Solvent free selective oxidation of styrene and benzyl alcohol to benzaldehyde over an eco-friendly and reusable catalyst, undecamolybdophosphate supported onto neutral alumina

Industrial and Engineering Chemistry Research

Volumn 51, Issue 2, 2012, Pages 732-740

  Patel, Anjali ^a   Pathan, Soyeb ^a  

^a M S UNIVERSITY OF BARODA   (India)

Author keywords

[No Author keywords available]

Indexed keywords

BENZYL ALCOHOL; ECO-FRIENDLY; MOLAR RATIO; PHYSICOCHEMICAL TECHNIQUES; REACTION PARAMETERS; REACTION TEMPERATURE; REUSABLE CATALYSTS; SELECTIVE OXIDATION; SOLVENT FREE; SOLVENT-FREE OXIDATION; XRD;

ALDEHYDES; ALUMINA; STYRENE;

CATALYST SUPPORTS;

EID: 84860143558     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie2020608     Document Type: Conference Paper

References (24)

1. Ulmann's, Encyclopedia of Industrial Chemistry, 5th ed.; VCH: Weinheim, 1985, p 469.
2. Pybus, D. H., Sell, C. S., Eds. The Chemistry of Fragrances; RSC Paperbacks: Cambridge, 1999.
3. Singh, R. P.; Subbarao, H. N.; Dev, S. Organic reactions in a solid matrix-V: Silica-gel supported chromic acid reagents. Tetrahedron 1979, 35, 1789-1793.
4. Fey, T.; Fischer, H.; Bachmann, S.; Albert, K.; Bolm, C. Silica-Supported TEMPO Catalysts: Synthesis and Application in the Anelli Oxidation of Alcohols. J. Org. Chem. 2001, 66, 8154-8159.
5. Li, G.; Enache, D. I.; Edwards, J. K.; Carley, A. F.; Knight, D. W.; Hutchings, G. J. Solvent-free oxidation of benzyl alcohol with oxygen using zeolite-supported Au and Au-Pd catalysts. Catal. Lett. 2006, 110, 7-13.
6. 2. J. Am. Chem. Soc. 1991, 113, 3611-3613.
7. 40) combined with cetylpyridinium bromide in the epoxidation of cyclopentene. J. Mol. Catal. A: Chem. 2005, 230, 121-128.
8. 2, as insoluble solid bifunctional catalysts: synthesis and selective oxidation of benzyl alcohol in liquid-solid systems. Appl. Catal. A: Gen. 2001, 218, 91-99.
9. Li, M.; Shen, J.; Ge, X.; Chen, X. Characterization and catalytic performance of supported molybdophosphoric acid catalysts for the oxidation of propylene to acetone. Appl. Catal. A: Gen. 2001, 206, 161-169.
10. 40 (n ≥ 3) for oxidation of ethanol. Appl. Catal. A: Gen. 2000, 194-195, 123-127.
11. Li, W.; Lee, K.; Oshihara, K.; Ueda, W. Catalytic performance for propane selective oxidation and surface properties of 12-molybdophosphoric acid treated with pyridine. Appl. Catal. A: Gen. 1999, 182, 357-363.
12. 40- Based Heteropoly Compounds. J. Catal. 1996, 163, 87-94.
13. Sharma, P.; Patel, A. Zirconia supported 12-molybdophosphoric acid: Physico-chemical characterization and non-solvent liquid phase oxidation of styrene. Appl. Surf. Sci. 2009, 255, 7635-7641.
14. Sharma, P.; Patel, A. Supported 12-molybdophosphoric acid: Characterization and non-solvent liquid phase oxidation of styrene. J. Mol. Catal. A: Chem. 2009, 299, 37-43.
15. Mizuno, N.; Yamaguchi, K.; Kamata, K. Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates. Coord. Chem. Rev. 2005, 249, 1944-1956.
16. Mizuno, N.; Misono, M. Heterogeneous Catalysis. Chem. Rev. 1998, 98, 199-218.
17. Hill, C. L.; Chrisina, C.; Prosser-McCartha, M. Homogeneous catalysis by transition metal oxygen anion clusters. Coord. Chem. Rev. 1995, 143, 407-455.
18. Mizuno, N.; Hikichi, S.; Yamaguchi, K.; Uchida, S.; Nakagawa, Y.; Uehara, K.; Kamata, K. Molecular design of selective oxidation catalyst with polyoxometalate. Catal. Today 2006, 117, 32-36.
19. Pathan, S.; Patel, A. Novel heterogeneous catalyst, supported undecamolybdophosphate: synthesis, physico-chemical characterization and solvent-free oxidation of styrene. Dalton Trans. 2011, 40, 348-355.
20. Okuhara, T.; Mizuno, N.; Misono, M. Catalytic Chemistry of Heteropoly Compounds. Adv. Catal. 1996, 41, 113-252.
21. Sheldon, A.; Walau, M.; Arends, I. W. C. E.; Schuchurdt, U. Heterogeneous Catalysts for Liquid- Phase Oxidations: Philosophers' Stones or Trojan Horses? Acc. Chem. Res. 1998, 31, 485-493.
22. 40], and its use as a catalyst in olefin epoxidation. Trans. Met. Chem. 2008, 33, 635-642.
23. Manyar, H. G.; Chaure, G. S.; Kumar, A. Supported polyperoxometallates: Highly selective catalyst for oxidation of alcohols to aldehydes. J. Mol. Catal. A: Chem. 2006, 243, 244-252.
24. 7- as benzyl alcohol oxidation catalyst with hydrogen peroxide. Catal. Commun. 2008, 9, 1688-1691.