Reaction pathway and rate-determining step of the Schmidt rearrangement/fragmentation: A kinetic study

Journal of Organic Chemistry

Volumn 77, Issue 8, 2012, Pages 4073-4078

  Akimoto, Ryo ^a   Tokugawa, Takehiro ^a   Yamamoto, Yutaro ^a   Yamataka, Hiroshi ^a  

^a RIKKYO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BECKMANN REARRANGEMENT; ELECTRON-DONATING SUBSTITUENTS; HAMMETT PLOTS; INDUCTION PERIODS; KINETIC STUDY; MOLECULAR DYNAMICS SIMULATIONS; PRODUCT SELECTIVITIES; PSEUDO-FIRST-ORDER RATE CONSTANT; RATE DETERMINING STEP; RATE MEASUREMENTS; REACTION PATHWAYS; SATURATION KINETICS; SUBSTITUENT EFFECT; TRIMETHYLSILYL AZIDE;

MOLECULAR DYNAMICS; RATE CONSTANTS;

IONS;

AZIDE;

ARTICLE; BECKMANN REARRANGEMENT; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; FRAGMENTATION REACTION; MOLECULAR DYNAMICS; SCHMIDT REARRANGEMENT;

EID: 84860123984     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo300419c     Document Type: Article

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