Formation of an unexpected rearrangement product using Grubbs' second generation catalyst: 2-allyl-3,4-dihydro-2H-1,4-benzothiazines from diene precursors

Tetrahedron Letters

Volumn 53, Issue 19, 2012, Pages 2384-2387

  Morgans, Garreth L ^a   Yadav, Dharmendra B ^a   Fernandes, Manuel A ^a   De Koning, Charles B ^a   Michael, Joseph P ^a   Van Otterlo, Willem A L ^a,b  

^a UNIVERSITY OF THE WITWATERSRAND   (South Africa)

^b STELLENBOSCH UNIVERSITY   (South Africa)

Author keywords

Benzothiazine; Benzothiazocine; Rearrangements; Ring closing metathesis; Ruthenium carbene

Indexed keywords

2 (2 METHYL 2 PROPENYL) 3,4 DIHYDRO 2H 1,4 BENZOTHIAZINE; 3,4 DIHYDRO 2H 1,4 BENZOTHIAZINE; 6 [(4 METHYLPHENYL)SULFONYL] 5,6 DIHYDRO 2H 1,6 BENZOTHIAZOCINE; 6 [(4 METHYLPHENYL)SULFONYL] 5,6 DIHYDRO 2H 1,6 BENZOTHIAZOCINE 1 OXIDE; ALKADIENE; BENZENESULFONAMIDE DERIVATIVE; BENZOTHIAZINE DERIVATIVE; BENZOTHIAZOCINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; RING CLOSING METATHESIS; STOICHIOMETRY;

EID: 84859495939     PISSN: 00404039     EISSN: 18733581     Source Type: Journal    
DOI: 10.1016/j.tetlet.2012.02.109     Document Type: Article

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