The gibbs-helmholtz equation and the thermodynamic consistency of chemical absorption data

Industrial and Engineering Chemistry Research

Volumn 51, Issue 13, 2012, Pages 5090-5097

  Mathias, Paul M ^a   O'Connell, John P ^b  

^a FLUOR CORPORATION   (United States)

^b University of Virginia   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CALORIMETRY; CARBON DIOXIDE; CHEMICAL ANALYSIS; EQUATIONS OF STATE OF LIQUIDS; ETHANOLAMINES; PHASE EQUILIBRIA; SOLUTIONS; THERMOCHEMISTRY;

CHEMICAL ABSORPTION; EQUATION OF STATE; HEAT OF SOLUTION; HIGHEST TEMPERATURE; MONOETHANOLAMINE; REGENERATION ENERGY; RELIABLE MODELS; THERMODYNAMIC CONSISTENCY;

SOLUTION MINING;

EID: 84859478190     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie202668k     Document Type: Article

References (38)

1. th ed.; Gulf Publishing Company: Houston, 1997.
2. Bottoms, R. R. Process for Separating Acidic Gases. US Patent 1,783,901, December 3, 1930.
3. 2 Capture Science 2009, 325, 1652-1654
4. Ciferno, J; Marano, P.; Munson, J. J.; Technology, R. K. Integration Challenges Chem. Eng. Prog. 2011, August, 34-44
5. O'Connell, J. P.; Gani, R.; Mathias, P. M.; Maurer, G.; Olson, J. D.; Crafts, P. A. Properties in Chemical Process and Product Engineering: Needs, Challenges and Perspectives Ind. Eng. Chem. Res. 1993, 48, 4619-4637
6. Deshmukh, R. D.; Mather, A. E. A Mathematical Model for Equilibrium Solubility of Hydrogen Sulfide and Carbon Dioxide in Aqueous Alkanolamine Solutions Chem. Eng. Sci. 1981, 36, 355-362 (Pubitemid 11466243)
7. Kosinski, J. J.; Wang, P.; Springer, R. D.; Anderko, A. Modeling Acid-Base Equilibria and Phase Behavior in Mixed-Solvent Electrolyte Systems Fluid Phase Equilib. 2007, 1-2, 34-41 (Pubitemid 46818801)
8. 2 Absorption in Aqueous MDEA Solution with Electrolyte NRTL Model Ind. Eng. Chem. Res. 2011, 50, 6436-6446
9. 2 Capture Into Aqueous Solutions of Piperazine Activated 2-Amino-2-methyl-1-propanol Chem. Eng. Sci. 2011, 66, 6193-6198
10. Prausnitz, J. M.; Lichtenthaler, R. N.; de Azevedo, E. G. Molecular Thermodynamics of Fluid-Phase Equilibria; Prentice-Hall, Inc.: Upper Saddle River, NJ, 1999.
11. Smith, J. M.; Van Ness, H. C.; Abbott, M. M. Introduction to Chemical Engineering Thermodynamics, 6 th ed.; McGraw-Hill: New York, 2003.
12. O'Connell, J. P.; Haile, J. M. Thermodynamics: Fundamentals for Applications; Cambridge University Press: New York, 2005.
13. 2 Capture by Aqueous Monoethanolamine AIChE J. 2003, 47, 1676-1686 (Pubitemid 36873810)
14. 2 Absorption in Aqueous MEA Solution with Electrolyte NRTL Model Fluid Phase Equilib. 2011, 311, 68-76
15. Crynes, B. I.; Maddox, R. N. How to Determine Heats from Partial Pressure Data. Oil Gas J. 1969, 15 December, 65-67.
16. 2 Capture by Wet Chemical Absorption: The Misguided Focus on Low Heat of Absorption Solvents Int. J. Greenhouse Gas Control 2010, 4, 36-43
17. 2 Capture at Coal-Fired Power Plants: Should the Heat of Desorption be High, Low or in Between? Current Opin. Chem. Eng. 2011, 1, 55-63
18. Perry, R. L.; Telotte, J. C.; O'Connell, J. P. Solution Thermodynamics for Reactive Components Fluid Phase Equilib. 1981, 5, 245-277
19. Copeman, T. W.; Stein, F. P. On the derivation an Application of Solution Thermodynamics for Reactive Components Fluid Phase Equilib. 1982, 9, 149-165
20. Soave, G. Equilibrium Constants from a Modified Redlich-Kwong Equation of State Chem. Eng. Sci. 1972, 27, 1197-1203
21. Austgen, D. M.; Rochelle, G. T.; Peng, X.; Chen, C.-C. Model of Vapor-Liquid Equilibria for Aqueous Acid Gas-Alkanolamine Systems Using the Electrolyte-NRTL Equation Ind. Eng. Chem. Res. 1989, 28, 1060-1073
22. Liu, Y.; Zhang, L.; Watanasiri, S. Representing Vapor-Liquid Equilibrium for an Aqueous MEA-CO2 System Using the Electrolyte Nonrandom-Two-Liquid Model, Ind Eng. Chem. Res. 1999, 38, 2080-2090 (Pubitemid 29236741)
23. 2 in Aqueous Alkanolamine Solutions using the Extended UNIQUAC model. Application to Monoethanolamine and Methyldiethanolamine Energy Procedia 2009, 1, 861-867
24. 2 in 15, 30, 45 and 60 Mass% MEA from 40 to120 °C and Model Representation Using the Extended UNIQUAC Framework Chem. Eng. Sci. 2011, 66, 6393-6406
25. Weiland, R. H.; Dingman, J. C.; Cronin, D. B.; Browning, G. J. Density and Viscosity of Some Partially Carbonated Aqueous Alkanolamine Solutions and Their Blends J. Chem. Eng. Data 1998, 43, 378-382 (Pubitemid 128594252)
26. Amundsen, T. G.; Øi, L. E.; Eimer, D. A. Density and Viscosity of Monoethanolamine + Water + Carbon Dioxide from (25 to 80) °C J. Chem. Eng. Data 2009, 54, 3096-3100
27. Rowley, R. L.; Wilding, W. V.; Oscarson, J. L.; Yang, Y.; Giles, N. F. DIPPR« Data Compilation of Pure Chemical Properties, Design Institute for Physical Properties, AIChE: New York, NY, 2010.
28. Span, R.; Wagner, W. A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800 MPa J. Phys. Chem. Ref. Data 1996, 25, 1509-1596
29. 2 in Aqueous Monoethanolamine Solutions Ind. Eng. Chem. Res. 1998, 37, 4136-4141
30. Carson, J. K.; Marsh, K. N.; Mather, A. E. Enthalpy of Solution of Carbon Dioxide in (Water + Monoethanolamine, or Diethanolamine, or n-Methyldiethanolamine) and (Water + Monoethanolamine + n-Methyldiethanolamine) at T = 298.15 K J. Chem. Thermodyn. 2000, 32, 1285-1296
31. 2) in Monoethanolamine (MEA) and 2-(Aminoethyl)ethanolamine (AEEA) Solutions Ind. Eng. Chem. Res. 2007, 46 (17) 5803-5809 (Pubitemid 47326299)
32. Arcis, H.; Ballerat-Busserolles, K.; Rodier, L.; Coxam, J.-Y. Enthalpy of Solution of Carbon Dioxide in Aqueous Solutions of Monoethanolamine at Temperatures of 322.5 and 372.9 K and Pressures up to 5 MPa J. Chem. Eng. Data 2011, 56, 3351-3362
33. 2 in 30 Mass Percent Monoethanolamine Solution Can. J. Chem. Eng. 1995, 73, 140-147
34. Ma'mun, S.; Nilsen, R.; Svendsen, H. F. Solubility of Carbon Dioxide in 30 mass % Monoethanolamine and 50 mass % Methyldiethanolamine Solutions J. Chem. Eng. Data 2005, 50, 630-634
35. Lee, J. L.; Otto, F. D.; Mather, A. E. Equilibrium Between Carbon Dioxide and Aqueous Methanolamine Solutions J. Appl. Chem. Biotechnol. 1976, 26, 541-549
36. Jones, J. H.; Froning, H. R.; Claytor, E. E., Jr. Solubility of Acidic Gases in Aqueous Methanolamine J. Chem. Eng. Data 1959, 4, 85-92
37. 2 in Monoethanolamine Solutions at Low Partial Pressures J. Chem. Eng. Data 1980, 25, 118-120
38. Lawson, J. D.; Garst, A. W. Gas sweetening Data: Equilibrium Solubility of Hydrogen Sulfide and Carbon Dioxide in Aqueous Monoethanolamine and Aqueous Diethanolamine Solutions J. Chem. Eng. Data 1976, 21, 20-30