Gold(I)-catalyzed synthesis of 1,5-benzodiazepines directly from o-phenylenediamines and alkynes

Journal of Organic Chemistry

Volumn 77, Issue 9, 2012, Pages 4484-4490

  Qian, Jianqiang ^a   Liu, Yunkui ^a,b   Cui, Jianhai ^a   Xu, Zhenyuan ^a  

^a ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

^b WENZHOU UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYZED SYNTHESIS; O-PHENYLENEDIAMINES;

ACETYLENE; GOLD COMPOUNDS;

CATALYSIS;

1,2 PHENYLENEDIAMINE; 2 METHYL 2,4 BIS(2 CHLOROPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(3 CHLOROPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 BROMOPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 CHLOROPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 ETHOXYPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 ETHYLPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 FLUOROPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 FLUOROPHENYL) 2,3 DIHYDRO 7,8 DICHLORO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(4 METHOXYPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 BIS(THIOPHEN 2 YL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 DIBUTYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 DICYCLOPROPYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 DIHEXYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 DIPHENYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 DIPHENYL 2,3 DIHYDRO 7,8 DICHLORO 1H 1,5 BENZODIAZEPINE; 2 METHYL 2,4 DITOLUYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2,4 DICYCLOPROPYL 2,7,8 TRIMETHYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2,7 DIMETHYL 2,4 DIPHENYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2,7,8 TRIMETHYL 2,4 BIS(4 CHLOROPHENYL) 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2,7,8 TRIMETHYL 2,4 DIPHENYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2,7,8 TRIMETHYL 2,4 DITOLUYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; 2,8 DIMETHYL 2,4 DIPHENYL 2,3 DIHYDRO 1H 1,5 BENZODIAZEPINE; ANTICONVULSIVE AGENT; ANTIINFLAMMATORY AGENT; ANXIOLYTIC AGENT; BENZODIAZEPINE DERIVATIVE; GOLD; HYPNOTIC SEDATIVE AGENT; UNCLASSIFIED DRUG; UNINDEXED DRUG;

ARTICLE; CATALYSIS; SYNTHESIS;

ALKYNES; BENZODIAZEPINES; CATALYSIS; GOLD; MOLECULAR STRUCTURE; PHENYLENEDIAMINES;

EID: 84860630954     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo300543n     Document Type: Article

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