Nonlinear frequency response analysis of dehydration phenomena in polymer electrolyte membrane fuel cells

International Journal of Hydrogen Energy

Volumn 37, Issue 9, 2012, Pages 7689-7701

  Kadyk, Thomas ^a,b   Hanke Rauschenbach, Richard ^a   Sundmacher, Kai ^a,b  

^a MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

^b OTTO VON GUERICKE UNIVERSITY   (Germany)

Author keywords

Dehydration; Electrochemical impedance spectroscopy; Nonlinear frequency response analysis; Polymer electrolyte membrane fuel cell; Proton transport

Indexed keywords

ACTIVE SITE; ANODE REACTION; CATALYST LAYERS; CO POISONING; FREQUENCY RESPONSE FUNCTIONS; KEY FEATURE; MEMBRANE RESISTANCE; NONLINEAR FREQUENCY RESPONSE; PEM FUEL CELL; POLYMER NETWORKS; PROTON TRANSPORT; PROTONIC; PROTONIC CONDUCTIVITIES; SECOND ORDERS;

DEHYDRATION; DEWATERING; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTROLYTES; FREQUENCY RESPONSE; POLYMERS;

PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

EID: 84860282188     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.01.148     Document Type: Article

References (33)

1. T. Kadyk, R. Hanke-Rauschenbach, and K. Sundmacher Nonlinear frequency response analysis of PEM fuel cells for diagnosis of dehydration, flooding and CO-poisoning J Electroanalyt Chem 630 2009 19 27
2. A.J. Bard, and L.R. Faulkner Electrochemical methods: fundamentals and applications 2nd ed. 2001 Wiley
3. E. Barsoukov, and J.R. MacDonald Impedance spectroscopy: theory, experiment, and applications 2nd ed. 2005 John Wiley and Sons
4. M.E. Orazem, and B. Tribollet Electrochemical impedance spectroscopy The electrochemical society series vol. 48 2008 Wiley-Interscience
5. X. Yuan, C. Song, H. Wang, and J. Zhang Electrochemical impedance spectroscopy in PEM fuel cells: fundamentals and applications 2009 Springer
6. T. Vidaković-Koch, V. Panić, M. Andrić, M. Petkovska, and K. Sundmacher Nonlinear frequency response analysis of the Ferrocyanide oxidation kinetics. Part I: a theoretical analysis J Phys Chem C 115 2011 17341 17351
7. V. Panić, T. Vidaković-Koch, M. Andrić, M. Petkovska, and K. Sundmacher Nonlinear frequency response analysis of the Ferrocyanide oxidation kinetics. Part II: measurement routine and experimental validation J Phys Chem C 115 2011 17352 17358
8. Q. Mao, U. Krewer, and R. Hanke-Rauschenbach Total harmonic distortion analysis for direct methanol fuel cell anode Electrochem Commun 12 2010 1517 1519
9. B. Bensmann, M. Petkovska, T. Vidaković-Koch, R. Hanke-Rauschenbach, and K. Sundmacher Nonlinear frequency response of electrochemical methanol oxidation kinetics: a theoretical analysis J Electrochem Soc 157 9 2010 B1279 B1289
10. T. Kadyk, R. Hanke-Rauschenbach, and K. Sundmacher Nonlinear frequency response analysis for the diagnosis of carbon monoxide poisoning in PEM fuel cell anodes J Appl Electrochem 41 2011 1021 1032
11. J. Jankowski Electrochemical methods for corrosion rate determination under cathodic polarisation conditions: a review. Part 2: AC methods Corros Rev 20 3 2002 179 200
12. K. Darowicki, and J. Majewska Harmonic analysis of electrochemical and corrosion systems - a review Corros Rev 17 5-6 1999 383 399
13. A. Groysman Corrosion monitoring Corros Rev 27 4-5 2009 205 343
14. T. Kadyk, S. Kirsch, R. Hanke-Rauschenbach, and K. Sundmacher Autonomous potential oscillations at the Pt anode of a PEM fuel cell under CO poisoning Electrochim Acta 56 2011 10593 10602
15. N. Wagner, W. Schnurnberger, B. Müller, and M. Lang Electrochemical impedance spectra of solid-oxide fuel cells and polymer membrane fuel cells Electrochim Acta 43 24 1998 3785 3793
16. 2/CO mixtures on Pt-based gas-diffusion electrodes J Electrochem Soc 146 11 1999 4031 4040
17. O. Himanen, T. Hottinen, M. Mikkola, and V. Saarinen Characterization of membrane electrode assembly with hydrogen-hydrogen cell and AC-impedance spectroscopy. Part I: experimental Electrochim Acta 52 1 2006 206 214
18. I.A. Schneider, S. von Dahlen, A. Wokaun, and G.G. Scherer A segmented microstructured flow field approach for submillimeter resolved local current measurement in channel and land areas of a PEFC J Electrochem Soc 157 3 2010 B338 B341
19. ® dehydration in PEM fuel cells J Appl Electrochem 34 7 2004 705 714
20. K.C. Neyerlin, H.A. Gasteiger, C.K. Mittelstaedt, J. Jorne, and W. Gu Effect of relative humidity on oxygen reduction kinetics in a PEMFC J Electrochem Soc 152 6 2005 A1073 A1080
21. M. Ciureanu, and H. Wang Electrochemical impedance study of anode CO-poisoning in PEM fuel cells J New Mat Electrochem Syst 3 2 2000 107 119
22. 2/CO mixtures on Pt/Ru-based gas-diffusion electrodes J Phys Chem B 103 44 1999 9645 9657
23. T.E. Springer, T.A. Zawodzinski, and S. Gottesfeld Polymer electrolyte fuel cell model J Electrochem Soc 138 8 1991 2334 2341
24. T.A. Zawodzinksi, C. Derouin, S. Radzinski, R.J. Sherman, V.T. Smith, and T.E. Springer Water uptake by and transport through Nafion 117 membranes J Electrochem Soc 140 4 1993 1041 1047
25. C. Yang, S. Srinivasan, A.B. Bocarsly, S. Tulyani, and J.B. Benziger A comparison of physical properties and fuel cell performance of Nafion and zirconium phosphate/Nafion composite membranes J Membr Sci 237 1-2 2004 145 161
26. T. Springer, T. Zawodzinski, and S. Gottesfeld Modelling of polymer electrolyte fuel cell performance with reformate feed streams: effects of low levels of CO in hydrogen J. McBreen, S. Muckerjee, S. Srinivasan, Electrode materials and processes for energy conversion and storage The electrochemical society proceedings vol. 97 1997 15 24
27. 2 dilution, and high fuel utilization J Electrochem Soc 148 1 2001 A11 A23
28. J. Wang, T. Springer, and R. Adzic Dual-pathway kinetic equation for the hydrogen oxidation reaction on Pt electrodes J Electrochem Soc 153 2006 A1732 A1740
29. S. Vilekar, I. Fishtik, and R. Datta Kinetics of the hydrogen electrode reaction J Electrochem Soc 157 7 2010 B1040 B1050
30. N.R. Elezović, L. Gajic-Krstajic, V. Radmilovic, L. Vracar, and N.V. Krstajic Effect of chemisorbed carbon monoxide on Pt/C electrode on the mechanism of the hydrogen oxidation reaction Electrochim Acta 54 4 2009 1375 1382
31. 2 bleeding in a PEM fuel cell anode Int J Energy Res 27 12 2003 1095 1116
32. J.S. Newman Electrochemical systems; chap. 5 2nd ed. 1991 Prentice-Hall New Jersey pp. 116-133
33. L.A. Belfiore Transport phenomena for chemical reactor design 2003 John Wiley & Sons