New insights in the velocity dependency of the external mass transfer coefficient in 2D and 3D porous media for liquid chromatography

Journal of Chromatography A

Volumn 1227, Issue , 2012, Pages 194-202

  Deridder, Sander ^a   Desmet, Gert ^a  

^a VRIJE UNIVERSITEIT BRUSSEL   (Belgium)

Author keywords

Computational fluid dynamics; Mass transfer; Monolith; Packed bed; TSM

Indexed keywords

3D STRUCTURE; AXIAL DISPERSIONS; EXPERIMENTAL STUDIES; EXTERNAL MASS TRANSFER COEFFICIENT; IN-LINE; LOW VELOCITIES; MASS TRANSFER PROCESS; MASS TRANSFER RATE; MOBILE PHASE; MONOLITH; NEW CORRELATIONS; NUMERICAL CALCULATION; PACKED BED COLUMN; PACKING GEOMETRY; PENETRATION MODELS; PILLAR ARRAYS; PLATE HEIGHT; REDUCED VELOCITY; TSM;

COMPUTATIONAL FLUID DYNAMICS; LIQUID CHROMATOGRAPHY; PACKED BEDS; POROUS MATERIALS; THREE DIMENSIONAL;

MASS TRANSFER;

ACCURACY; ARTICLE; COMPUTATIONAL FLUID DYNAMICS; CONCENTRATION (PARAMETERS); CONSTANTS AND COEFFICIENTS; CONTROLLED STUDY; DIFFUSION COEFFICIENT; LIQUID CHROMATOGRAPHY; MASS TRANSFER COEFFICIENT; MATHEMATICAL COMPUTING; MATHEMATICAL MODEL; PARTICLE SIZE; POROSITY; PREDICTION; PRIORITY JOURNAL; STEADY STATE; STRUCTURE ANALYSIS; VALIDATION PROCESS; VELOCITY;

CHROMATOGRAPHY, LIQUID; COMPUTER SIMULATION; HYDRODYNAMICS; MODELS, CHEMICAL;

EID: 84856589968     PISSN: 00219673     EISSN: 18733778     Source Type: Journal    
DOI: 10.1016/j.chroma.2012.01.007     Document Type: Article

References (39)

1. Lapidus L., Amundson N.R.J. Phys. Chem. 1952, 56:984.
2. van Deemter J.J., Zuiderweg F.J., Klinkenberg A. Chem. Eng. Sci. 1956, 5:271.
3. Huber J. J. Chromatogr. Sci. 1969, 7:85.
4. Kucera E. J. Chromatogr. 1965, 19:237.
5. Horvath C., Lin H.-J. J. Chromatogr. 1976, 126:401.
6. Gritti F., Guiochon G. Anal. Chem. 2006, 78:5329.
7. Felinger A. J. Chromatogr. A 2006, 1126:120.
8. Desmet G., Broeckhoven K. Anal. Chem. 2008, 80:8076.
9. Desmet G., Deridder S. J. Chromatogr. A 2011, 1218:32.
10. Miyabe K., Ando M., Ando N., Guiochon G. J. Chromatogr. A 2008, 1210:60.
11. Giddings J.C. Dynamics of Chromatography. Part 1 1965, Marcel Dekker, New York.
12. Magnico P., Martin M. J. Chromatogr. A 1990, 571:31.
13. Wilson E.J., Geankoplis C.J. Ind. Eng. Chem. Fundam. 1966, 5:9.
14. Gritti F., Guiochon G. J. Chromatogr. A 2010, 1217:5137.
15. Cavazzini A., Gritti F., Kaczmarski K., Marchetti N., Guiochon G. Anal. Chem. 2007, 79:5972.
16. Guiochon G. J. Chromatogr. A 2007, 1168:101.
17. Gritti F., Guiochon G. J. Chromatogr. A 2009, 1216:4752.
18. Detobel F., Desmet G. Modeling chromatographic band broadening in monolithic columns. Monolithic Silicas in Separation Science: Concepts, Synthesis, Characterization, Modeling and Applications 2011, 105-126. VCH Wiley Verlag GmbH, Weinheim. E. Machtejevas, N. Tanaka, K.K. Unger (Eds.).
19. De Wilde D., Detobel F., Billen J., Deconinck J., Desmet G. J. Sep. Sci. 2009, 32:4077.
20. Papoutsakis E., Ramkrishna D., Lim H.C. Appl. Sci. Res. 1980, 36:13.
21. Fedkiw P., Newman J. Chem. Eng. Sci. 1978, 33:1043.
22. Fedkiw P., Newman J. Int. J. Heat Mass Transfer 1982, 25:935.
23. Wakao N., Kaguei S., Funazkri T. Chem. Eng. Sci. 1978, 34:325.
24. Sohn H.Y. Lett. Heat Mass Transfer 1977, 4:403.
25. Gritti F., Guiochon G. J. Chromatogr. A 2011, 1218:907.
26. Miyauchi T., Kikuchi T., Hsu K.H. Chem. Eng. Sci. 1975, 31:493.
27. Gunn D.J., Souza J.F.C. Chem. Eng. Sci. 1974, 29:1363.
28. Pfeffer R. Ind. Eng. Chem. Fundam. 1964, 3:380.
29. Rexwinkel G., Heesink A.B.M., Swaaij W.P.M. Chem. Eng. Sci. 1997, 52:3995.
30. Tock P.P.H., Duijsters P.P.E., Kraak J.C., Poppe H. J. Chromatogr. 1990, 506:185.
31. Knox J.H. J. Chromatogr. Sci. 1980, 7:453.
32. De Malsche W., Gardeniers H., Desmet G. Anal. Chem. 2008, 80:5391.
33. Eghbali H., Verdoold V., Vankeerbergen L., Gardeniers J.G.E., Desmet G. Anal. Chem. 2009, 81:705.
34. Detobel F., De Bruyne S., Vangelooven J., De Malsche W., Aerts T., Terryn H., Gardeniers H., Eeltink S., Desmet G. Anal. Chem. 2010, 82:7208.
35. Vervoort N., Gzil P., Baron G.V., Desmet G. Anal. Chem. 2003, 75:843.
36. Vervoort N., Gzil P., Baron G.V., Desmet G. J. Chromatogr. A 2004, 1030:177.
37. Gzil P., Vervoort N., Baron G.V., Desmet G. J. Sep. Sci. 2004, 27:887.
38. Incropera F.P., DeWitt D.P. Fundamentals of Heat and Mass Transfer 2002, John Wiley & Sons, New York. 5th ed.
39. Kataoka T., Yoshida H., Ueyama K. J. Chem. Eng. Jpn. 1972, 5:132.