Construction of rhodium(I) and gold(I) macrocycles by transferring a phosphine-functionalized 4,5-diazafluorenide ligand from its copper(I) N-heterocyclic carbene complex

Organometallics

Volumn 31, Issue 6, 2012, Pages 2184-2192

  Tan, Runyu ^a   Chiu, Frederick Sin Nang ^a   Hadzovic, Alen ^a   Song, Datong ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

MACROCYCLES; MACROCYCLIC COMPLEX; MONOMERIC STRUCTURES; MONONUCLEAR COMPLEXES; N-HETEROCYCLIC CARBENE COMPLEX;

CHELATION; CHLORINE COMPOUNDS; COPPER COMPOUNDS; GOLD COMPOUNDS; LIGANDS; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; RHODIUM; SYNTHESIS (CHEMICAL);

RHODIUM COMPOUNDS;

EID: 84859120514     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om200994b     Document Type: Article

References (25)

1. Boyer, J. L.; Kuhlman, M. L.; Rauchfuss, T. B. Acc. Chem. Res. 2007, 40, 233
2. Swiegers, G. F.; Malefetse, T. J. Chem. Rev. 2000, 100, 3483
3. Caulder, D. L.; Raymond, K. N. Acc. Chem. Res. 1999, 32, 975
4. Stang, P. J.; Olenyuk, B. Acc. Chem. Res. 1997, 30, 502
5. Grote, Z.; Scopelliti, R.; Severin, K. Eur. J. Inorg. Chem. 2007, 694
6. Saur, I.; Scopelliti, R.; Severin, K. Chem. Eur. J. 2006, 12, 1058
7. Comprehensive Organometallic Chemistry III; Crabtree, R.; Mingos, M., Eds.; Wiley-VCH: Weinheim, Germany, 2006.
8. Furst, M. R. L.; Cazin, C. S. J. Chem. Commun. 2010, 46, 6924
9. Stepowska, E.; Jiang, H.; Song, D. Chem. Commun. 2010, 46, 556
10. Jiang, H.; Stepowska, E.; Song, D. Eur. J. Inorg. Chem. 2009, 2083
11. Jiang, H.; Stepowska, E.; Song, D. Dalton Trans. 2008, 5879
12. Jiang, H.; Song, D. Organometallics 2008, 27, 3587
13. Baudron, S. A.; Hosseini, M. W. Chem. Commun. 2008, 44, 4558
14. Baudron, S. A.; Hosseini, M. W.; Kyritsakas, N.; Kurmoo, M. Dalton Trans. 2007, 1129
15. Wang, Z.; Shao, H.; Ye, J.; Zhang, L.; Lu, P. Adv. Funct. Mater. 2007, 17, 253
16. Diez-Gonzalez, S.; Escudero-Adan, E. C.; Benet-Buchholz, J.; Stevens, E. D.; Slawin, A. M. Z.; Nolan, S. P. Dalton Trans. 2010, 7595
17. 31P signal should shift downfield significantly (>6 ppm) in comparison to the free ligand. For examples, see: Masar, M. S., III; Mirkin, C. A.; Stern, C. L.; Zakharov, L. N.; Rheingold, A. L. Inorg. Chem. 2004, 43, 4693
18. Lu, Z.; Duan, C.; Tian, Y.; You, X.; Huang, X. Inorg. Chem. 1996, 35, 2253
19. Gimeno, M. C.; Laguna, A. Chem. Rev. 1997, 97, 511
20. Brandys, M.; Jennings, M. C.; Puddephatt, R. J. Dalton Trans. 2000, 4601
21. De Fremont, P.; Scott, N. M.; Stevens, E. D.; Nolan, S. P. Organometallics 2005, 24, 2411
22. Plater, M. J.; Kemp, S.; Lattmann, E. J. Chem. Soc., Perkin Trans. 1 2000, 971
23. Apex 2 Software Package; Bruker AXS Inc., 2008.
24. Sheldrick, G. M. Acta Crystallogr., Sect. A: Found. Crystallogr. 2008, 64, 112
25. Spek, A. L. J. Appl. Crystallogr. 2003, 36, 7