Insertion of CO 2 into divalent group 2 and 12 bis(silylamides)

Main Group Chemistry

Volumn 11, Issue 1, 2012, Pages 13-29

  Felix, Ana M ^a   Boro, Brian J ^a   Dickie, Diane A ^a   Tang, Yongjun ^a   Saria, Josephat A ^a   Moasser, Bahram ^b   Stewart, Constantine A ^c   Frost, Brian J ^d   Kemp, Richard A ^a,c  

^a UNIVERSITY OF NEW MEXICO   (United States)

^b GEORGETOWN UNIVERSITY   (United States)

^c ADVANCED MATERIALS LABORATORY   (United States)

^d UNIVERSITY OF NEVADA   (United States)

Author keywords

carbodiimides; CO 2, main group; isocyanates; X ray crystallography

Indexed keywords

EID: 84860254511     PISSN: 10241221     EISSN: 17451167     Source Type: Journal    
DOI: 10.3233/MGC-2012-0057     Document Type: Conference Paper

References (38)

1. H. Arakawa, M. Aresta, J.N. Armor, M.A. Barteau, E.J. Beckman, A.T. Bell, J.E. Bercaw, C. Creutz, E. Dinjus, D.A. Dixon, K. Domen, D.L. DuBois, J. Eckert, E. Fujita, D.H. Gibson,W.A. Goddard, D.W. Goodman, J. Keller, G.J. Kubas, H.H. Kung, J.E. Lyons, L.E. Manzer, T.J. Marks, K. Morokuma, K.M. Nicholas, R. Periana, L. Que, J. Rostrup-Nielson, W.M.H. Sachtler, L.D. Schmidt, A. Sen, G.A. Somorjai, P.C. Stair, B.R. Stults and W. Tumas, Catalysis research of relevance to carbon management: Progress, challenges, and opportunities, Chem Rev 101 (2001), 953-996. (Pubitemid 35375211)
2. T. Sakakura, J.-C. Choi and H. Yasuda, Transformation of carbon dioxide, Chem Rev 107 (2007), 2365-2387. (Pubitemid 47029097)
3. R. Martín and A.W. Kleij, Myth or reality? Fixation of carbon dioxide into complex organic matter under mild conditions, ChemSusChem 4 (2011), 1259-1263.
4. M. Peters, B. Köhler, W. Kuckshinrichs, W. Leitner, P. Markewitz and T.E. Müller, Chemical technologies for exploiting and recycling carbon dioxide into the value chain, ChemSusChem 4 (2011), 1216-1240.
5. 2 as a chemical feedstock: Opportunities and challenges, Dalton Trans (2007), 2975-2992. (Pubitemid 47152307)
6. P.G. Jessop, T. Ikariya and R. Noyori, Homogeneous hydrogenation of carbon dioxide, Chem Rev 95 (1995), 259-272.
7. W. Leitner, The coordination chemistry of carbon dioxide and its relevance for catalysis: A critical study, Coord Chem Rev 153 (1996), 257-284.
8. 2 for sustainable development involving energy, catalysis, adsorption and chemical processing, Catal Today 115 (2006), 2-32.
9. M. Mikkelsen, M. Jorgensen and F.C. Krebs, The teraton challenge. A review of fixation and transformation of carbon dioxide, Energy Environ Sci 3 (2010), 43-81.
10. 2 conversion, Catal Today 148 (2009), 221-231.
11. L.R. Sita, J.R. Babcock and R. Xi, Facile metathetical exchange between carbon dioxide and the divalent group 14 bisamides M[N(SiMe3)2]2 (M=Ge and Sn), J Am Chem Soc 118 (1996), 10912-10913. (Pubitemid 26390030)
12. J.R. Babcock and L.R. Sita, Facile preparation of unsymmetrical carbodiimides via in situ tin(II)-mediated heterocumulene metathesis, J Am Chem Soc 120 (1998), 5585-5586.
13. C.S. Weinert, I.A. Guzei, A.L. Rheingold and L.R. Sita, Heterocumulene metathesis of Pb[N(SiMe3)2]2. High-yield syntheses of the heteroleptic dimer {Pb[N(SiMe3)2](-OSiMe3)}2 and the novel lead(II) oxo cluster Pb7(3-O)(4-O)(-OSiMe3)10, Organometallics 17 (1998), 498-500.
14. R. Xi and L.R. Sita, Mechanistic details for metathetical exchange between XCO (X=O and RN) and the tin(II) dimer, {Sn[N(SiMe3)2](-OBut)}2, Inorg Chim Acta 270 (1998), 118-122. (Pubitemid 128350833)
15. U. Wannagat, H. Kuckertz, C. Krueger and J. Pump, Silicon-nitrogen compounds. XXXVIII. Reactions of sodium bis(trimethylsilyl)amide with carbon chalcogens and halides, Z Anorg Allg Chem 333 (1964), 54-61.
16. 2, ACS Symp Ser 917 (2006), 410-421.
17. 3)2]}2, Polyhedron 20 (2001), 815-821. (Pubitemid 32936578)
18. Bruker, APEX2, Bruker AXS, Inc.: Madison, Wisconsin, USA, 2007.
19. G.M. Sheldrick, A short history of SHELX, Acta Crystallogr., Sect. A: Found. Crystallogr A64 (2008), 112-122.
20. K. Brandenburg, Diamond, Crystal Impact GbR: Bonn, Germany, 1999.
21. Y. Tang, L.N. Zakharov, A.L. Rheingold and R.A. Kemp, Insertion of carbon dioxide into Mg-N bonds. Structural characterization of a previously unknown-2) chelation mode to magnesium in magnesium carbamates, Organometallics 23 (2004), 4788-4791.
22. Y. Tang, A.M. Felix, B.J. Boro, L.N. Zakharov, A.L. Rheingold and R.A. Kemp, Syntheses and X-ray crystal structures of monomeric zinc and mercury bis(silylamides), Polyhedron 24 (2005), 1093-1100. (Pubitemid 40714320)
23. Y. Tang, W.S. Kassel, L.N. Zakharov, A.L. Rheingold and R.A. Kemp, Insertion reactions of carbon dioxide into Zn-N bonds: Syntheses and structures of tetrameric and dimeric alkylzinc carbamato complexes, Inorg Chem 44 (2005), 359-364. (Pubitemid 40129363)
24. Y. Tang, L.N. Zakharov,W.S. Kassel, A.L. Rheingold and R.A.Kemp, Synthesis and structural characterization of solvated calcium amides containing bulky silylamide ligands, Inorg Chim Acta 358 (2005), 2014-2022. (Pubitemid 40341798)
25. Y. Tang, L.N. Zakharov, A.L. Rheingold and R.A. Kemp, Synthesis and structural characterization of magnesium amide complexes containing -N[(R)(SiMe3)] ligands, Organometallics 24 (2005), 836-841. (Pubitemid 40338498)
26. Y. Tang, L.N. Zakharov, A.L. Rheingold and R.A. Kemp, Two new bulky amido ligands useful for the preparation of metal complexes and examples of their reactivity, Inorg Chim Acta 359 (2006), 775-781.
27. M.F. Lappert, A.R. Sanger, R.C. Srivastava and P.P. Power, Metal and Metalloid Amides: Synthesis, Structure, and Physical and Chemical Properties, John Wiley and Sons, 1980, pp. 847.
28. L. Messerle, Convenient pressure reactors for organometallic reactivity studies, ACS Symp Ser 357 (1987), 198-203.
29. V.E. Shashoua, The homopolymerization of monoisocyanates, J Am Chem Soc 81 (1959), 3156.
30. A.J. Bur and L.J. Fetters, The chain structure, polymerization, and conformation of polyisocyanates, Chem Rev 76 (1976), 727-746.
31. C.J. Smith, T.R. Early, A.B. Holmes and R.E. Shute, Palladium catalysed cross-coupling reactions of silylamines, Chem Commun (2004), 1976-1977. (Pubitemid 39336029)
32. N. Hering, K. Schreiber, R. Riedel, O. Lichtenberger and J. Woltersdorf, Synthesis of polymeric precursors for the formation of nanocrystalline Ti-C-N/amorphous Si-C-N composites, Appl Organomet Chem 15 (2001), 879-886.
33. 2), OCS, and CS2) and comparison to that of bis[bis(trimethylsilyl) amido]tin, Inorg Chem 49 (2010), 11133-11141.
34. 2) and epoxides: Catalyst synthesis and unprecedented polymerization activity, J Am Chem Soc 123 (2001), 8738-8749. (Pubitemid 32852674)
35. A. Belforte, F. Calderazzo, U. Englert and J. Straehle, Deoxygenation of carbon dioxide to diethylformamide in the zinc/diethylamine/carbon dioxide system. Crystal and molecular structure of hexakis(diethylcarbamato) oxotetrazinc, Inorg Chem 30 (1991), 3778-3781.
36. 2CNMe2)6, Inorg Chim Acta 350 (2003), 661-664.
37. C.S. McCowan, T.L. Groy and M.T. Caudle, Synthesis, structure, and preparative transamination of tetrazinc carbamato complexes having the basic zinc carboxylate structure, Inorg Chem 41 (2002), 1120-1127.
38. 2 fixation and their use as precursors for ZnO particles under mild conditions, Eur J Inorg Chem 2008 (2008), 3177-3185.