Enhanced selectivity for the hydrolysis of block copoly(2-oxazoline)s in ethanol-water resulting in linear poly(ethylene imine) copolymers

Macromolecular Rapid Communications

Volumn 33, Issue 9, 2012, Pages 827-832

  Van Kuringen, Huub P C ^a   De La Rosa, Victor R ^b   Fijten, Martin W M ^a   Heuts, Johan P A ^a   Hoogenboom, Richard ^b  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b GHENT UNIVERSITY   (Belgium)

Author keywords

biological applications of polymers; block copolymers; controlled hydrolysis; linear poly(ethylenimine)s; poly(2 oxazoline)s

Indexed keywords

2-METHYL-2-OXAZOLINE; 2-OXAZOLINE; BINARY SOLVENT MIXTURES; BIOLOGICAL APPLICATIONS OF POLYMER; BIOMEDICAL APPLICATIONS; CONTROLLED HYDROLYSIS; ETHANOL-WATER; GENE DELIVERY; HYDROLYSIS KINETICS; POLY(2-ETHYL-2-OXAZOLINE); POLY(2-OXAZOLINE)S; POLYETHYLENE IMINES; POLYETHYLENIMINES; SOLVENT MIXTURES; SWITCHABLE; TUNABLE PROPERTIES;

BIOSENSORS; BLOCK COPOLYMERS; ETHANOL; GENE TRANSFER; HYDROLYSIS; MEDICAL APPLICATIONS; MIXTURES; NITROGEN COMPOUNDS; POLYMERS; SOLVENTS;

ORGANIC SOLVENTS;

ALCOHOL; IMINE; OXAZOLE DERIVATIVE; POLY(2 ETHYL 2 OXAZOLINE); POLY(2 METHYL 2 OXAZOLINE); POLY(2-ETHYL-2-OXAZOLINE); POLY(2-METHYL-2-OXAZOLINE); POLY(ETHYLENE IMINE); POLYAMINE; POLYETHYLENE DERIVATIVE; POLYMER; SOLVENT; WATER;

ARTICLE; CHEMISTRY; HYDROLYSIS; KINETICS; SYNTHESIS;

ETHANOL; HYDROLYSIS; IMINES; KINETICS; OXAZOLES; POLYAMINES; POLYETHYLENES; POLYMERS; SOLVENTS; WATER;

EID: 84860827491     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.201200046     Document Type: Article

References (33)

1. R. Hoogenboom, Angew. Chem. Int. Ed. 2009, 48, 7978.
2. K. Aoi, M. Okada, Prog. Polym. Sci. 1996, 21, 151.
3. A. Makino, S. Kobayashi, J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 1251.
4. H. Schlaad, C. Diehl, A. Gress, M. Meyer, A. L. Demirel, Y. Nur, A. Bertin, Macrom. Rapid Commun. 2010, 31, 511.
5. M. M. Bloksma, R. M. Paulus, H. P. C. van Kuringen, F. van der Woerdt, H. M. L. Lambermont-Thijs, U. S. Schubert, R. Hoogenboom, Macrom. Rapid Commun. 2011, 33, 92.
6. D. A. Tomalia, D. P. Sheetz, J. Polym. Sci., Part A: Polym. Chem. 1966, 4, 2253.
7. T. Saegusa, H. Ikeda, H. Fujii, Macromolecules 1972, 5, 108.
8. M. Neu, D. Fischer, T. Kissel, J. Gene Med. 2005, 7, 992.
9. A. K. Larsen, D. Malinska, I. Koszela-Piotrowska, L. Parhamifar, A. C. Hunter, S. M. Moghimi, Mitochondrion 2012, 12, 162.
10. A. Beyerle, A. Braun, O. Merkel, F. Koch, T. Kissel, T. Stoeger, J. Controlled Release 2011, 151, 51.
11. J. H. Jeong, S. H. Song, D. W. Lim, H. Lee, T. G. Park, J. Controlled Release 2001, 73, 391.
12. M. Günther, J. Lipka, A. Malek, D. Gutsch, W. Kreyling, A. Aigner, Eur. J. Pharm. Biopharm. 2011, 7, 438.
13. O. Boussif, F. Lezoualc'h, M. A. Zanta, M. D. Mergny, D. Scherman, B. Demeneix, J. Behr, Proc. Natl. Acad. Sci. USA 1995, 92, 7297.
14. B. Brissault, A. Kichler, C. Guis, C. Leborgne, O. Danos, H. Cheradame, Bioconjugate Chem. 2003, 14, 581.
15. J. Dai, S. Zou, Y. Pei, D. Cheng, H. Ai, X. Shuai, Biomaterials 2011, 32, 1694.
16. Y. Shukla, P. Kumar, K. C. Gupta, Nanomed. NBM 2012, 8, 167.
17. Y. Ping, C. Liu, Z. Zhang, K. L. Liu, J. Chen, J. Li, Biomaterials 2011, 32, 8328.
18. J. Dai, S. Zou, Y. Pei, D. Cheng, H. Ai, X. Shuai, Biomaterials 2011, 32, 1694.
19. H. M. L. Lambermont-Thijs, J. P. A. Heuts, S. Hoeppener, R. Hoogenboom, U. S. Schubert, Polym. Chem. 2011, 2, 313.
20. M. H. Litt, C. S. Lin, J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 779.
21. R. H. Jin, ChemPhysChem. 2003, 4, 1118.
22. R. J. Speedy, J. A. Ballance, B. D. Cornish, J. Phys. Chem. 1983, 87, 325.
23. S. Dixit, J. Crain, W. C. K. Poon, J. L. Finney, A. K. Soper, Nature 2002, 416, 829.
24. W. S. Price, H. Ide, Y. Arata, J. Phys. Chem. A 2003, 107, 4784.
25. K. Nam, T. Kimura, A. Kishida, Macromol. Biosci. 2008, 8, 32.
26. M. Balakrishnan, G. Venkoba Rao, N. Venkatasubramanian, Int. J. Chem. Kinet. 1974, 103.
27. A. M. Ismail, Int. J. Chem. Kinet. 2012, 44, 125.
28. T. W. Bentley, I. S. Koo, H. Choi, G. Llewellyn, J. Phys. Org. Chem. 2008, 21, 251.
29. B. Åkundrić, J. Penavin, Z. Phys. Chem. 1984, 141, 29.
30. H. M. L. Lambermont-Thijs, H. P. C. van Kuringen, J. P. W. van der Put, U. S. Schubert, R. Hoogenboom, Polymers 2010, 2, 188.
31. R. Hoogenboom, H. M. L. Lambermont-Thijs, D. Wouters, S. Hoeppener, U. S. Schubert, Soft Matter 2008, 4, 103.
32. H. M. L. Lambermont-Thijs, F. S. Woerdt, A. Baumgaertel, L. Bonami, F. E. Du Prez, U. S. Schubert, R. Hoogenboom, Macromolecules 2010, 43, 927.
33. K. Hori, Y. Ikenaga, K. Arata, T. Takahashi, K. Kasai, Y. Noguchi, M. Sumimoto, H. Yamamoto, Tetrahedron 2007, 63, 1264.