The heterogenization of l-phenylalanine-Ru(III) complex and its application as catalyst in esterification of ethyl alcohol with acetic acid

Chemical Engineering Research and Design

Volumn 90, Issue 5, 2012, Pages 633-642

  Adam, Farook ^a   Hello, Kasim Mohammed ^b   Chai, Suk Jin ^a  

^a SCHOOL OF PHYSICS   (Malaysia)

^b AL MUTHANNA UNIVERSITY   (Iraq)

Author keywords

Esterification; L Phenylalanine; Ruthenium(III) complex; Sol gel technique; Surface modification

Indexed keywords

CARBON ATOMS; CATALYTIC PERFORMANCE; ETHYL ACETATES; HETEROGENIZATION; L-PHENYLALANINE; MAS NMR; PROPYL GROUPS; SILICON CENTERS; SOL-GEL TECHNIQUE;

ACETIC ACID; AMINO ACIDS; CATALYSTS; ESTERS; ETHANOL; RUTHENIUM COMPOUNDS; SILICA; SOL-GELS; SURFACE TREATMENT;

ESTERIFICATION;

EID: 84860483869     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2011.09.009     Document Type: Article

References (28)

1. Adam F., Chua J.H. The adsorption of palmytic acid on rice husk ash chemically modified with Al(III) ion using the sol-gel technique. J. Colloid Interface Sci. 2004, 280(1):55.
2. Adam F., Hello K.M., Ben Aisha M.R. The synthesis of heterogeneous 7-amino-1-naphthalene sulfonic acid immobilized silica nano particles and its catalytic activity. J. Taiwan Inst. Chem. Eng. 2011, 10.1016/j.jtice.2011.02.002.
3. Adam F., Hello K.M., Osman H. Esterification via saccharine mediated silica sold catalyst. Appl. Catal. A 2009, 365(2):165.
4. Adam F., Hello K.M., Osman H. The heterogenation of melamine and it's catalytic activity. Appl. Catal. A 2010, 382(1):115.
5. Adam F., Osman H., Hello K.M. The immobilization of 3-(chloropropyl) triethoxysiline onto silica by a simple one-pot synthesis. J. Colloid Interface Sci. 2009, 331:143.
6. Ahmed A.E., Adam F. Indium incorporated silica from rice husk and it's catalytic activity. Micropor. Mesopor. Mater. 2007, 103(1-3):284.
7. Breivogel A., Hempel K., Heinze K. Dinuclear bis(terpyridine)ruthenium (II) complexes by amide coupling of ruthenium amino acids: synthesis and properties. Inorg. Chim. Acta 2011, 374(12):152.
8. Chatterjee D., Mitra A., Shepherd R.E. Oxo-transfer catalysis from t-BuOOH with C-H bond insertion using tridentate Schiff-base-chelate complexes of ruthenium(III). Inorg. Chim. Acta 2004, 357(4):980.
9. 31P NMR spectroscopy. Tetrahedron: Asymmetry 2000, 11(14):2907.
10. 2 in alkaline medium for selective oxidation of alcohol. Micropor. Mesopor. Mater. 2007, 101(1-2):256.
11. Guijarro D., Pablo Ó., Yus M. Achiral b-amino alcohols as efficient ligands for the ruthenium-catalysed asymmetric transfer hydrogenation of sulfinylimines. Tetrahedron Lett. 2011, 52(2011):789.
12. Hockless D.C.R., Mayadunne R.C., Wild S.B. Convenient resolution of (±)-piperidine-2-carboxylic acid ((±)-pipecolic acid) by separation of palladium(II) diastereomers containing orthometallated (S)-(-)-1-[1-(dimethylamino)ethyl]naphthalene. Tetrahedron: Asymmetry 1995, 6(12):3031.
13. Jayakumar M., Venkatesan K.A., Srinivasan T.G., Vasudeva Rao P.R. Electrochemical behavior of ruthenium (III), rhodium (III) and palladium (II) in 1-butyl-3-methylimidazolium chloride ionic liquid. Electrochim. Acta 2009, 54(26):6747.
14. 3 complexes. J. Organomet. Chem. 2000, 593-594:299.
15. 2-hydrogenation and transfer hydrogenation of imines. Bull. Chem. Soc. Jpn. 2008, 81(9):1053.
16. 2NH)], M=Pd, Pt. Inorg. Chim. Acta 2002, 334(6):365.
17. Kovalchuk T.V., Kochkin Ju.N., Sfihi H., Zaitsev V.N., Fraissard J. Oniumsilica-immobilized-Keggin acids: acidity and catalytic activity for ethyl tert-butyl ether synthesis and acetic acid esterification with ethanol. J. Catal. 2009, 263(2):247.
18. Comprehensive Coordination Chemistry 1987, 739. Pergamon Press, Oxford. S.H. Laurie, G. Wilkinson, R.D. Gillard, J.A. McCleverty (Eds.).
19. Mercs L., Pozzi G., Quici S. Efficient condensation of carboxylic acids with alcohols catalyzed by fluorous ammonium triflates. Tetrahedron Lett. 2007, 48(17):3053.
20. Neumann R., Elad M.L. Vanadium silicate xerogels in hydrogen peroxide catalyzed oxidations. Appl. Catal. A 1995, 122(2):85.
21. Rác B., Molnár Á., Forgo P., Mohai M., Bertóti I. A comparative study of solid sulfonic acid catalysts based on various ordered mesoporous silica materials. J. Mol. Catal. A: Chem. 2006, 244(1-2):46.
22. Rahman M.M., Takafuji M., Ihara H. Preparation, telomerization, immobilization and application of N-alkyl l-phenylalanine-derived polymerizable organogelator for reversed-phase high-performance liquid chromatography. J. Chromatogr. A 2008, 1203(1):59.
23. Rajkumar E., Rajagopal S., Ramamurthy P., Vairamani M. Photophysics of ruthenium(II) complexes carrying amino acids in the ligand 2,20-bipyridine and intramolecular electron transfer from methionine to photogenerated Ru(III). Inorg. Chim. Acta 2009, 362:1629-1636.
24. 2]. Inorg. Chim. Acta 1989, 166(2):213.
25. 6-coordinated α-amino acids. J. Organomet. Chem. 1994, 470(1-2):183.
26. Thommes M. Physical adsorption characterization of nanoporous materials. Chem. Ing. Tech. 2010, 82(7):1059.
27. 2. J. Organomet. Chem. 1996, 517(1-2):191.
28. Zhi-rong Z., Qun W., Shu-yan Z. Catalytic effects of trace ruthenium on oxidation of dimethyl yellow with bromate and its application. J. China Univ. Min. Technol. 2008, 18(4):613.