Porous metal materials for polymer electrolyte membrane fuel cells - A review

Applied Energy

Volumn 94, Issue , 2012, Pages 309-329

  Yuan, Wei ^a   Tang, Yong ^a   Yang, Xiaojun ^a   Wan, Zhenping ^a  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Active functional design; Fuel cell; Polymer electrolyte membrane; Porous flow field; Porous metal material

Indexed keywords

ELECTROLYTES; FLOW CONTROL; FOAMS; FUEL CELLS; FUNCTIONAL MATERIALS; METALS; POLYMERS; SINTERING;

CURRENT COLLECTOR; EXPERIMENTAL INVESTIGATIONS; FLOW DISTRIBUTORS; FUEL CELL PERFORMANCE; FUNCTIONAL DESIGN; GAS DIFFUSION BACKING; HIGH POROSITY; HIGH SPECIFIC SURFACE AREA; METAL FOAMS; METAL MESH; POLYMER ELECTROLYTE MEMBRANE; POROUS FLOW; POROUS METAL; POROUS METAL MATERIALS;

PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC);

CATALYST; ELECTROLYTE; FLOW FIELD; FUEL CELL; MEMBRANE; OPTIMIZATION; PERMEABILITY; POLYMER; POROSITY; POROUS MEDIUM;

EID: 84857289301     PISSN: 03062619     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apenergy.2012.01.073     Document Type: Review

References (90)

1. Ashby M.F., Evans A.G., Fleck N.A., Gibson L.J., Hutchinson J.W., Wadley H.N.G. Metal foams: a design guide 2000, Butterworth-Heinemann, Woburn.
2. Gibson L.J., Ashby M.F. Cellular solids: structure and properties 1997, Cambridge University Press, Cambridge, UK. 2nd ed.
3. Evans A.G., Hutchinson J.W., Ashby M.F. Multifunctionality of cellular metal systems. Prog Mater Sci 1999, 43:171-221.
4. Ashby M.F., Lu T.J. Metal foams: a survey. Sci China Ser B 2003, 46:521-532.
5. Davies G.J., Zhen S. Metallic foams: their production, properties and applications. J Mater Sci 1983, 18:1899-1911.
6. Banhart J. Manufacture, characterisation and application of cellular metals and metal foams. Prog Mater Sci 2001, 46:559-632.
7. Lefebvre L.P., Banhart J., Dunand D.C. Porous metals and metallic foams: current Status and recent developments. Adv Eng Mater 2008, 10:775-787.
8. http://www.mkicorp.com/a-fuelcells.asp.
9. Sosnick B. Process for making foam like mass of metal. US patent no. 2434775; 1948.
10. Elliott JC. Method of producing metal foam. US patent no. 2751289; 1956.
11. Hryniewicz T., Skubala W., Chrzczonowicz M. Porous sinters for elevated-temperature natural-gas fuel cells. Powder Technol 1990, 61:217-223.
12. Hui R., Berghaus J.O., Decès-Petit C., Qu W., Yick S., Legoux J.G., et al. High performance metal-supported solid oxide fuel cells fabricated by thermal spray. J Power Sources 2009, 191:371-376.
13. Molin S., Gazda M., Jasinski P. High temperature oxidation of porous alloys for solid oxide fuel cell applications. Solid State Ionics 2010, 181:1214-1220.
14. Wang Y., Chen K.S., Mishler J., Cho S.C., Adroher X.C. A review of polymer electrolyte membrane fuel cells: technology, applications, and needs on fundamental research. Appl Energy 2011, 88:981-1007.
15. Tang Y., Yuan W., Pan M.Q., Wan Z.P. Experimental investigation on the dynamic performance of a hybrid PEM fuel cell/battery system for lightweight electric vehicle application. Appl Energy 2011, 88:68-76.
16. Oszcipok M., Zedda M., Hesselmann J., Huppmann M., Wodrich M., Junghardt M., et al. Portable proton exchange membrane fuel-cell systems for outdoor applications. J Power Sources 2006, 157:666-673.
17. Liu B.H., Li Z.P. Current status and progress of direct borohydride fuel cell technology development. J Power Sources 2009, 187:291-297.
18. Lamy C., Lima A., LeRhun V., Delime F., Coutanceau C., Léger J.M. Recent advances in the development of direct alcohol fuel cells. J Power Sources 2002, 105:283-296.
19. Arun kumar J., Kalyani P., Saravanan R. Studies on PEM fuel dells using various alcohols for low power applications. Int J Electrochem Sci 2008, 3:961-969.
20. Demirci U.B. How green are the chemicals used as liquid fuels in direct liquid-feed fuel cells?. Environ Int 2009, 35:626-631.
21. Tsuchiya H., Kobayashi O. Mass production cost of PEM fuel cell by learning curve. Int J Hydrogen Energy 2004, 29:985-990.
22. Yan X.Q., Hou M., Zhang H.F., Jing F.N., Ming P.W., Yi B.L. Performance of PEMFC stack using expanded graphite bipolar plates. J Power Sources 2006, 160:252-257.
23. Liu Y.X., Hua L. Fabrication of metallic bipolar plate for proton exchange membrane fuel cells by rubber pad forming. J Power Sources 2010, 195:3529-3535.
24. Peng L.F., Lai X.M., Liu D.A., Hua P., Ni J. Flow channel shape optimum design for hydroformed metal bipolar plate in PEM fuel cell. J Power Sources 2008, 178:223-230.
25. Lee S.J., Chen Y.P., Huang C.H. Electroforming of metallic bipolar plates with micro-featured flow field. J Power Sources 2005, 145:369-375.
26. Arisetty S., Prasad A.K., Advani S.G. Metal foams as flow field and gas diffusion layer in direct methanol fuel cells. J Power Sources 2007, 165:49-57.
27. Antunes R.A., Oliveira M.C.L., Ett G., Ett V. Corrosion of metal bipolar plates for PEM fuel cells: a review. Int J Hydrogen Energy 2010, 35:3632-3647.
28. Tawfik H., Hung Y., Mahajan D. Metal bipolar plates for PEM fuel cell-a review. J Power Sources 2007, 163:755-767.
29. Ye H., Liu X.Y., Hong H. Fabrication of metal matrix composites by metal injection molding-a review. J Mater Process Technol 2008, 200:12-24.
30. Kumar S., Kruth J.P. Composites by rapid prototyping technology. Mater Des 2010, 31:850-856.
31. Staiger M.P., Kolbeinsson I., Kirkland N.T., Nguyen T., Dias G., Woodfield T.B.F. Synthesis of topologically-ordered open-cell porous magnesium. Mater Lett 2010, 64:2572-2574.
32. Tang Y., Yuan W., Pan M.Q., Wan Z.P. Feasibility study of porous copper fiber sintered felt: a novel porous flow field in proton exchange membrane fuel cells. Int J Hydrogen Energy 2010, 35:9661-9677.
33. Tang Y., Zhou W., Pan M.Q., Chen H.Q., Liu W.Y., Yu H. Porous copper fiber sintered felts: an innovative catalyst support of methanol steam reformer for hydrogen production. Int J Hydrogen Energy 2008, 33:2950-2956.
34. Tang Y., Xiang J.H., Wan Z.P., Zhou W., Wu L. A novel miniaturized loop heat pipe. Appl Therm Eng 2010, 30:1152-1158.
35. http://www.umtri.umich.edu/content/USFCC-TransportationBrochure.pdf.
36. http://www.mottcorp.com/news/100305_fuel_cells.cfm.
37. Mott porous metal in fuel cells and hydrogen separation. Fuel Cells Bull 2007;5:10.
38. Kumar A., Reddy R.G. Materials and design development for bipolar/end plates in fuel cells. J Power Sources 2004, 129:62-67.
39. Tan J.C., Elliott J.A., Clyne T.W. Analysis of tomography images of bonded fibre networks to measure distributions of fibre segment length and fibre orientation. Adv Eng Mater 2006, 8:495-500.
40. Nakajima H. Fabrication, properties and application of porous metals with directional pores. Prog Mater Sci 2007, 52:1091-1173.
41. http://www.pmiapp.com/publications/.
42. Tang H.L., Wang S.L., Pan M., Yuan R.Z. Porosity-graded micro-porous layers for polymer electrolyte membrane fuel cells. J Power Sources 2007, 166:41-46.
43. Suo C., Liu X., Tang X.C., Zhang Y., Zhang B., Zhang P. A novel MEA architecture for improving the performance of a DMFC. Electrochem Commun 2008, 10:1606-1609.
44. Kannan A.M., Cindrella L., Munukutla L. Functionally graded nano-porous gas diffusion layer for proton exchange membrane fuel cells under low relative humidity conditions. Electrochim Acta 2008, 53:2416-2422.
45. Kumar A., Reddy R.G. Polymer electrolyte membrane fuel cell with metal foam in the gas flow-field of bipolar/end plates. J New Mater Electr Sys 2003, 6:231-236.
46. Kumar A., Reddy R.G. Modeling of polymer electrolyte membrane fuel cell with metal foam in the flow-field of the bipolar/end plates. J Power Sources 2003, 114:54-62.
47. Gajewski A. Contact angle and sessile drop diameter hysteresis on metal surfaces. Int J Heat Mass Transfer 2008, 51:4628-4636.
48. Cheng X., Sastry A.M., Layton B.E. Transport in stochastic fibrous networks. J Eng Mater-T ASME 2001, 123:12-19.
49. Wang H., Sweikart M.A., Turner J.A. Stainless steel as bipolar plate material for polymer electrolyte membrane fuel cells. J Power Sources 2003, 115:243-251.
50. Wang H., Turner J.A. Ferritic stainless steels as bipolar plate material for polymer electrolyte membrane fuel cells. J Power Sources 2004, 128:193-200.
51. Li M.C., Zeng C.L., Luo S.Z., Shen J.N., Lin H.C., Cao C.N. Electrochemical corrosion characteristics of type 316 stainless steel in simulated anode environment for PEMFC. Electrochim Acta 2003, 48:1735-1741.
52. Shudo T., Suzuki K. Performance improvement in direct methanol fuel cells using a highly porous corrosion-resisting stainless steel flow field. Int J Hydrogen Energy 2008, 33:2850-2856.
53. Murphy O.J., Cisar A., Clarke E. Low-cost light weight high power density PEM fuel cell stack. Electrochim Acta 1998, 43:3829-3840.
54. http://www.cea.fr/var/cea/storage/static/gb/library/Clefs50/pdf/076a083baurens-gb.pdf.
55. Hontañón E., Escudero M.J., Bautista C., García-Ybarra P.L., Daza L. Optimisation of flow-field in polymer electrolyte membrane fuel cells using computational fluid dynamics techniques. J Power Sources 2000, 86:363-368.
56. Senn S.M., Poulikakos D. Polymer electrolyte fuel cells with porous materials as fluid distributors and comparisons with traditional channeled systems. J Heat Trans-T ASME 2004, 126:410-418.
57. Birgersson E., Vynnycky M. A quantitative study of the effect of flow-distributor geometry in the cathode of a PEM fuel cell. J Power Sources 2006, 153:76-88.
58. http://www.mae.ncsu.edu/academics/duke-energy-research/pdfs/brown.pdf.
59. Jiang R., Rong C., Chu D. Determination of energy efficiency for a direct methanol fuel cell stack by a fuel circulation method. J Power Sources 2004, 126:119-124.
60. Chen R., Zhao T.S. Porous current collectors for passive direct methanol fuel cells. Electrochim Acta 2007, 52:4317-4324.
61. Chen R., Zhao T.S. A novel electrode architecture for passive direct methanol fuel cells. Electrochem Commun 2007, 9:718-724.
62. Gamburzev S., Appleby A.J. Recent progress in performance improvement of the proton exchange membrane fuel cell (PEMFC). J Power Sources 2002, 107:5-12.
63. Mitchell JP. Current distributors of sintered metals and fuel cells using them. Patent no. WO/1998/52241; 1998.
64. Hottinen T., Mikkola M., Mennola T., Lund P. Titanium sinter as gas diffusion backing in PEMFC. J Power Sources 2003, 118:183-188.
65. Hottinen T., Himanen O., Lund P. Effect of cathode structure on planar free-breathing PEMFC. J Power Sources 2004, 138:205-210.
66. Liu J.G., Sun G.Q., Zhao F.L., Wang G.X., Zhao G., Chen L.K., et al. Study of sintered stainless steel fiber felt as gas diffusion backing in air-breathing DMFC. J Power Sources 2004, 133:175-180.
67. Scott K., Argyropoulos P., Yiannopoulos P., Taama W.M. Electrochemical and gas evolution characteristics of direct methanol fuel cells with stainless steel mesh flow beds. J Appl Electrochem 2001, 31:823-832.
68. Allen R.G., Lim C., Yang L.X., Scott K., Roy S. Novel anode structure for the direct methanol fuel cell. J Power Sources 2005, 143:142-149.
69. Lim C., Scott K., Allen R.G., Roy S. Direct methanol fuel cells using thermally catalysed Ti mesh. J Appl Electrochem 2004, 34:929-933.
70. Cheng H., Scott K. Improvement in methanol oxidation in a centrifugal field. J Power Sources 2003, 123:137-150.
71. Chetty R., Scott K. Direct ethanol fuel cells with catalysed metal mesh anodes. Electrochim Acta 2007, 52:4073-4081.
72. Yu E.H., Scott K. Direct methanol alkaline fuel cell with catalysed metal mesh anodes. Electrochem Commun 2004, 6:361-365.
73. Shao Z.G., Lin W.F., Zhu F.Y., Christensen P.A., Li M.Q., Zhang H.M. Novel electrode structure for DMFC operated with liquid methanol. Electrochem Commun 2006, 8:5-8.
74. Shao Z.G., Lin W.F., Christensen P.A., Zhang H.M. Ti mesh anodes prepared by electrochemical deposition for the direct methanol fuel cell. Int J Hydrogen Energy 2006, 31:1914-1919.
75. Shao Z.G., Lin W.F., Zhu F.Y., Christensen P.A., Zhang H.M., Yi B.L. A tubular direct methanol fuel cell with Ti mesh anode. J Power Sources 2006, 160:1003-1008.
76. Guo Z., Faghri A. Development of planar air breathing direct methanol fuel cell stacks. J Power Sources 2006, 160:1183-1194.
77. Zhang Y., Pitchumani R. Numerical studies on an air-breathing proton exchange membrane (PEM) fuel cell. Int J Heat Mass Transfer 2007, 50:4698-4712.
78. Kim J.H., Kim H.K., Hwang K.T., Lee J.Y. Performance of air-breathing direct methanol fuel cell with anion-exchange membrane. Int J Hydrogen Energy 2010, 35:768-773.
79. Oedegaard A., Hebling C., Schmitz A., Møller-Holst S., Tunold R. Influence of diffusion layer properties on low temperature DMFC. J Power Sources 2004, 127:187-196.
80. Hsiao M.C., Liao S.H., Yen M.Y., Ma C.C.M., Lee S.J., Chen Y.H., et al. Electrical and thermal conductivities of novel metal mesh hybrid polymer composite bipolar plates for proton exchange membrane fuel cells. J Power Sources 2010, 195:509-515.
81. Chang J.Y., Kuan Y.D., Lee S.M., Lee S.R. Characterization of a liquid feed direct methanol fuel cell with Sierpinski carpets fractal current collectors. J Power Sources 2008, 184:180-190.
82. Kuan Y.D., Chang J.Y., Lee S.M., Lee S.R. Characterization of a direct methanol fuel cell using Hilbert curve fractal current collectors. J Power Sources 2009, 187:112-122.
83. Kuan Y.D., Chang J.Y., Lee S.M. Experimental investigation of the effect of free openings of current collectors on a direct methanol fuel cell. J Power Sources 2011, 196:717-728.
84. Tang Y., Yuan W., Pan M.Q., Tang B., Li Z.T., Wan Z.P. Effects of structural aspects on the performance of a passive air-breathing direct methanol fuel cell. J Power Sources 2010, 195:5628-5636.
85. Yuan W., Tang Y., Wang Q.H., Wan Z.P. Dominance evaluation of structural factors in a passive air-breathing direct methanol fuel cell based on orthogonal array analysis. Appl Energy 2011, 88:1671-1680.
86. Yuan W., Tang Y., Wan Z.P., Pan M.Q. Operational characteristics of a passive air-breathing direct methanol fuel cell under various structural conditions. Int J Hydrogen Energy 2011, 36:2237-2249.
87. Hwang J.J., Wu S.D., Lai L.K., Chen C.K., Lai D.Y. Effect of breathing-hole size on the electrochemical species in a free-breathing cathode of a DMFC. J Power Sources 2006, 161:240-249.
88. Yang W.M., Chou S.K., Shu C. Effect of current-collector structure on performance of passive micro direct methanol fuel cell. J Power Sources 2007, 164:549-554.
89. Esquivel J.P., Sabaté N., Santander J., Torres-Herrero N., Gràcia I., Ivanov P., et al. Influence of current collectors design on the performance of a silicon-based passive micro direct methanol fuel cell. J Power Sources 2009, 194:391-396.
90. Li X., Faghri A. Effect of the cathode open ratios on the water management of a passive vapor-feed direct methanol fuel cell fed with neat methanol. J Power Sources 2011, 196:6318-6324.