Dispersion energy enforced dimerization of a cyclic disilylated plumbylene

Journal of the American Chemical Society

Volumn 134, Issue 14, 2012, Pages 6409-6415

  Arp, Henning ^a   Baumgartner, Judith ^a   Marschner, Christoph ^a   Zark, Patrick ^b   Müller, Thomas ^b  

^a GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

^b UNIVERSITY OF OLDENBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DENSITY FUNCTIONAL COMPUTATIONS; DISPERSION ENERGIES; DONOR-ACCEPTORS; TRIETHYLPHOSPHINE; TRIMETHYLSILYL;

DIMERS; PHOSPHORUS COMPOUNDS; VAN DER WAALS FORCES;

DENSITY FUNCTIONAL THEORY;

BROMINE DERIVATIVE; DIMER; ORGANOLEAD COMPOUND; PHOSPHINE DERIVATIVE; SILANE DERIVATIVE;

ARTICLE; CHEMICAL BINDING; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; DIMERIZATION; DISPERSION; SILYLATION;

EID: 84859586438     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja300654t     Document Type: Article

References (44)

1. Goldberg, D. E.; Harris, D. H.; Lappert, M. F.; Thomas, K. M. J. Chem. Soc., Chem. Commun. 1976, 261-262
2. Goldberg, D. E.; Hitchcock, P. B.; Lappert, M. F.; Thomas, K. M.; Thorne, A. J.; Fjeldberg, T.; Haaland, A.; Schilling, B. E. R. J. Chem. Soc., Dalton Trans. 1986, 2387-2394
3. Ganzer, I.; Hartmann, M.; Frenking, G. In The Chemistry of Organic Germanium, Tin and Lead Compounds Vol. 2; Rappoport, Z., Ed.; John Wiley & Sons, Ltd.: 2002; pp 169-282.
4. Fischer, R. C.; Power, P. P. Chem. Rev. 2010, 110, 3877-3923
5. Mizuhata, Y.; Sasamori, T.; Tokitoh, N. Chem. Rev. 2009, 109, 3479-3511
6. Lee, V. Y.; Fukawa, T.; Nakamoto, M.; Sekiguchi, A.; Tumanskii, B. L.; Karni, M.; Apeloig, Y. J. Am. Chem. Soc. 2006, 128, 11643-11651
7. Klinkhammer, K. W.; Schwarz, W. Angew. Chem., Int. Ed. Engl. 1995, 34, 1334-1336
8. Klinkhammer, K. Polyhedron 2002, 21, 587-598
9. Arp, H.; Baumgartner, J.; Marschner, C.; Müller, T. J. Am. Chem. Soc. 2011, 133, 5632-5635
10. Kayser, C.; Kickelbick, G.; Marschner, C. Angew. Chem., Int. Ed. 2002, 41, 989-992
11. Fischer, R.; Frank, D.; Gaderbauer, W.; Kayser, C.; Mechtler, C.; Baumgartner, J.; Marschner, C. Organometallics 2003, 22, 3723-3731
12. Welch, G. C.; Prieto, R.; Dureen, M. A.; Lough, A. J.; Labeodan, O. A.; Holtrichter-Rossmann, T.; Stephan, D. W. Dalton Trans. 2009, 1559-1570
13. Wrackmeyer, B.; Stader, C.; Horchler, K. J. Magn. Reson. 1989, 83, 601-607
14. Fischer, R.; Konopa, T.; Baumgartner, J.; Marschner, C. Organometallics 2004, 23, 1899-1907
15. Müller, T. J. Organomet. Chem. 2003, 686, 251-256
16. Klett, J.; Klinkhammer, K. W.; Niemeyer, M. Chem.-Eur. J. 1999, 5, 2531-2536
17. Eaborn, C.; Ganicz, T.; Hitchcock, P. B.; Smith, J. D.; Sözerli, S. E. Organometallics 1997, 16, 5621-5622
18. Klinkhammer, K. Silylderivate der schweren Alkalimetalle in der Synthese niedervalenter Hauptgruppenelementverbindungen, habilitation thesis, Universität Stuttgart, 1998.
19. Pyykkö, P.; Atsumi, M. Chem.-Eur. J. 2009, 15, 12770-12779
20. Mantina, M.; Chamberlin, A. C.; Valero, R.; Cramer, C. J.; Truhlar, D. G. J. Phys. Chem. A 2009, 113, 5806-5812
21. Preut, H.; Huber, F. Z. Anorg. Allg. Chem. 1976, 419, 92-96
22. Weidenbruch, M.; Kilian, H.; Peters, K.; Schnering, H. G. V.; Marsmann, H. Chem. Ber. 1995, 128, 983-985
23. Stabenow, F.; Saak, W.; Marsmann, H.; Weidenbruch, M. J. Am. Chem. Soc. 2003, 125, 10172-10173
24. Stürmann, M.; Weidenbruch, M.; Klinkhammer, K. W.; Lissner, F.; Marsmann, H. Organometallics 1998, 17, 4425-4428
25. Stürmann, M.; Saak, W.; Marsmann, H.; Weidenbruch, M. Angew. Chem., Int. Ed. 1999, 38, 187-189
26. The Gaussian 09 program was used. Gaussian 09 Revision B. 01; Gaussian, Inc.: Wallingford, 2010.
27. Pb(II)Si(IV) bonds in plumbylene 270-271 pm, see: Klinkhammer, K. In The Chemistry of Organic Germanium, Tin and Lead Compounds Vol. 2; Rappoport, Z., Ed.; John Wiley & Sons, Ltd.: 2002; pp 283-357.
28. Wiberg, N.; Schuster, H.; Simon, A.; Peters, K. Angew. Chem. 1986, 98, 100-101
29. Masters (née Hinchley), S. L.; Grassie, D. A.; Robertson, H. E.; Hölbling, M.; Hassler, K. Chem. Commun. 2007, 2618-2620
30. Bock, H.; Solouki, B. In The Chemistry of Organic Silicon Compounds, Vol. 3; Apeloig, Y.; Rappoport, Z., Eds.; Wiley: Chichester, 2001; p 187.
31. Sieffert, N.; Bühl, M. Inorg. Chem. 2009, 48, 4622-4624
32. Schreiner, P. R.; Chernish, L. V.; Gunchenko, P. A.; Tikhonchuk, E. Y.; Hausmann, H.; Serafin, M.; Schlecht, S.; Dahl, J. E. P.; Carlson, R. M. K.; Fokin, A. A. Nature 2011, 477, 308-311
33. Grimme, S.; Schreiner, P. R. Angew. Chem., Int. Ed. 2011, 50, 12639-12642
34. Zhao, Y.; Truhlar, D. G. Theor. Chem. Acc. 2007, 120, 215-241
35. Adapted from Goethe, J. W. "Faust", J. G. Cotta'schen Buchhandlung Tübingen 1808, translated by Priest, G. M. Princeton University, 1932.
36. Takahashi, M.; Tsutsui, S.; Sakamoto, K.; Kira, M.; Müller, T.; Apeloig, Y. J. Am. Chem. Soc. 2000, 123, 347-348
37. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520
38. Morris, G. A.; Freeman, R. J. Am. Chem. Soc. 1979, 101, 760-762
39. Helmer, B. J.; West, R. Organometallics 1982, 1, 877-879
40. SAINTPLUS: Software Reference Manual, Version 6.45: Bruker-AXS: Madison, WI, 1997-2003.
41. Blessing, R. H. Acta Crystallogr., Ser. A 1995, 51, 33-38
42. SADABS: Version 2.1; Bruker-AXS: Madison, WI, 1998.
43. Sheldrick, G. M. Acta Crystallogr., Ser. A 2008, 64, 112-122
44. Lancaster, S. Alkylation of boron trifluoride with pentafluorophenyl Grignard reagent; Tris(pentafluorophenyl)boron. http://cssp.chemspider.com/215 (accessed Nov 21, 2011).