Direct conversion of methane into formaldehyde mediated by [Al 2O 3] .+ at room temperature

Angewandte Chemie - International Edition

Volumn 51, Issue 15, 2012, Pages 3703-3707

  Wang, Zhe Chen ^a,c   Dietl, Nicolas ^a   Kretschmer, Robert ^a   Ma, Jia Bi ^a   Weiske, Thomas ^a   Schlangen, Maria ^a   Schwarz, Helmut ^a,b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b KING ABDULAZIZ UNIVERSITY   (Saudi Arabia)

^c Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

density functional calculations; gas phase reactions; mass spectrometry; radical ions; reaction mechanisms

Indexed keywords

DIRECT CONVERSION; GAS-PHASE REACTIONS; GASPHASE; HYDROGEN-ATOM TRANSFER; ONE STEP; RADICAL IONS; REACTION MECHANISM; ROOM TEMPERATURE;

DENSITY FUNCTIONAL THEORY; HYDROGEN; MASS SPECTROMETRY; PHASE INTERFACES;

METHANE;

EID: 84859554395     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201200015     Document Type: Article

References (66)

1. J. R. Webb, T. Bolaño, T. B. Gunnoe, ChemSusChem 2011, 4, 37
2. G. A. Olah, A. Goeppert, G. K. S. Prakash, Beyond Oil and Gas: The Methanol Economy, Wiley-VCH, Weinheim, 2009.
3. D. Schröder, H. Schwarz, Proc. Natl. Acad. Sci. USA 2008, 105, 18114.
4. G. Reuss, W. Disteldorf, A. O. Gamer, A. Hilt, "Formaldehyde" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002.
5. G. A. Du, S. Y. Lim, Y. H. Yang, C. Wang, L. Pfefferle, G. L. Haller, Appl. Catal. A 2006, 302, 48
6. H. Berndt, A. Martin, A. Brückner, E. Schreier, D. Müller, H. Kosslick, G. U. Wolf, B. Lücke, J. Catal. 2000, 191, 384.
7. H. Matsumura, K. Okumura, T. Shimamura, N. Ikenaga, T. Miyake, T. Suzuki, J. Mol. Catal. A 2006, 250, 122.
8. D. L. An, Q. H. Zhang, Y. Wang, Catal. Today 2010, 157, 143.
9. J. G. Larson, W. K. Hall, J. Phys. Chem. 1965, 69, 3080.
10. R. Wischert, C. Copéret, F. Delbecq, P. Sautet, Angew. Chem. 2011, 123, 3260
11. Angew. Chem. Int. Ed. 2011, 50, 3202
12. C. Copéret, Chem. Rev. 2010, 110, 656.
13. H. Schwarz, Angew. Chem. 2011, 123, 10276
14. Angew. Chem. Int. Ed. 2011, 50, 10096
15. M. Schlangen, H. Schwarz, J. Catal. 2011, 284, 126
16. D. K. Böhme, H. Schwarz, Angew. Chem. 2005, 117, 2388
17. Angew. Chem. Int. Ed. 2005, 44, 2336.
18. M. Sierka, J. Döbler, J. Sauer, G. Santambrogio, M. Brummer, L. Woste, E. Janssens, G. Meijer, K. R. Asmis, Angew. Chem. 2007, 119, 3437
19. Angew. Chem. Int. Ed. 2007, 46, 3372.
20. S. Feyel, J. Döbler, R. Höckendorf, M. K. Beyer, J. Sauer, H. Schwarz, Angew. Chem. 2008, 120, 1972
21. Angew. Chem. Int. Ed. 2008, 47, 1946.
22. N. Dietl, M. Schlangen, H. Schwarz, Angew. Chem. 2012, DOI:; Angew. Chem. Int. Ed. 2012, DOI
23. Z.-C. Wang, T. Weiske, R. Kretschmer, M. Schlangen, M. Kaupp, H. Schwarz, J. Am. Chem. Soc. 2011, 133, 16930
24. K. Chen, Z.-C. Wang, M. Schlangen, Y.-D. Wu, X. Zhang, H. Schwarz, Chem. Eur. J. 2011, 17, 9619
25. A. BožoviÄ, S. Feil, G. K. Koyanagi, A. A. Viggiano, X. Zhang, M. Schlangen, H. Schwarz, D. K. Bohme, Chem. Eur. J. 2010, 16, 11605
26. M. Schlangen, H. Schwarz, Dalton Trans. 2009, 46, 10155
27. S. Feyel, J. Döbler, D. Schröder, J. Sauer, H. Schwarz, Angew. Chem. 2006, 118, 4797
28. Angew. Chem. Int. Ed. 2006, 45, 4681
29. I. Kretzschmar, A. Fiedler, J. N. Harvey, D. Schröder, H. Schwarz, J. Phys. Chem. A 1997, 101, 6252
30. D. Schröder, A. Fiedler, J. Hrušák, H. Schwarz, J. Am. Chem. Soc. 1992, 114, 1215.
31. N. Dietl, C. van der Linde, M. Schlangen, M. K. Beyer, H. Schwarz, Angew. Chem. 2011, 123, 5068
32. Angew. Chem. Int. Ed. 2011, 50, 4966
33. N. Dietl, R. F. Höckendorf, M. Schlangen, M. Lerch, M. K. Beyer, H. Schwarz, Angew. Chem. 2011, 123, 1466
34. Angew. Chem. Int. Ed. 2011, 50, 1430
35. Y.-X. Zhao, X.-N. Wu, Z.-C. Wang, S.-G. He, X.-L. Ding, Chem. Commun. 2010, 46, 1736
36. Z.-C. Wang, X.-N. Wu, Y.-X. Zhao, J.-B. Ma, X.-L. Ding, S.-G. He, Chem. Phys. Lett. 2010, 489, 25
37. J.-B. Ma, X.-N. Wu, Y.-X. Zhao, X.-L. Ding, S.-G. He, Phys. Chem. Chem. Phys. 2010, 12, 12223
38. J. Roithová, D. Schröder, Chem. Rev. 2010, 110, 1170
39. A. BožoviÄ, S. Feil, G. K. Koyanagi, A. A. Viggiano, X. Zhang, M. Schlangen, H. Schwarz, D. K. Bohme, Chem. Eur. J. 2010, 16, 11605
40. G. de Petris, A. Troiani, M. Rosi, G. Angelini, O. Ursini, Chem. Eur. J. 2009, 15, 4248
41. D. Schröder, J. Roithová, Angew. Chem. 2006, 118, 5835
42. Angew. Chem. Int. Ed. 2006, 45, 5705
43. M. Brönstrup, D. Schröder, I. Kretzschmar, H. Schwarz, J. N. Harvey, J. Am. Chem. Soc. 2001, 123, 142
44. A. Fiedler, I. Kretzschmar, D. Schröder, H. Schwarz, J. Am. Chem. Soc. 1996, 118, 9941.
45. M. B. Comisarow, V. Grassi, G. Parisod, Chem. Phys. Lett. 1978, 57, 413.
46. M. Schlangen, D. Schröder, H. Schwarz, Helv. Chim. Acta 2005, 88, 1405.
47. T. Su, M. T. Bowers, J. Chem. Phys. 1973, 58, 3027.
48. K. Eller, W. Zummack, H. Schwarz, J. Am. Chem. Soc. 1990, 112, 621
49. K. Eller, H. Schwarz, Int. J. Mass Spectrom. Ion Processes 1989, 93, 243.
50. D. Schröder, H. Schwarz, D. E. Clemmer, Y. Chen, P. B. Armentrout, V. I. Baranov, D. K. Böhme, Int. J. Mass Spectrom. Ion Processes 1997, 161, 175.
51. Gaussian 09 (Revision A.02), M. J. Frisch, et al., Gaussian, Inc., Wallingford CT, 2009.
52. A. D. Becke, J. Chem. Phys. 1993, 98, 5648
53. A. D. Becke, Phys. Rev. A 1988, 38, 3098
54. C. T. Lee, W. T. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785.
55. W. Kohn, L. J. Sham, Phys. Rev. 1965, 140, A 1133.
56. A. Schafer, C. Huber, R. Ahlrichs, J. Chem. Phys. 1994, 100, 5829.
57. Z.-C. Wang, N. Dietl, R. Kretschmer, T. Weiske, M. Schlangen, H. Schwarz, Angew. Chem. 2011, 123, 12559
58. Angew. Chem. Int. Ed. 2011, 50, 12351.
59. Z. C. Wang, X. N. Wu, Y. X. Zhao, J. B. Ma, X. L. Ding, S. G. He, Chem. Eur. J. 2011, 17, 3449.
60. H. B. Schlegel, J. Comput. Chem. 1982, 3, 214.
61. C. Peng, P. Y. Ayala, H. B. Schlegel, M. J. Frisch, J. Comput. Chem. 1996, 17, 49.
62. D. G. Truhlar, M. S. Gordon, Science 1990, 249, 491
63. C. Gonzalez, H. B. Schlegel, J. Phys. Chem. 1990, 94, 5523
64. C. Gonzalez, H. B. Schlegel, J. Chem. Phys. 1989, 90, 2154
65. K. Fukui, Acc. Chem. Res. 1981, 14, 363
66. K. Fukui, J. Phys. Chem. 1970, 74, 4161.