Correlating sterics parameters and diastereomeric ratio values for a multicomponent assembly to predict exciton-coupled circular dichroism intensity and thereby enantiomeric excess of chiral secondary alcohols

Journal of the American Chemical Society

Volumn 134, Issue 16, 2012, Pages 7126-7134

  You, Lei ^a   Berman, Jeffrey S ^a   Lucksanawichien, Attaporn ^a   Anslyn, Eric V ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL STRUCTURE; ASYMMETRIC CATALYSTS; CALIBRATION CURVES; CHIRAL ALCOHOLS; CHIRAL SECONDARY ALCOHOLS; COVALENT ASSEMBLIES; DIASTEREOMERIC RATIOS; DYNAMIC COVALENT CHEMISTRY; ENANTIOMERIC EXCESS; LINEAR FREE ENERGY RELATIONSHIPS; MULTICOMPONENT ASSEMBLY; MULTICOMPONENTS; REACTION MECHANISM; SPECTRAL PROPERTIES; STERIC PARAMETERS; STERICS; TEST SAMPLES;

DICHROISM; ENANTIOMERS; EXCITONS; FORECASTING; METAL COMPLEXES; SCREENING;

STEREOCHEMISTRY;

ALCOHOL DERIVATIVE; METAL COMPLEX; PYRIDINE;

ARTICLE; CALIBRATION; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; CONTROLLED STUDY; CROSS COUPLING REACTION; DIASTEREOISOMER; ENANTIOMER; EXCITON COUPLED CIRCULAR DICHROISM; LINEAR FREE ENERGY RELATIONSHIP; PREDICTION; PROTON NUCLEAR MAGNETIC RESONANCE; PURIFICATION; SIGNAL PROCESSING; SPECTRAL SENSITIVITY; STEREOCHEMISTRY; SYNTHESIS; THERMODYNAMICS;

ALCOHOLS; CIRCULAR DICHROISM; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 84860327193     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3012534     Document Type: Article

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