Photoelectron spectroscopic study of the E⊗e Jahn-Teller effect in the presence of a tunable spin-orbit interaction. I. Photoionization dynamics of methyl iodide and rotational fine structure of CH3I+ and CD3I+

Journal of Chemical Physics

Volumn 134, Issue 5, 2011, Pages

  Grutter M ^a   Michaud, J M ^a   Merkt, F ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ADIABATIC IONIZATION ENERGIES; ANGULAR MOMENTUM COUPLING; DOUBLE GROUPS; FINE STRUCTURES; HIGH RESOLUTION; IONIC STATE; IONIZATION SPECTRUM; ISOTOPOMERS; JAHN TELLER EFFECT; JAHN-TELLER COUPLINGS; METHYL IODIDE; NEUTRAL STATE; PHOTOELECTRON SPECTRUM; PHOTOIONIZATION DYNAMICS; PULSED FIELD IONIZATION ZERO KINETIC ENERGIES; QUANTUM NUMBERS; ROTATIONAL CONSTANTS; ROTATIONAL STRUCTURES; ROVIBRONIC STRUCTURES; SELECTION RULES; SPECTROSCOPIC STUDIES; SPIN ORBIT INTERACTIONS; SPIN ORBITS; SPIN-ORBIT COUPLINGS; SUB-BANDS;

ANGULAR MOMENTUM; ORBITS; PHOTOELECTRON SPECTROSCOPY; PHOTOELECTRONS; PHOTONS; QUANTUM THEORY; SPECTROSCOPIC ANALYSIS;

PHOTOIONIZATION;

EID: 79951524688     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3547548     Document Type: Article

References (60)

1. I. B. Bersuker, The Jahn-Teller Effect (Cambridge University Press, Cambridge, UK, 2006).
2. Conical Intersections: Electronic Structure, Dynamics and Spectroscopy, Advanced Series in Physical Chemistry Vol. 15, edited by, W. Domcke, D. R. Yarkony, and, H. Kppel, (World Scientific Publishing Co., Singapore, 2004).
3. T. A. Barckholtz and T. A. Miller, Int. Rev. Phys. Chem. 17, 435 (1998). 10.1080/014423598230036
4. J. L. Ragle, I. A. Stenhouse, D. C. Frost, and C. A. McDowell, J. Chem. Phys. 53, 178 (1970). 10.1063/1.1673762
5. D. W. Turner, Philos. Trans. R. Soc. London, Ser. A 268, 7 (1970). 10.1098/rsta.1970.0059
6. A. W. Potts, H. J. Lempka, D. G. Streets, and W. C. Price, Philos. Trans. R. Soc. London, Ser. A 268, 59 (1970). 10.1098/rsta.1970.0061
7. R. N. Dixon, J. N. Murrell, and B. Narayan, Mol. Phys. 20, 611 (1971). 10.1080/00268977100100591
8. L. Karlsson, R. Jadrny, L. Mattsson, F. T. Chau, and K. Siegbahn, Phys. Scr. 16, 225 (1977). 10.1088/0031-8949/16/5-6/010
9. R. Locht, B. Leyh, A. Hoxha, D. Dehareng, H. W. Jochims, and H. Baumgrtel, Chem. Phys. 257, 283 (2000). 10.1016/S0301-0104(00)00167-1
10. R. Locht, B. Leyh, A. Hoxha, D. Dehareng, K. Hottmann, H. W. Jochims, and H. Baumgrtel, Chem. Phys. 272, 293 (2001). 10.1016/S0301-0104(01)00466-9 (Pubitemid 32958796)
11. R. Locht, D. Dehareng, K. Hottmann, H. W. Jochims, H. Baumgrtel, and B. Leyh, J. Phys. B 43, 105101 (2010). 10.1088/0953-4075/43/10/105101
12. F. T. Chau and L. Karlsson, Phys. Scr. 16, 258 (1977). 10.1088/0031-8949/16/5-6/014
13. S. Mahapatra, V. Vallet, C. Woywood, H. Kppel, and W. Domcke, Chem. Phys. 304, 17 (2004). 10.1016/j.chemphys.2004.04.021
14. S. Mahapatra, V. Vallet, C. Woywood, H. Kppel, and W. Domcke, J. Chem. Phys. 123, 231103 (2005). 10.1063/1.2140739 (Pubitemid 41828964)
15. A. Strobel, I. Fischer, A. Lochschmidt, K. Mller-Dethlefs, and V. E. Bondybey, J. Phys. Chem. 98, 2024 (1994). 10.1021/j100059a008
16. B. Urban and V. E. Bondybey, J. Chem. Phys. 116, 4938 (2002). 10.1063/1.1447219 (Pubitemid 34923854)
17. P. Wang, X. Xing, K.-C. Lau, H. K. Woo, and C. Y. Ng, J. Chem. Phys. 121, 7049 (2004). 10.1063/1.1807818
18. X. Xing, B. Reed, M.-K. Bahng, S.-J. Baek, P. Wang, and C. Y. Ng, J. Chem. Phys. 128, 104306 (2008). 10.1063/1.2888557 (Pubitemid 351399707)
19. X. Xing, P. Wang, B. Reed, S.-J. Baek, and C. Y. Ng, J. Phys. Chem. A 112, 9277 (2008). 10.1021/jp8019649
20. M. Lee, Y. J. Bae, and M. S. Kim, J. Chem. Phys. 128, 044310 (2008). 10.1063/1.2823032 (Pubitemid 351191608)
21. D. C. McGilvery and J. D. Morrison, J. Chem. Phys. 67, 368 (1977). 10.1063/1.434534
22. S. P. Goss, J. D. Morrison, and D. L. Smith, J. Chem. Phys. 75, 757 (1981). 10.1063/1.442117
23. R. G. McLoughlin, J. D. Morrison, D. L. Smith, and A. L. Wahrhaftig, J. Chem. Phys. 82, 1237 (1985). 10.1063/1.448443
24. M. Lee and M. S. Kim, J. Chem. Phys. 127, 124313 (2007). 10.1063/1.2778679 (Pubitemid 47502666)
25. Y. J. Bae and M. S. Kim, J. Chem. Phys. 128, 124324 (2008). 10.1063/1.2884340 (Pubitemid 351474091)
26. Y. J. Bae and M. S. Kim, ChemPhysChem 9, 1709 (2008). 10.1002/cphc.200800207
27. Y. Endo, S. Saito, and E. Hirota, J. Chem. Phys. 81, 122 (1984). 10.1063/1.447375
28. Y. Endo, S. Saito, and E. Hirota, J. Chem. Phys. 85, 1770 (1986). 10.1063/1.451178
29. D. Melnik, J. Liu, R. F. Curl, and T. A. Miller, Mol. Phys. 105, 529 (2007). 10.1080/00268970601146864 (Pubitemid 46781387)
30. J. Liu, M.-W. Chen, D. Melnik, J. T. Yi, and T. A. Miller, J. Chem. Phys. 130, 074302 (2009). 10.1063/1.3072104
31. J. M. Brown, Mol. Phys. 20, 817 (1971). 10.1080/00268977100100801
32. H. C. Longuet-Higgins, U. pik, M. H. L. Pryce, and R. A. Sack, Proc. R. Soc. London, Ser. A 244, 1 (1958). 10.1098/rspa.1958.0022
33. M. Grtter and F. Merkt (unpublished).
34. U. Hollenstein, H. Palm, and F. Merkt, Rev. Sci. Instrum. 71, 4023 (2000). 10.1063/1.1310344
35. U. Hollenstein, R. Seiler, H. Schmutz, M. Andrist, and F. Merkt, J. Chem. Phys. 115, 5461 (2001). 10.1063/1.1396856 (Pubitemid 32962094)
36. Th.A. Paul, J. Liu, and F. Merkt, Phys. Rev. A 79, 022505 (2009). 10.1103/PhysRevA.79.022505
37. G. S. Coumbarides, J. Eames, and N. Weerasooriya, J. Labelled Compd. Radiopharm. 46, 291 (2003). 10.1002/jlcr.666 (Pubitemid 36514051)
38. W. Domcke, S. Mishra, and L. V. Poluyanov, Chem. Phys. 322, 405 (2006). 10.1016/j.chemphys.2005.09.009
39. J. T. Hougen, J. Mol. Spectrosc. 81, 73 (1980). 10.1016/0022-2852(80) 90330-6
40. F. S. Ham, Phys. Rev. 138, A1727 (1965). 10.1103/PhysRev.138.A1727
41. G. Herzberg, Molecular Spectra and Molecular Structure, Vol. III: Electronic Spectra and Electronic Structure of Polyatomic Molecules (Krieger Publishing Company, Malabar, 1991).
42. D. S. McClure, J. Chem. Phys. 20, 682 (1952). 10.1063/1.1700516
43. H. A. Kramers, Proc. Kon. Akad. Wet. Amsterdam 33, 959 (1930).
44. P. R. Bunker and P. Jensen, Molecular Symmetry and Spectroscopy, 2nd ed. (NRC Research Press, Ottawa, 1998).
45. M. S. Child, Mol. Phys. 5, 391 (1962). 10.1080/00268976200100441
46. J. K.G. Watson, Mol. Phys. 15, 479 (1968). 10.1080/00268976800101381
47. F. Hund, Z. Phys. 51, 759 (1928). 10.1007/BF01400239
48. M. S. Child and H. C. Longuet-Higgins, Philos. Trans. R. Soc. London, Ser. A 254, 259 (1961). 10.1098/rsta.1961.0017
49. J. H. Van Vleck, Rev. Mod. Phys. 23, 213 (1951). 10.1103/RevModPhys.23. 213
50. G. Wlodarzcak, D. Boucher, R. Bocquet, and J. Demaison, J. Mol. Spectrosc. 124, 53 (1987). 10.1016/0022-2852(87)90120-2
51. M. Koivusaari, J. Mol. Spectrosc. 172, 176 (1995). 10.1006/jmsp.1995.1164
52. S. Carocci, A. Di Lieto, A. De Fanis, P. Minguzzi, S. Alanko, and J. Pietil, J. Mol. Spectrosc. 191, 368 (1998). 10.1006/jmsp.1998.7652
53. F. Merkt and T. P. Softley, Int. Rev. Phys. Chem. 12, 205 (1993). 10.1080/01442359309353282
54. R. Signorell and F. Merkt, Mol. Phys. 92, 793 (1997).
55. A. D. Buckingham, B. J. Orr, and J. M. Sichel, Philos. Trans. R. Soc. London, Ser. A 268, 147 (1970). 10.1098/rsta.1970.0068
56. S. Willitsch and F. Merkt, Int. J. Mass Spectrom. 245, 14 (2005). 10.1016/j.ijms.2005.06.004 (Pubitemid 41317812)
57. J. M. Sichel, Mol. Phys. 18, 95 (1970). 10.1080/00268977000100081
58. J. E. Sansonetti, W. C. Martin, and S. L. Young, Handbook of Basic Atomic Spectroscopic Data (version 1.1.2) (National Institute of Standards and Technology, Gaithersburg, 2005).
59. A. W. Potts and W. C. Price, Trans. Faraday Soc. 67, 1242 (1971). 10.1039/tf9716701242
60. H. J. Wrner and F. Merkt, J. Chem. Phys. 127, 034303 (2007). 10.1063/1.2748049 (Pubitemid 47120718)