Tetrachloridocuprates(II)-synthesis and electron paramagnetic resonance (EPR) spectroscopy

International Journal of Molecular Sciences

Volumn 13, Issue 2, 2012, Pages 1612-1619

  Winter, Alette ^a   Zabel, André ^a   Strauch, Peter ^a  

^a UNIVERSITY OF POTSDAM   (Germany)

Author keywords

Copper(II); Electron paramagnetic resonance; Ionic liquid; Tetrachloridocuprate(II)

Indexed keywords

BENZYLTRIETHYLAMMONIUM; BIS(BENZYLTRIETHYLAMMONIUM)TETRACHLORIDOCUPRATE; BIS(HEXADECYLTRIMETHYLAMMONIUM)TETRACHLORIDOCUPRATE; BIS(N BUTYLPYRIDINIUM)TETRACHLORIDOCUPRATE ZINCATE; BIS(TETRABUTYLAMMONIUM)TETRACHLORIDOCUPRATE; BIS(TETRADECYLTRIMETHYLAMMONIUM)TETRACHLORIDOCUPRATE; CATION; CUPRIC ION; HEXADECYLTRIMETHYLAMMONIUM; IONIC LIQUID; PARAMAGNETIC CUPRIC ION; TETRABUTYLAMMONIUM; TETRADECYLTRIMETHYLAMMONIUM; UNCLASSIFIED DRUG; CHLORIDE; COPPER;

ARTICLE; CONTROLLED STUDY; ELECTRON SPIN RESONANCE; ELECTRON ZEEMANN TENSOR; GEOMETRY; MAGNETISM; MOLECULAR INTERACTION; PHYSICAL PARAMETERS; SYNTHESIS; TEMPERATURE DEPENDENCE; THERMOSTABILITY; ULTRAVIOLET SPECTROPHOTOMETRY; CHEMICAL MODEL; CHEMISTRY;

CHLORIDES; COPPER; ELECTRON SPIN RESONANCE SPECTROSCOPY; IONIC LIQUIDS; MODELS, CHEMICAL;

EID: 84857672857     PISSN: None     EISSN: 14220067     Source Type: Journal    
DOI: 10.3390/ijms13021612     Document Type: Article

References (38)

1. Taubert, A. Heavy elements in ionic liquids. Top. Curr. Chem. 2009, 290, 127-159.
2. Taubert, A. CuCl nanoplatelets from an ionic liquid-crystal precursor. Angew. Chem. Int. Ed. 2004, 43, 5380-5382.
3. Saito, G. Electric Conductivity and Magnetic Ionic Liquids. In Electrochemical Aspects of Ionic Liquids, 2nd ed.; Ohno, H., Ed.; John Wiley & Sons, Inc.: New York, NY, USA, 2011; pp. 337-346.
4. Kalb, R. Use of Magnetic, Ionic Liquids as an Extraction Agent. International Application No.: PCT/EP2008/067731, 17 December 2008.
5. Dengler, J.E.; Doroodian, A.; Rieger, B. Protic metal-containing ionic liquids as catalysts: Cooperative effects between anion and cation. J. Organomet. Chem. 2011, 696, 3831-3835.
6. Bica, K.; Gaertner, P. Metal-containing ionic liquids as efficient catalysts for hydroxymethylation in water. Eur. J. Org. Chem. 2008, 20, 3453-3456.
7. Bica, K.; Gaertner, P. An iron-containing ionic liquid as recyclable catalyst for aryl grignard cross-coupling of aryl halides. Org. Lett. 2006, 8, 733-735.
8. Lin, I.J.B.; Vasam, C.S. Metal-containing ionic liquids and ionic liquid crystals based on imidazolium moiety. J. Organomet. Chem. 2005, 690, 3498-3512.
9. Bowlas, C.J.; Bruce, D.W.; Seddon, K.R. Liquid-crystalline ionic liquids. Chem. Commun. 1996, 14, 1625-1626.
10. 4] copper(II) pyridinium salts. From ionic liquids to layered solids to liquid crystals. Chem. Mater. 2001, 13, 2032-2041.
11. Neve, F.; Francescangeli, O.; Crispini, A. Crystal architecture and mesophase structure of long-chain N-alkylpyridinium tetrachlorometallates. Inorg. Chim. Acta 2002, 338, 51-58.
12. Neve, F.; Crispini, A. C-H···Br-M interactions at work: Tetrabromometalates of the bolaamphiphilic N,N'-dodecamethylenedipyridinium cation. Cryst. Growth Des. 2001, 1, 387-393.
13. Neve, F.; Crispini, A. C-H···Br-M interactions at work: Tetrabromometalates of the bolaamphiphilic N,N′-dodecamethylenedipyridinium cation (correction). Cryst. Growth Des. 2001, 1, 519-519.
14. Taubert, A.; Palivan, C.; Casse, O.; Gozzo, F.; Schmitt, B. Ionic liquid-crystal precursors (ILCPs) for CuCl platelets: The origin of the exothermic peak in the DSC curves. J. Phys. Chem. C 2007, 111, 4077-4082.
15. Taubert, A.; Steiner, P.; Mantion, A. Ionic liquid crystal precursors for inorganic particles: Phase diagram and thermal properties of a CuCl nanoplatelet precursor. J. Phys. Chem. B 2005, 109, 15542-15547.
16. Willett, R.D.; Haugen, J.A.; Lebsack, J.; Morrey, J. Thermochromism in copper(II) chlorides. Coordination geometry. Inorg. Chem. 1974, 13, 2510-2513.
17. Zhuravlev, O.E.; Verolainen, N.V.; Voronchikhina, L.I. Thermal stability of 1,3-disubstituted imidazolium tetrachloroferrates, magnetic ionic liquids. Russ. J. Appl. Chem. 2011, 84, 1158-1164.
18. Branco, A.; Branco, L.C.; Pina, F. Electrochromic and magnetic ionic liquids. Chem. Commun. 2011, 47, 2300-2302.
19. Neve, F.; Crispini, A.; Armentano, S. Synthesis, structure, and thermotropic mesomorphism of layered N-alkylpyridinium tetrahalopalladate(II) salts. Chem. Mater. 1998, 10, 1904-1913.
20. Neve, F.; Francescangeli, O. Layered ω-substituted alkylpyridinium salts with inorganic anions: Effects of H-bonding patterns on the layer thickness. Cryst. Growth Des. 2005, 5, 163-166.
21. Neve, F.; Crispini, A. Competitive interactions in carboxy-functionalized pyridinium salts: Crossover from O-H···O to O-H···X-M contacts. Cryst. Eng. Comm. 2007, 9, 698-703.
22. Neve, F.; Crispini, A. N,N'-Dodecamethylene-bis(pyridinium) goes lamellar. Role of C-H···I, C-H···M, and I···I interactions in the crystal structure of its hexaiododipalladate(II) derivative. Cryst. Eng. Comm. 2003, 5, 265-268.
23. Neve, F.; Crispini A.; Francescangeli, O. Structural studies on layered alkylpyridinium iodopalladate networks. Inorg. Chem. 2000, 39, 1187-1194.
24. Binnemans, K. Ionic liquid crystals. Chem. Rev. 2005, 105, 4148-4204.
25. Goossens, K.; Lava, K.; Nockemann, P.; van Hecke, K.; van Meervelt, L.; Driesen, K.; Görller-Walrand, C.; Binnemans, K.; Cardinaels, C. Pyrrolidinium ionic liquid crystals. Chem. Eur. J. 2009, 15, 656-674.
26. Martinez Casado, F.J.; Ramos Riesco, M.; da Silva, I.; Labrador, A.; Redondo, M.I.; Garcia Perez, M.V.; Lopez-Andres, S.; Rodriguez Cheda, J.A. Thermal and structural study of the crystal phases and mesophases in the lithium and thallium(I) propanoates and pentanoates binary systems: Formation of mixed salts and stabilization of the ionic liquid crystal phase. J. Phys. Chem. B 2010, 114, 10075-10085.
27. Suisse, J.-M.; Douce, L.; Bellemin-Laponnaz, S.; Maisse-Francois, A.; Welter, R.; Miyake, Y.; Shimizu, Y. Liquid crystal imidazolium salts: Towards materials for catalysis and molecular electronics. Eur. J. Inorg. Chem. 2007, 3899-3905.
28. Dobbs, W.; Suisse, J.-M.; Douce, L.; Welter, R. Electrodeposition of silver particles and gold nanoparticles from ionic liquid-crystal precursors. Angew. Chem. Int. Ed. 2006, 45, 4179-4182.
29. Lee, C.K.; Peng, H.H.; Lin, I.J.B. Liquid crystals of N,N'-dialkylimidazolium salts comprising palladium(II) and copper(II) ions. Chem. Mater. 2004, 16, 530-536.
30. 57Fe-labeled tetrachloroferrate(III)-based magnetic ionic liquids. Int. J. Mol. Sci. 2011, 12, 6397-6406.
31. 4]. J. Phys. Condens. Matter 2010, 22, 296006:1-296006:4.
32. Sasaki, T.; Zhong, C.; Tada, M.; Iwasawa, Y. Immobilized metal ion-containing ionic liquids: Preparation, structure and catalytic performance in Kharasch addition reaction. Chem. Commun. 2005, 19, 2506-2508.
33. 2- in CuCl nanoplatelet formation from an ionic liquid precursor (ILP). Phys. Chem. Chem. Phys. 2011, 13, 13537-13543.
34. Farra, R.; Thiel, K.; Winter, A.; Klamroth, T.; Pöppl, A.; Kelling, A.; Schilde, U.; Taubert, A.; Strauch, P. Tetrahalidocuprates(II)-Structure and EPR spectroscopy. Part 1: Tetrabromidocuprates(II). New J. Chem. 2011, 35, 2793-2803.
35. Smith, D.W. Chlorocuprates(II). Coord. Chem. Rev. 1976, 21, 93-158.
36. 4 (X-Cl, Br). Chem. J. Internet 2004, 6, 066039ne.
37. Choi, S.; Larrabee, J.A. Thermochromic tetrachlorocuprate(II). J. Chem. Educ. 1989, 66, 774-776.
38. 4. Mater. Sci. Eng. B 2005, 117, 313-316.