

Indexed keywords

22 ACETOXY 24 METHYL 3ALPHA,5 CYCLO 5 ALPHA CHOLESTAN 6 ONE; 22 ACETOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 6 ONE; 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 6 ON 22 OL; 24 METHYL 5ALPHA CHOLESTAN 22 OL; 24 METHYL 5ALPHA CHOLESTAN 6 ONE 3BETA,22 DIOL; 24 METHYLCHOLEST 5 EN 22 OL; 26 METHANESULFONYLOXY 22,23 EPOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 6 ONE; 3BETA,22 DIACETOXY 24 METHYL 5ALPHA CHOLESTAN 6 ONE; 6 (1,3 DIOXOLAN 2 YL) 22 HYDROXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTANO 26,23 LACTONE; 6 (1,3 DIOXOLAN 2 YL) 22 METHOXYMETHYL 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 23,26 DIOL; 6 (1,3 DIOXOLAN 2 YL) 22 METHOXYMETHYL 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTANO 26,23 LACTONE; 6 (1,3 DIOXOLAN 2 YL) 23,26 THIO 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 22 OL; 6 (1,3 DIOXOLAN 2 YL) 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLEST 22 EN 26 OIC ACID ETHYL ESTERS; 6 (1,3 DIOXOLAN 2 YL) 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 22 OL; 6 (1,3 DIOXOLAN 2 YL) 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 22 ONE; 6 (1,3 DIOXOLAN 2 YL) 26 METHANESULFONYLOXY 22 METHOXYMETHYL 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 23 OL; 6 (1,3 DIOXOLAN 2 YL) 26 METHANESULFONYLOXY 22,23 EPOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTANE; 6 (1,3 DIOXOLAN 2 YL) 26 METHANESULFONYLOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLEST 22 ENE; 6 (1,3 DIOXOLAN 2 YL) 3ALPHA,5 CYCLO 20 FORMYL 5ALPHA PREGNANE; 6 (1,3 DIOXOLAN 2 YL) 3ALPHA,5 CYCLO 26,27 BISNOR 5ALPHA CHOLEST 23 EN 22 OL; 6 (1,3 DIOXOLAN 2 YL) 3ALPHA,5 CYCLO 26,27 BISNOR 5ALPHA CHOLEST 23 YN 22 OL; 6BETA METHOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 22 OL; 6BETA METHOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTAN 22 ONE; 6BETA METHOXY 26 METHANESULFONYLOXY 22,23 EPOXY 24 METHYL 3ALPHA,5 CYCLO 5ALPHA CHOLESTANE; BRASSINOLIDE; HYDROXY 24R METHYL STEROID; STEROID; UNCLASSIFIED DRUG;

ARTICLE; CLAISEN REARRANGEMENT; DESULFURIZATION; DRUG STRUCTURE; DRUG SYNTHESIS; EPOXIDATION; STEREOCHEMISTRY;

BRASSINOSTEROIDS; EPOXY COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; MASS SPECTROMETRY; STEROIDS; STEROIDS, HETEROCYCLIC;

EID: 84861182700     PISSN: 0039128X     EISSN: 18785867     Source Type: Journal    
DOI: 10.1016/j.steroids.2012.03.010     Document Type: Article

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