Regeneration characteristics and kinetics of Ni/ZnO-SiO 2-Al 2O 3 adsorbent for reactive adsorption desulfurization

Industrial and Engineering Chemistry Research

Volumn 51, Issue 10, 2012, Pages 3939-3950

  Wen, Yaoshun ^a   Wang, Gang ^a   Wang, Qian ^a   Xu, Chunming ^a   Gao, Jinsen ^a  

^a CHINA UNIVERSITY OF PETROLEUM   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERE PRESSURE; FIXED-BED; HIGH TEMPERATURE; MICRO-REACTOR; PHYSICAL AND CHEMICAL PROPERTIES; REACTIVE ADSORPTION; REGENERATION CYCLES; REGENERATION RATE; SHRINKING CORE MODEL; X-RAY PHOTOELECTRONS; ZINC SULFATE;

ADSORPTION; ALUMINUM; CHEMICAL PROPERTIES; DESULFURIZATION; KINETICS; SILICON COMPOUNDS; X RAY DIFFRACTION; ZINC;

ADSORBENTS;

EID: 84858322272     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie202730w     Document Type: Article

References (43)

1. Brunet, S.; Mey, D.; Perot, G.; Bouchy, C.; Diehl, F. On the hydrodesulfurization of FCC gasoline: a review Appl. Catal., A 2005, 278, 143-172
2. Dos Santos, N.; Dulot, H.; Marchal, N.; Vrinat, M. New insight on competitive reactions during deep HDS of FCC gasoline Appl. Catal., A 2009, 352, 114-123
3. Yu, Z.; Fareid, L. E.; Moljord, K.; Blekkan, E. A.; Walmsley, J. C.; Chen, D. Hydrodesulfurization of thiophene on carbon nanofiber supported Co/Ni/Mo catalysts Appl. Catal., B 2008, 84, 482-489
4. Fan, Y.; Shi, G.; Liu, H. Y.; Bao, X. J. Morphology tuning of supported MoS2 slabs for selectivity enhancement of fluid catalytic cracking gasoline hydrodesulfurization catalysts Appl. Catal., B 2009, 91, 73-82
5. Gao, L. D.; Xue, Q. S.; Liu, Y.; Lu, Y. Base-Free Catalytic Aerobic Oxidation of Mercaptans for Gasoline Sweetening over HTLcs-Derived CuZnAl Catalyst AIChE J. 2009, 55, 3214-3220
6. Jose, N.; Sengupta, S.; Basu, J. K. Optimization of oxidative desulfurization of thiophene using Cu/titanium silicate-1 by box-Behnken design Fuel 2011, 90, 626-632
7. Kedra-Krolik, K.; Fabrice, M.; Jaubert, J. N. Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids: Gasoline and Diesel Desulfurization Ind. Eng. Chem. Res. 2011, 50, 2296-2306
8. Cychosz, K. A.; Wong-Foy, A. G.; Matzger, A. J. Enabling Cleaner Fuels: Desulfurization by Adsorption to Microporous Coordination Polymers J. Am. Chem. Soc. 2009, 131, 14538-14543
9. 3 adsorbents for selective adsorption of thiophene out of hydrocarbon Ind. Eng. Chem. Res. 2006, 45, 6169-6174 (Pubitemid 44412605)
10. Khare, G. P. Desulfurization and novel sorbents for same. U.S. Patent US 20010029311, Al 09864909, 2001.
11. Gislason, J. Refiners sulfur dilemma: Phillips sulfur-removal process nears commercialization Oil Gas J. 2001, 99, 72-76 (Pubitemid 34060829)
12. Babich, I. V.; Moulijn, J. A. Science and technology of novel processes for deep desulfurization of oil refinery streams: A review Fuel 2003, 82, 607-631
13. Bezverkhyy, I.; Ryzhikov, A.; Gadacz, G.; Bellat, J. P. Kinetics of thiophene reactive adsorption on Ni/SiO2 and Ni/ZnO Catal. Today 2008, 130, 199-205 (Pubitemid 350123004)
14. Bezverkhyy, I.; Safonova, O. V.; Afanasiev, P.; Bellat, J. P. Reaction between Thiophene and Ni Nanoparticles Supported on SiO2 or ZnO: In Situ Synchrotron X-ray Diffraction Study J. Phys. Chem. C 2009, 113, 17064-17069
15. Malandra, J. L.; Sughure, E. L.; Johnson, M. J.; Dodwell, G. W.; Reed, L. E.; Bares, J. E.; Gislason, J. J.; Morton, R. W. Desulfurization and novel sorbents for same. U.S. Patent US 20040048743, Al 10660138, 2004.
16. Fan, J. X.; Wang, G.; Sun, Y.; Xu, C. M.; Zhou, H. J.; Zhou, G. L.; Gao, J. S. Research on Reactive Adsorption Desulfurization over Ni/ZnO-SiO2-Al2O3 Adsorbent in a Fixed-Fluidized Bed Reactor Ind. Eng. Chem. Res. 2010, 49, 8450-8460
17. 3 adsorbent by reactive adsorption desulfurization Ind. Eng. Chem. Res. 2011, 50, 12449-12459
18. Huang, L. C.; Wang, G. F.; Qin, Z. F.; Du, M. X.; Dong, M.; Ge, H.; Wu, Z. W.; Zhao, Y. D.; Ma, C. Y.; Hu, T. D.; Wang, J. A sulfur K-edge XANES study on the transfer of sulfur species in the reactive adsorption desulfurization of diesel oil over Ni/ZnO Catal. Commun. 2010, 11, 592-596
19. Huang, L. C.; Wang, G.; Qin, Z.; Dong, M.; Du, M.; Ge, H.; Li, X.; Zhao, Y.; Zhang, J.; Hu, T.; Wang, J. In situ XAS study on the mechanism of reactive adsorption desulfurization of oil product over Ni/ZnO Appl. Catal., B 2011, 106, 26-38
20. 2S removal sorbents in fixed-bed reactors at high temperatures. California Institute of Technology, Pasadena, CA, 1988.
21. Fan, H. L.; Ju, S. G.; Liang, L. T.; Shen, F.; Li, C. H. Reduction Behavior of Iron Oxide Sorbent and Its Effect on Sulfidation Energy Fuels 2010, 24, 3784-3788
22. Jun, H. K.; Lee, T. J.; Kim, J. C. Role of iron oxide in the promotion of Zn-Ti-based desulfurization sorbents during regeneration at middle temperatures Ind. Eng. Chem. Res. 2002, 41, 4733-4738 (Pubitemid 35034219)
23. Park, N. K.; Lee, T. J.; Ryu, S. O. Study on Deactivation of Zinc-Based Sorbents for Hot Gas Desulfurization Ind. Eng. Chem. Res. 2010, 49, 4694-4699
24. Gislason, J. J.; Dodwell, G. W.; Just, D. K.; Morton, R. W.; Johnson, M. J. Desulfurization and novel sorbent for same. U.S. Patent US 20050153838, Al 11054021, 2005.
25. 2S Sorbents Ind. Eng. Chem. Res. 1998, 37, 1929-1933 (Pubitemid 28429760)
26. Guo, J. J.; Huang, J. J.; Zhao, J. T.; Fang, Y. T. Study on regeneration of Ni-Zn-Fe based oxide desulfurizer J. Fuel Chem. Technol. 2010, 38, 352-358
27. Huang, J. J.; Zhao, J. T.; Wei, X. F.; Wang, Y.; Bu, X. P. Kinetics studies on the sulfidation and regeneration of zinc titanate desulfurization sorbent Powder Technol. 2008, 180, 196-202
28. Fan, J. X. Study on mechanism and kinetics of reactive adsorption desulfurization of FCC gasoline. China University of Petroleum Beijing, Beijing, 2010.
29. Kolthoff, I. M.; Stenger, V. A. Volumetric Analysis, 2nd ed.; Interscience Publisher: New York, 1947; Vol. II.
30. Wang, G.; Chen, Z. T.; Lan, X. Y.; Wang, W.; Xu, C. M.; Gao, J. S. Restricted diffusion of residual molecules in catalyst pores under reactive conditions Chem. Eng. Sci. 2011, 66, 1200-1211
31. 2S removal sorbents promoted with cobalt and nickel oxides Energy Fuels 2004, 18, 41-48
32. Narayan, R.; Tabatabaie-Raissi, A.; Antal, M. J. A study of zinc sulfate decomposition at low heating rates Ind. Eng. Chem. Res. 1988, 27, 1050-1058 (Pubitemid 18623432)
33. Zhang, J. C.; Liu, Y. Q.; Tian, S. A.; Chai, Y. M.; Liu, C. G. Reactive adsorption of thiophene on Ni/ZnO adsorbent: Effect of ZnO textural structure on the desulfurization activity J. Nat. Gas Chem. 2010, 19, 327-332
34. Polychronopoulou, K.; Galisteo, F. C.; Granados, M. L.; Fierro, J. L. G.; Bakas, T.; Efstathiou, A. M. Novel Fe-Mn-Zn-Ti-O mixed-metal oxides for the low-temperature removal of H2S from gas streams in the presence of H-2, CO2, and H2O J. Catal. 2005, 236, 205-220
35. Poston, J. A. A Reduction in the Spalling of Zinc Titanate Desulfurization Sorbents through the Addition of Lanthanum Oxide Ind. Eng. Chem. Res. 1996, 35 (3) 875-882
36. http://srdata.nist.gov/xps.
37. Priecel, P.; Kubička, D.; Čapek, L.; Bastl, Z.; Ryšánek, P. The role of Ni species in the deoxygenation of rapeseed oil over NiMo-alumina catalysts Appl. Catal., A 2011, 397, 127-137
38. Dhage, P.; Samokhvalov, A.; Repala, D.; Duin, E. C.; Bowman, M.; Tatarchuk, B. J. Copper-Promoted ZnO/SiO2 Regenerable Sorbents for the Room Temperature Removal of H2S from Reformate Gas Streams Ind. Eng. Chem. Res. 2010, 49, 8388-8396
39. Monazam, E. R.; Shadle, L. J.; Berry, D. A. Modeling and analysis of S-sorption with ZnO in a transport reactor Chem. Eng. Sci. 2008, 63, 2614-2623
40. Konttinen, J. T.; Zevenhoven, C. A. P.; Yrjas, K. P.; Hupa, M. M. Modeling of Sulfided Zinc Titanate Regeneration in a Fluidized-Bed Reactor. 1. Determination of the Solid Conversion Rate Model Parameters Ind. Eng. Chem. Res. 1997, 36, 5432-5438
41. Gbor, P. K.; Jia, C. Q. Critical evaluation of coupling particle size distribution with the shrinking core model Chem. Eng. Sci. 2004, 59, 1979-1987 (Pubitemid 38641238)
42. Jun, H. K.; Lee, T. J.; Ryu, S. O.; Kim, J. C. A study of Zn-Ti-based H2S removal sorbents promoted with cobalt oxides Ind. Eng. Chem. Res. 2001, 40, 3547-3556
43. Levenspiel, O. Chemical Reaction Engineering, 3rd ed.; Wiley: New York, 1999.