Photoelectron spectroscopic study of the e ⊗ e Jahn-Teller effect in the presence of a tunable spin-orbit interaction. II. Rovibronic analysis of the 2E ground state of CH 3 +

Molecular Physics

Volumn 109, Issue 17-18, 2011, Pages 2251-2266

  Grtuter M ^a   Merkt, F ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

Jahn Teller effect; methyl chloride; PFI ZEKE photoelectron spectroscopy; spin orbit interaction

Indexed keywords

COMBINED EFFECT; ELECTRONIC EFFECTS; JAHN-TELLER; JAHN-TELLER COUPLINGS; METHYL CHLORIDES; MOLECULAR SYMMETRY; PFI-ZEKE PHOTOELECTRON SPECTROSCOPY; PHOTOELECTRON SPECTRUM; ROTATIONAL CONSTANTS; ROTATIONAL STRUCTURES; SATELLITE BANDS; SELECTION RULES; SINGLE PHOTON EXCITATION; SPECTROSCOPIC STUDIES; SPIN ORBIT INTERACTIONS; SPIN-ORBIT INTERACTION; SPIN-ORBIT SPLITTINGS; VIBRATIONAL LEVELS;

CHLORINE COMPOUNDS; GROUND STATE; PHOTOELECTRON SPECTROSCOPY; PHOTOELECTRONS; SPECTROSCOPIC ANALYSIS;

JAHN-TELLER EFFECT;

EID: 84856993461     PISSN: 00268976     EISSN: 13623028     Source Type: Journal    
DOI: 10.1080/00268976.2011.609143     Document Type: Conference Paper

References (45)

1. L. Karlsson, R. Jadrny, L. Mattsson, F.T. Chau and K. Siegbahn, Physica Scripta 16, 225 (1977).
2. F.T. Chau and L. Karlsson, Physica Scripta 16, 258 (1977).
3. W. Domcke, D.R. Yarkony and H. Köppel, editors, Conical Intersections: Electronic Structure, Dynamics and Spectroscopy Advanced Series in Physical Chemistry, Vol. 15 (World Scientific Publishing, Singapore, 2004).
4. M. Grütter, J.M. Michaud and F. Merkt, J. Chem. Phys. 134, 054308 (2011).
5. J.L. Ragle, I.A. Stenhouse, D.C. Frost and C.A. McDowell, J. Chem. Phys. 53, 178 (1970).
6. R.N. Dixon, J.N. Murrell and B. Narayan, Mol. Phys. 20, 611 (1971).
7. C.L. Lugez, D. Forney, M.E. Jacox and K.K. Irikura, J. Chem. Phys. 106, 489 (1996).
8. R. Locht, B. Leyh, A. Hoxha, D. Dehareng, K. Hottmann, H.W. Jochims and H. Baumgärtel, Chem. Phys. 272, 293 (2001).
9. T.A. Barckholtz and T.A. Miller, Int. Rev. Phys. Chem. 17, 435 (1998).
10. Y. Endo, S. Saito and E. Hirota, J. Chem. Phys. 81, 122 (1984).
11. D. Melnik, J. Liu, R.F. Curl and T.A. Miller, Mol. Phys. 105, 529 (2007).
12. Y. Endo, S. Saito and E. Hirota, J. Chem. Phys. 85, 1770 (1986).
13. M. Grütter, X. Qian and F. Merkt, unpublished results (2011).
14. X. Xing, P. Wang, B. Reed, S.J. Baek and C.Y. Ng, J. Phys. Chem. A 112, 9277 (2008).
15. M. Lee and M.S. Kim, J. Chem. Phys. 127, 124313 (2007).
16. M. Lee, Y.J. Bae and M.S. Kim, J. Chem. Phys. 128, 044310 (2008).
17. Y.J. Bae and M.S. Kim, J. Chem. Phys. 128, 124324 (2008).
18. Y.J. Bae and M.S. Kim, ChemPhysChem 9, 1709 (2008).
19. P. Wang, X. Xing, K.C. Lau, H.K. Woo and C.Y. Ng, J. Chem. Phys. 121, 7049 (2004).
20. X. Xing, B. Reed, M.K. Bahng, S.J. Baek, P. Wang and C.Y. Ng, J. Chem. Phys. 128, 104306 (2008).
21. R. Locht, B. Leyh, A. Hoxha, H.W. Jochims and H. Baumgärtel, Chem. Phys. 272, 259 (2001).
22. S. Eden, P. Limao-Vieira, S.V. Hoffmann and N.J. Mason, Chem. Phys. 331, 232 (2007).
23. P. Rupper and F. Merkt, Rev. Sci. Instrum. 75, 613 (2004).
24. F.M. Phelps III, editor, M.I.T. Wavelength Tables, Vol. 2, Wavelengths by Element (MIT Press, Cambridge, MA, 1982).
25. U. Hollenstein, R. Seiler, H. Schmutz, M. Andrist and F. Merkt, J. Chem. Phys. 115, 5461 (2001).
26. I.B. Bersuker, The Jahn-Teller Effect (Cambridge University Press, Cambridge, 2006).
27. S. Mahapatra, V. Vallet, C. Woywood, H. Köppel and W. Domcke, Chem. Phys. 304, 17 (2004).
28. S. Mahapatra, V. Vallet, C. Woywood, H. Köppel and W. Domcke, J. Chem. Phys. 123, 231103 (2005).
29. B.F. Yates, W.J. Bouma and L. Radom, J. Am. Chem. Soc. 109, 2250 (1987).
30. J.W. Gauld and L. Radom, J. Phys. Chem. 98, 777 (1994).
31. H.C. Longuet-Higgins, U. Öpik, M.H.L Pryce and R.A. Sack, Proc. R. Soc. London Ser. A 244 (1236), 1 (1958).
32. H.A. Kramers, Proc. Kon. Akad. Wet. Amsterdam 33, 959 (1930).
33. M.S. Child, J. Mol. Spectrosc. 10, 357 (1963).
34. J.M. Brown, Mol. Phys. 20, 817 (1971).
35. M.S. Child and H.C. Longuet-Higgins, Phil. Trans. R. Soc. London Ser. A 254 (1041), 259 (1961).
36. R. Signorell and F. Merkt, Mol. Phys. 92, 793 (1997).
37. A.V. Nikitin, J. Mol. Spectrosc. 252, 17 (2008).
38. G. Herzberg, Molecular Spectra and Molecular Structure. Volume II, Infrared and Raman Spectra of Polyatomic Molecules (Van Nostrand Reinhold, New York, 1945).
39. L.N. Stříteská, M. Šimečková , P. Kania, P. Musil, L. Kolesniková , J. Koubek and Š. Urban, J. Mol. Struct. 919, 89 (2009).
40. A. Nikitin and J.P. Champion, J. Mol. Spectrosc. 230, 168 (2005).
41. J. Xie and R.N. Zare, J. Chem. Phys. 97, 2891 (1992).
42. A.W. Potts and W.C. Price, Trans. Farad. Soc. 67, 1242 (1971).
43. J.E. Sansonetti, W.C. Martin and S.L. Young, Handbook of Basic Atomic Spectroscopic Data (version 1.1.2), National Institute of Standards and Technology, Gaithersburg, MD [Online] http://physics.nist.gov/ Handbook [2010, Nov 18] 2005.
44. M. Grütter and F. Merkt, unpublished results (2011).
45. F. Merkt, S. Willitsch and U. Hollenstein, High-resolution Photoelectron Spectroscopy, in Handbook of High-Resolution Spectroscopy, edited by M. Quack and F. Merkt, Vol. 3 (John Wiley, Chichester, 2011).