Isolation of (CO) 1- and (CO 2) 1- radical complexes of rare earths via Ln(NR 2) 3/K reduction and [K 2(18-crown-6) 2] 2+ oligomerization

Journal of the American Chemical Society

Volumn 134, Issue 14, 2012, Pages 6064-6067

  Fang, Ming ^a   Farnaby, Joy H ^a   Ziller, Joseph W ^a   Bates, Jefferson E ^a   Furche, Filipp ^a   Evans, William J ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

18-CROWN-6; CO-REDUCTION; COLORLESS CRYSTALS; DICATIONS; DIETHYL ETHERS; POLYMERIC STRUCTURES; RADICAL COMPLEXES; REACTION CONDITIONS; TRIGONAL BIPYRAMIDAL;

BYPRODUCTS; CARBON DIOXIDE; CROWN ETHERS; ETHERS; OLIGOMERIZATION; OLIGOMERS; POTASSIUM;

COMPLEXATION;

ANION; CARBON MONOXIDE; ETHER; LANTHANIDE; LIGAND; LUTETIUM; OXYGEN; POLYMER; POTASSIUM DERIVATIVE; RADICAL; YTTRIUM;

ARTICLE; ATOM; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL; ISOLATION PROCEDURE; OLIGOMERIZATION; REACTION ANALYSIS; REDUCTION KINETICS; ROOM TEMPERATURE; SYNTHESIS; TEMPERATURE; VACUUM;

EID: 84859622476     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja211220r     Document Type: Article

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