Synthesis of [26-2H3]brassinosteroids

Steroids

Volumn 67, Issue 7, 2002, Pages 587-595

  Khripach, Vladimir A ^a   Zhabinskii, Vladimir N ^a   Konstantinova, Olga V ^a   Antonchick, Andrey P ^a   Schneider, Bernd ^b  

^a INSTITUTE OF BIOORGANIC CHEMISTRY   (Belarus)

^b MAX PLANCK INSTITUTE FOR CHEMICAL ECOLOGY   (Germany)

Author keywords

Brassinolide; Brassinosteroids; Claisen rearrangement; Labeled compounds; Plant growth hormone

Indexed keywords

ALKENE; BRASSINOSTEROID; DEUTERIUM; PHYTOHORMONE; BRASSINOLIDE; CHOLESTANOL; HETEROCYCLIC STEROID;

ARTICLE; HYDROXYLATION; STEROIDOGENESIS; CHEMICAL STRUCTURE; SYNTHESIS;

CHOLESTANOLS; HYDROXYLATION; MOLECULAR STRUCTURE; PLANT GROWTH REGULATORS; STEROIDS, HETEROCYCLIC;

EID: 0036011268     PISSN: 0039128X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-128X(02)00004-1     Document Type: Article

References (25)

1. Studies on biosynthesis of brassinosteroids
2. The structure, biosynthesis and function of brassinosteroids
3. An alternative brassinolide biosynthetic pathway via late C-6 oxidation
4. Brassinosteroids in Arabidopsis thaliana
5. Biochemical analysis of natural brassinosteroids
6. Conversion of 24-methylcholesterol to 6-oxo-24-methylcholestanol, a putative intermediate of the biosynthesis of brassinosteroids, in cultured cells of Catharanthus roseus
7. Identification of a new brassinosteroid, cathasterone, in cultured cells of Catharanthus roseus as a biosynthetic precursor to teasterone
8. A general approach to synthesis of labelled brassinosteroids: Preparation of [25,26,27-H-2(7)]brassinolide with 60% isotopic purity from the parent brassinolide
9. Synthesis of deuterio-labelled 24-methylenecholesterol and related steroids
10. Biosynthesis of brassinolide from teasterone via typhasterol and castasterone in cultured cells of Catharanthus roseus
11. 6]teasterone
12. 6]castasterone
13. 6]teasterone
14. 24-Epibrassinolide uptake in growing maize root segments evaluated by multiple-selected ion monitoring
15. Synthesis of tritium labelled 24-epibrassinolide
16. Labelling of biogenetic brassinosteroid precursors
17. 3]-epicastasterone
18. 25-crinosterol side chain construction
19. Syntheses and crystal structures of the cinchona alkaloid derivatives used as ligands in the osmium-catalyzed asymmetric dihydroxylation of olefins
20. 5,7-unsaturated brassinosteroid analogs
21. Facile syntheses of brassinosteroids: Brassinolide, castasterone, teasterone and typhasterol
22. Secasterone, the first naturally occurring 2,3-epoxybrassinosteroid from Secale cereale
23. Synthesis of 3,24-diepicastasterone: A natural brassinosteroid with 2,3-trans-diol function